New analytical techniques for mycotoxins in complex organic matrices

Air samples are collected for analysis from the Ames Solid Waste Recovery System. The high level of airborne fungi within the processing area is of concern due to the possible presence of toxic mycotoxins, and carcinogenic fungal metabolites. An analytical method has been developed to determine the concentration of aflatoxins B1, B2, G1, and G2 in the air of the plant which produces Refuse Derived Fuel (RDF);After extraction with methanol, some components in the matrix are precipitated by dissolving the sample in 30% acetonitrile/chloroform. An aliquot of this solution is injected onto a Styragel column where the sample components undergo simultaneous size exclusion and reverse phase partitioning. Additional studies have provided a more thorough understanding of solvent related non-exclusion effects on size exclusion gels. The Styragel column appears to have a useable lifetime of more than six months. After elution from Styragel, the sample is diverted to a second column containing Florisil which has been modified with oxalic acid and deactivated with water;Aflatoxins are eluted with 5% water/acetone. After removal of this solvent, the sample is dissolved in 150 (mu)L of a spotting solvent and the entire sample applied to a thin layer chromatography (TLC) plate using a unique sample applicator developed here. The aflatoxins on the TLC plate are analyzed by laser fluorescence;A detection limit of 10 pg is possible for aflatoxin standards using a nitrogen laser as the excitation source. Sample concentrations are determined by comparing with an internal standard, a specially synthesized aflatoxin derivative. In two separate RDF samples, aflatoxin B1 was found at levels of 6.5 and 17.0 ppb. The analytical method has also proven useful in the analysis of contaminated corn and peanut meal samples;In a separate study, the spore pigment in Aspergillus flavus wasisolated. The mass spectrum indicates a molecular weight in excessof 700. Only aliphatic hydrocarbons have been identified in the massspectrum of products from a permanganate oxidation. The isolatedpigment is obviously a mixture and no further work was done to;elucidate structures;(\u271)This research was supported by U.S. Department of Energy, Contract No. W-7405-Eng-82

Generation and remote detection of THz sound using semiconductor superlattices

The authors introduce a novel approach to study the propagation of high frequency acoustic phonons in which the generation and detection involves two spatially separated superlattices $\sim 1 {\rm \mu m}$ apart. Propagating modes of frequencies up to $\sim 1 {\rm THz}$ escape from the superlattice where they are generated and reach the second superlattice where they are detected. The measured frequency spectrum reveals finite size effects, which can be accounted for by a continuum elastic model.Comment: Submitted to Applied Physics Letter

UV slope of z∼\sim3 bright (L>L∗L>L^{*}) Lyman-break galaxies in the COSMOS field

We analyse a unique sample of 517 bright ($L>L^{*}$) LBGs at redshift z$\sim$3 in order to characterise the distribution of their UV slopes $\beta$ and infer their dust extinction under standard assumptions. We exploited multi-band observations over 750 arcmin$^2$ of the COSMOS field that were acquired with three different ground-based facilities: the Large Binocular Camera (LBC) on the Large Binocular Telescope (LBT), the Suprime-Cam on the SUBARU telescope, and the VIRCAM on the VISTA telescope (ULTRAVISTA DR2). Our multi-band photometric catalogue is based on a new method that is designed to maximise the signal-to-noise ratio in the estimate of accurate galaxy colours from images with different point spread functions (PSF). We adopted an improved selection criterion based on deep Y-band data to isolate a sample of galaxies at $z\sim 3$ to minimise selection biases. We measured the UV slopes ($\beta$) of the objects in our sample and then recovered the intrinsic probability density function of $\beta$ values (PDF($\beta$)), taking into account the effect of observational uncertainties through detailed simulations. The galaxies in our sample are characterised by mildly red UV slopes with $\simeq -1.70$ throughout the enitre luminosity range that is probed by our data ($-24\lesssim M_{1600}\lesssim -21$). The resulting dust-corrected star formation rate density (SFRD) is $log(SFRD)\simeq-1.6 M_{\odot}/yr/Mpc^{3}$, corresponding to a contribution of about 25% to the total SFRD at z$\sim$3 under standard assumptions. Ultra-bright LBGs at $z \sim 3$ match the known trends, with UV slopes being redder at decreasing redshifts, and brighter galaxies being more highly dust extinct and more frequently star-forming than fainter galaxies. [abridged]Comment: Matched to journal version. 11 pages, 13 figures, Astronomy & Astrophysics in pres

Effect of Fibonacci Modulation On Superconductivity

We have studied finite-sized single band models with short range pairing interactions between electrons in presence of diagonal Fibonacci modulation in one dimension. Two models, namely the attractive Hubbard model and the Penson-Kolb model, have been investigated at half-filling at zero temperature by solving the Bogoliubov-de Gennes equations in real space within a mean field approximation. The competition between ``disorder'' and the pairing interaction leads to a suppression of superconductivity (of usual pairs with zero centre-of-mass momenta) in the strong-coupling limit while an enhancement of the pairing correlation is observed in the weak-coupling regime for both the models. However, the dissimilarity of the pairing mechanisms in these two models brings about notable difference in the results. The extent to which the bond ordered wave and the $\eta$-paired (of pairs with centre-of-mass momenta = $\pi$) phases of the Penson-Kolb model are affected by the disorder has also been studied in the present calculation. Some finite size effects are also identified.Comment: 14 pages, 13 figure

Dynamical phenomena in Fibonacci Semiconductor Superlattices

We present a detailed study of the dynamics of electronic wavepackets in Fibonacci semiconductor superlattices, both in flat band conditions and subject to homogeneous electric fields perpendicular to the layers. Coherent propagation of electrons is described by means of a scalar Hamiltonian using the effective-mass approximation. We have found that an initial Gaussian wavepacket is filtered selectively when passing through the superlattice. This means that only those components of the wavepacket whose wavenumber belong to allowed subminibands of the fractal-like energy spectrum can propagate over the entire superlattice. The Fourier pattern of the transmitted part of the wavepacket presents clear evidences of fractality reproducing those of the underlying energy spectrum. This phenomenon persists even in the presence of unintentional disorder due to growth imperfections. Finally, we have demonstrated that periodic coherent-field induced oscillations (Bloch oscillations), which we are able to observe in our simulations of periodic superlattices, are replaced in Fibonacci superlattices by more complex oscillations displaying quasiperiodic signatures, thus sheding more light onto the very peculiar nature of the electronic states in these systems.Comment: 7 pagex, RevTex, 5 Postscript figures. Physical Review B (in press

Raman scattering by optical phonons in In1−y−zAlyGazAs lattice matched to InP

We report on Raman scattering by longitudinal optical phonons in In1−y−zAlyGazAs (1−y−z=0.53) lattice matched to InP. The quaternary alloys were grown on (001) InP by molecular beam epitaxy. The phonon spectra exhibit three‐mode behavior. The frequencies of AlAs‐ and GaAs‐like modes vary linearly with the concentration of Al (or Ga) while the position of the InAs‐like phonon remains nearly constant. The data show no evidence of alloy clustering.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/71267/2/APPLAB-53-17-1652-1.pd

Phonon Universal Transmission Fluctuations and Localization in Semiconductor Superlattices with a Controlled Degree of Order

We study both analytically and numerically phonon transmission fluctuations and localization in partially ordered superlattices with correlations among neighboring layers. In order to generate a sequence of layers with a varying degree of order we employ a model proposed by Hendricks and Teller as well as partially ordered versions of deterministic aperiodic superlattices. By changing a parameter measuring the correlation among adjacent layers, the Hendricks- Teller superlattice exhibits a transition from periodic ordering, with alterna- ting layers, to the phase separated opposite limit; including many intermediate arrangements and the completely random case. In the partially ordered versions of deterministic superlattices, there is short-range order (among any $N$ conse- cutive layers) and long range disorder, as in the N-state Markov chains. The average and fluctuations in the transmission, the backscattering rate, and the localization length in these multilayered systems are calculated based on the superlattice structure factors we derive analytically. The standard deviation of the transmission versus the average transmission lies on a {\it universal\/} curve irrespective of the specific type of disorder of the SL. We illustrate these general results by applying them to several GaAs-AlAs superlattices for the proposed experimental observation of phonon universal transmission fluctuations.Comment: 16-pages, Revte

Field‐dependent linewidths and photoluminescence energies in GaAs‐AlGaAs multiquantum well modulators

Photoluminescence linewidths and transition energies have been measured in GaAs‐AlGaAs multiple quantum wells with large (≥160 Å) barrier widths as a function of applied transverse electric field. The experimental data agree well with values calculated by using a recently developed variational technique. It is apparent that heterointerface roughness is the dominant line broadening mechanism. The emission intensity decreases rapidly with field, principally due to carrier tunneling at high fields. At 80 kV/cm a shift of 20 meV in the emission energy is observed.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70001/2/APPLAB-48-19-1246-1.pd

Vertical Transmission of Herpes Simplex Virus Acquired After Primary Outbreak in Second Trimester of a Dichorionic Twin Gestation

Background: The incidence of genital herpes simplex virus (HSV) has increased in recent years, particularly among women of reproductive age. This places more neonates at risk for severe morbidity and mortality. Treatment recommendations for primary disease in pregnancy are lacking, particularly for those who acquire. HSV remote from term

Methane, ammonia, and their irradiation products at the surface of an intermediate-size KBO? A portrait of Plutino (90482) Orcus

Orcus is an intermediate-size 1000km-scale Kuiper Belt Object in 3:2 mean-motion resonance with Neptune, in an orbit very similar to that of Pluto. We present visible and near-infrared photometry and spectroscopy obtained with the Keck 10m-telescope and the Gemini 8m-telescope . We confirm the unambiguous detection of crystalline water ice as well as absorption in the 2.2\mu m region. Both in the visible and near-infrared Orcus' spectral properties appear to be homogeneous over time (and probably rotation) at the resolution available. From Hapke radiative transfer models involving intimate mixtures of various ices we find for the first time that ammonium (NH+4) and traces of ethane (C2 H6), which are most probably solar irradiation products of ammonia and methane, and a mixture of methane and ammonia (diluted or not) are the best candidates to improve the description of the data with respect to a simple water ice mixture (Haumea type surface). The possible more subtle structure of the 2.2\mu m band(s) should be investigated thoroughly in the future for Orcus and other intermediate size Plutinos to better understand the methane and ammonia chemistry at work, if any. We investigated the thermal history of Orcus with a new 3D thermal evolution model. Simulations over 4.5 x109 yrs with an input 10% porosity, bulk composition of 23% amorphous water ice and 77% dust, and cold accretion show that even with the action of long-lived radiogenic elements only, Orcus should have a melted core and most probably suffered a cryovolcanic event in its history which brought large amounts of crystalline ice to the surface. The presence of ammonia in the interior would strengthen the melting process. The crystalline water ice possibly brought to the surface by a past cryovolcanic event sbe detectable after several billion years despite the irradiation eects, as demonstrated by recent laboratory experiments.Comment: 15 pages, 9 figure