191 research outputs found
Cyclic Voltammetric Experiment - Simulation. Comparisons of the Complex Mechanism Associated with Electrochemical Reduction of Zr4+ in LiCl-KCl Eutectic Molten Salt
Nuclear energy increasingly represents an important option for generating largely clean CO2-free electricity and zirconium is a fission product that is expected to be present in irradiated fuels. The present investigation addresses the electrochemical reduction of Zr4+ to Zro in LiCl - KCl eutectic molten salt in the temperature range 425–550◦C using cyclic voltammetry (CV), square-wave
voltammetry (SWV) and bulk electrolysis. Simulations of the CV data indicate that the initial reduction proceeds through surface confined steps: Zr4+* + 2e− ↔Zr2+* and Zr2+* + 2e− ↔Zr* processes (* adsorbed species) followed by a peak-shaped complex diffusion controlled step that consists of a combination of closely spaced processes associated with the reactions Zr4+ + 4e− →Zr and Zr4+ + 3e− →Zr+*. Zr+*, probably in the form of ZrCl* is then further reduced to Zro* at even more negative potentials. The
simulations provide the first quantitative analysis of the thermodynamics and kinetics of the Zr4+ reduction in the LiCl-KCl eutectic
Un Spongiaire Sphinctozoaire colonial apparenté aux constructeurs de récifs triasiques survivant dans le bathyal de Nouvelle-Calédonie
Un second représentant actuel des Sphinctozoaires, importants constructeurs de récifs au Permo-Trias, a été découvert dans la zone bathyale de la NouvelleCalédonie. Contrairement au survivant déjà connu, #Valecetia crypta$, il a conservé le mode de croissance colonial et les capacités constructrices de ses analogues fossiles. Sa croissance est bien plus lente que celle des coraux récifaux actuels. La base d'une construction de 10 cm d'épaisseur a été datée de 700 ans. (Résumé d'auteur
Characterisation of the Fusarium graminearum-Wheat Floral Interaction.
PublishedJournal ArticleFusarium Ear Blight is a destructive fungal disease of cereals including wheat and can contaminate the crop with various trichothecene mycotoxins. This investigation has produced a new β-glucuronidase (GUS) reporter strain that facilitates the quick and easy assessment of plant infection. The constitutively expressed gpdA:GUS strain of Fusarium graminearum was used to quantify the overall colonisation pattern. Histochemical and biochemical approaches confirmed, in susceptible wheat ear infections, the presence of a substantial phase of symptomless fungal growth. Separate analyses demonstrated that there was a reduction in the quantity of physiologically active hyphae as the wheat ear infection proceeded. A simplified linear system of rachis infection was then utilised to evaluate the expression of several TRI genes by RT-qPCR. Fungal gene expression at the advancing front of symptomless infection was compared with the origin of infection in the rachis. This revealed that TRI gene expression was maximal at the advancing front and supports the hypothesis that the mycotoxin deoxynivalenol plays a role in inhibiting plant defences in advance of the invading intercellular hyphae. This study has also demonstrated that there are transcriptional differences between the various phases of fungal infection and that these differences are maintained as the infection proceeds.Chinese governmentBritish Society for Plant Pathology (BSPP)BBSRCEU FP 6 Integrated Project BioexploitSyngent
Weak and strong fillability of higher dimensional contact manifolds
For contact manifolds in dimension three, the notions of weak and strong
symplectic fillability and tightness are all known to be inequivalent. We
extend these facts to higher dimensions: in particular, we define a natural
generalization of weak fillings and prove that it is indeed weaker (at least in
dimension five),while also being obstructed by all known manifestations of
"overtwistedness". We also find the first examples of contact manifolds in all
dimensions that are not symplectically fillable but also cannot be called
overtwisted in any reasonable sense. These depend on a higher-dimensional
analogue of Giroux torsion, which we define via the existence in all dimensions
of exact symplectic manifolds with disconnected contact boundary.Comment: 68 pages, 5 figures. v2: Some attributions clarified, and other minor
edits. v3: exposition improved using referee's comments. Published by Invent.
Mat
Cloacal Bacterial Diversity Increases with Multiple Mates: Evidence of Sexual Transmission in Female Common Lizards
Sexually transmitted diseases have often been suggested as a potential cost of multiple mating and as playing a major role in the evolution of mating systems. Yet there is little empirical data relating mating strategies to sexually transmitted microorganisms in wild populations. We investigated whether mating behaviour influences the diversity and composition of cloacal assemblages by comparing bacterial communities in the cloaca of monandrous and polyandrous female common lizards Zootoca vivipara sampled after the mating period. We found that polyandrous females harboured more diverse communities and differed more in community composition than did monandrous females. Furthermore, cloacal diversity and variability were found to decrease with age in polyandrous females. Our results suggest that the higher bacterial diversity found in polyandrous females is due to the sexual transmission of bacteria by multiple mates. The impact of mating behaviour on the cloacal microbiota may have fitness consequences for females and may comprise a selective pressure shaping the evolution of mating systems
Kinetic Theory of Plasmas: Translational Energy
In the present contribution, we derive from kinetic theory a unified fluid
model for multicomponent plasmas by accounting for the electromagnetic field
influence. We deal with a possible thermal nonequilibrium of the translational
energy of the particles, neglecting their internal energy and the reactive
collisions. Given the strong disparity of mass between the electrons and heavy
particles, such as molecules, atoms, and ions, we conduct a dimensional
analysis of the Boltzmann equation. We then generalize the Chapman-Enskog
method, emphasizing the role of a multiscale perturbation parameter on the
collisional operator, the streaming operator, and the collisional invariants of
the Boltzmann equation. The system is examined at successive orders of
approximation, each of which corresponding to a physical time scale. The
multicomponent Navier-Stokes regime is reached for the heavy particles, which
follow a hyperbolic scaling, and is coupled to first order drift-diffusion
equations for the electrons, which follow a parabolic scaling. The transport
coefficients exhibit an anisotropic behavior when the magnetic field is strong
enough. We also give a complete description of the Kolesnikov effect, i.e., the
crossed contributions to the mass and energy transport fluxes coupling the
electrons and heavy particles. Finally, the first and second principles of
thermodynamics are proved to be satisfied by deriving a total energy equation
and an entropy equation. Moreover, the system of equations is shown to be
conservative and the purely convective system hyperbolic, thus leading to a
well-defined structure
Tightness in contact metric 3-manifolds
This paper begins the study of relations between Riemannian geometry and
global properties of contact structures on 3-manifolds. In particular we prove
an analog of the sphere theorem from Riemannian geometry in the setting of
contact geometry. Specifically, if a given three dimensional contact manifold
(M,\xi) admits a complete compatible Riemannian metric of positive 4/9-pinched
curvature then the underlying contact structure \xi is tight; in particular,
the contact structure pulled back to the universal cover is the standard
contact structure on S^3. We also describe geometric conditions in dimension
three for \xi to be universally tight in the nonpositive curvature setting.Comment: 29 pages. Added the sphere theorem, removed high dimensional material
and an alternate approach to the three dimensional tightness radius estimate
Parallelization of a relaxation scheme modelling the bedload transport of sediments in shallow water flow
Detour and break optimising distance, a new perspective on transport and urbanism
International audienceFrom a discussion about the mathematical properties of metrics, we identify three fundamental characteristics of distance, which are optimality, detour and break. We then explore the implications of these properties for transport planning, urbanism and spatial planning. We state that distances contain the idea of optimum and that any distance is associated to a search for optimisation. Pedestrian movements obey this principle and sometimes depart from designed routes. Local sub-optimality conveyed by public transport maps has to be corrected by interventions on public space to relieve the load on central parts of networks. The second principle we state is that detour in distances is most often a means to optimise movement. Fast transport systems generates most of the detour observed in geographical spaces at regional scale. This is why detour has to be taken into account in regional transport policies. The third statement is that breaks in movement contribute to optimising distances. Benches, cafés, pieces of art, railway stations are examples of the urban break. These facilities of break represent an urban paradox: they organise the possibility of a break, of a waste of time in a trip, and they also contribute to optimising distances in a wider network. In that sense break should be considered as a relevant principle for the design of urban space in order to support a pedestrian oriented urban form
Opioid receptors in GtoPdb v.2021.3
Opioid and opioid-like receptors are activated by a variety of endogenous peptides including [Met]enkephalin (met), [Leu]enkephalin (leu), β-endorphin (β-end), α-neodynorphin, dynorphin A (dynA), dynorphin B (dynB), big dynorphin (Big dyn), nociceptin/orphanin FQ (N/OFQ); endomorphin-1 and endomorphin-2 are also potential endogenous peptides. The Greek letter nomenclature for the opioid receptors, μ, δ and κ, is well established, and NC-IUPHAR considers this nomenclature appropriate, along with the symbols spelled out (mu, delta, and kappa), and the acronyms, MOP, DOP, and KOP. [121, 100, 91]. The human N/OFQ receptor, NOP, is considered 'opioid-related' rather than opioid because, while it exhibits a high degree of structural homology with the conventional opioid receptors [294], it displays a distinct pharmacology. Currently there are numerous clinically used drugs, such as morphine and many other opioid analgesics, as well as antagonists such as naloxone, however only for the μ receptor
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