Trace gases and CO2 isotope records from cabo de rama, India

Concentrations of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), nitrous oxide (N2O) and hydrogen (H2), and the stable carbon (δ 13C-CO2) and oxygen (δ 18O-CO2) isotopic composition of CO2 have been measured in air samples collected from Cabo de Rama (CRI), India, for the period 1993-2002. The observations show clear signatures of Northern and Southern Hemispheric (NH and SH) air masses, mixed with their regional fluxes and chemical loss mechanisms, resulting in complex seasonal variation of these gases. The CRI measurements are compared with remote marine sites at Seychelles and Mauna Loa. Simulations of two major anthropogenic greenhouse gases (CO2 and CH4) concentrations using a chemistry-transport model for the CRI site suggest that globally optimized fluxes can produce results comparable to the observations. We discuss that CRI observations have provided critical guidance in optimizing the fluxes to constrain the regional source/sinks balance

Atmospheric methane levels off: Temporary pause or a new steady-state?

[1] The globally-averaged atmospheric methane abundance determined from an extensive network of surface air sampling sites was constant at similar to1751 ppb from 1999 through 2002. Assuming that the methane lifetime has been constant, this implies that during this 4-year period the global methane budget has been at steady state. We also observed a significant decrease in the difference between northern and southern polar zonal annual averages of CH4 from 1991 to 1992. Using a 3-D transport model, we show that this change is consistent with a decrease in CH4 emissions of similar to10 Tg CH4 from north of 50degreesN in the early-1990s. This decrease in emissions may have accelerated the global methane budget towards steady state. Based on current knowledge of the global methane budget and how it has changed with time, it is not possible to tell if the atmospheric methane burden has peaked, or if we are only observing a persistent, but temporary pause in its increase

Uncertainty in temperature projections reduced using carbon cycle and climate observations

The future behaviour of the carbon cycle is a major contributor to uncertainty in temperature projections for the twenty-first century1,2. Using a simplified climate model3, we show that, for a given emission scenario, it is the second most important contributor to this uncertainty after climate sensitivity, followed by aerosol impacts. Historical measurements of carbon dioxide concentrations4 have been used along with global temperature observations5 to help reduce this uncertainty. This results in an increased probability of exceeding a 2 °C global–mean temperature increase by 2100 while reducing the probability of surpassing a 6 °C threshold for non-mitigation scenarios such as the Special Report on Emissions Scenarios A1B and A1FI scenarios6, as compared with projections from the Fourth Assessment Report7 of the Intergovernmental Panel on Climate Change. Climate sensitivity, the response of the carbon cycle and aerosol effects remain highly uncertain but historical observations of temperature and carbon dioxide imply a trade–off between them so that temperature projections are more certain than they would be considering each factor in isolation. As well as pointing out the promise from the formal use of observational constraints in climate projection, this also highlights the need for an holistic view of uncertainty

Sensitivity of atmospheric CO2 growth rate to observed changes in terrestrial water storage

International audienc

Observational determination of surface radiative forcing by CO2 from 2000 to 2010.

The climatic impact of CO2 and other greenhouse gases is usually quantified in terms of radiative forcing, calculated as the difference between estimates of the Earth's radiation field from pre-industrial and present-day concentrations of these gases. Radiative transfer models calculate that the increase in CO2 since 1750 corresponds to a global annual-mean radiative forcing at the tropopause of 1.82 ± 0.19 W m(-2) (ref. 2). However, despite widespread scientific discussion and modelling of the climate impacts of well-mixed greenhouse gases, there is little direct observational evidence of the radiative impact of increasing atmospheric CO2. Here we present observationally based evidence of clear-sky CO2 surface radiative forcing that is directly attributable to the increase, between 2000 and 2010, of 22 parts per million atmospheric CO2. The time series of this forcing at the two locations-the Southern Great Plains and the North Slope of Alaska-are derived from Atmospheric Emitted Radiance Interferometer spectra together with ancillary measurements and thoroughly corroborated radiative transfer calculations. The time series both show statistically significant trends of 0.2 W m(-2) per decade (with respective uncertainties of ±0.06 W m(-2) per decade and ±0.07 W m(-2) per decade) and have seasonal ranges of 0.1-0.2 W m(-2). This is approximately ten per cent of the trend in downwelling longwave radiation. These results confirm theoretical predictions of the atmospheric greenhouse effect due to anthropogenic emissions, and provide empirical evidence of how rising CO2 levels, mediated by temporal variations due to photosynthesis and respiration, are affecting the surface energy balance