64 research outputs found
Magnetic Tilting in Nematic Liquid Crystals Driven by Self‐Assembly
Self-assembly is one of the crucial mechanisms allowing the design multifunctional materials. Soft hybrid materials contain components of different natures and exhibit competitive interactions which drive self-organization into structures of a particular function. Here a novel type of a magnetic hybrid material where the molecular tilt can be manipulated through a delicate balance between the topologically-assisted colloidal self-assembly of magnetic nanoparticles and the anisotropic molecular interactions in a liquid crystal matrix is demonstrated
Electroreflectance characterization of AlInGaN/GaN high-electron mobility heterostructures
Room temperature electroreflectance (ER) spectroscopy has been used to study the fundamental properties of AlxInyGaN/AlN/GaN heterostructures under different applied bias. The (0001)-oriented heterostructures were grown by metal-organic vapor phase epitaxy on sapphire. The band gap energy of the AlxInyGa layers has been determined from analysis of the ER spectra using Aspnes' model. The obtained values are in good agreement with a nonlinear band gap interpolation equation proposed earlier. Bias-dependent ER allows one to determine the sheet carrier density of the two-dimensional electron gas and the barrier field strength
Применение метода Гаусса для решения системы линейных алгебраических уравнений больших размерностей в кластерных системах
Материалы IX Междунар. межвуз. науч.-техн. конф. студентов, магистрантов и аспирантов,Гомель, 28–29 апр. 2009 г
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Optical properties of In2O3 from experiment and first-principles theory: influence of lattice screening
The framework of many-body perturbation theory led to deep insight into electronic structure and optical properties of diverse systems and, in particular, many semiconductors. It relies on an accurate approximation of the screened Coulomb electron–electron interaction W, that in current implementations is usually achieved by describing electronic interband transitions. However, our results for several oxide semiconductors indicate that for polar materials it is necessary to also account for lattice contributions to dielectric screening. To clarify this question in this work, we combine highly accurate experimentation and cutting-edge theoretical spectroscopy to elucidate the interplay of quasiparticle and excitonic effects for cubic bixbyite In2O3 across an unprecedentedly large photon energy range. We then show that the agreement between experiment and theory is excellent and, thus, validate that the physics of quasiparticle and excitonic effects is described accurately by these first-principles techniques, except for the immediate vicinity of the absorption onset. Finally, our combination of experimental and computational data clearly establishes the need for including a lattice contribution to dielectric screening in the screened electron–electron interaction, in order to improve the description of excitonic effects near the absorption edge
Luminescence from two-dimensional electron gases in InAlN/GaN heterostructures with different In content
The luminescence properties of InxAl1−xN/GaN heterostructures are investigated systematically as a function of the In content (x = 0.067 − 0.208). The recombination between electrons confined in the two-dimensional electron gas and free holes in the GaN template is identified and analyzed. We find a systematic shift of the recombination with increasing In content from about 80 meV to only few meV below the GaN exciton emission. These results are compared with model calculations and can be attributed to the changing band profile and originating from the polarization gradient between InAlN and GaN
In-situ study and modeling of the reaction kinetics during molecular beam epitaxy of GeO2 and its etching by Ge
Rutile GeO2 has been predicted to be an ultra-wide bandgap semiconductor
suitable for future power electronics devices while quartz-like GeO2 shows
piezoelectric properties. To explore these crystalline phases for application
and fundamental materials investigations, molecular beam epitaxy (MBE) is a
well-suited thin film growth technique. In this study, we investigate the
reaction kinetics of GeO2 during plasma-assisted MBE using elemental Ge and
plasma-activated oxygen fluxes. The growth rate as a function of oxygen flux is
measured in-situ by laser reflectometry at different growth temperatures. A
flux of the suboxide GeO desorbing off the growth surface is identified and
quantified in-situ by the line-of-sight quadrupole mass spectrometry. Our
measurements reveal that the suboxide formation and desorption limits the
growth rate under metal-rich or high temperature growth conditions, and leads
to etching of the grown GeO2 layer under Ge flux in the absence of oxygen. The
quantitative results fit the sub-compound mediated reaction model, indicating
the intermediate formation of the suboxide at the growth front. This model is
further utilized to delineate the GeO2-growth window in terms of oxygen-flux
and substrate temperature. Our study can serve as a guidance for the thin film
synthesis of GeO2 and defect-free mesa etching in future GeO2-device
processing
Epitaxial synthesis of unintentionally doped p-type SnO (001) via suboxide molecular beam epitaxy
By employing a mixed SnO+Sn source, we demonstrate suboxide molecular
beam epitaxy growth of phase-pure single crystalline metastable SnO(001) thin
films at a growth rate of ~1.0nm/min without the need for additional oxygen.
These films grow epitaxially across a wide substrate temperature range from 150
to 450{\deg}C. Hence, we present an alternative pathway to overcome the
limitations of high Sn or SnO cell temperatures and narrow growth windows
encountered in previous MBE growth of metastable SnO. In-situ laser
reflectometry and line-of-sight quadrupole mass spectrometry were used to
investigate the rate of SnO desorption as a function of substrate temperature.
While SnO ad-molecules desorption at Ts = 450{\deg}C was growth-rate
limiting,the SnO films did not desorb at this temperature after growth in
vacuum. The SnO (001) thin films are transparent and unintentionally p-type
doped, with hole concentrations and mobilities in the range of 0.9 to
6.0x10cm and 2.0 to 5.5 cm/V.s, respectively. These p-type
SnO films obtained at low temperatures are promising for back-end-of-line
(BEOL) compatible applications and for integration with n-type oxides in p-n
heterojunction and field-effect transistorsComment: 18 pages, 10 figure
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Epitaxial synthesis of unintentionally doped p-type SnO (001) via suboxide molecular beam epitaxy
By employing a mixed SnO2 + Sn source, we demonstrate suboxide molecular beam epitaxy (S-MBE) growth of phase-pure single-crystalline metastable SnO (001) thin films on Y-stabilized ZrO2 (001) substrates at a growth rate of ∼1.0 nm/min without the need for additional oxygen. These films grow epitaxially across a wide substrate temperature range from 150 to 450 °C. Hence, we present an alternative pathway to overcome the limitations of high Sn or SnO2 cell temperatures and narrow growth windows encountered in previous MBE growth of metastable SnO. In situ laser reflectometry and line-of-sight quadrupole mass spectrometry were used to investigate the rate of SnO desorption as a function of substrate temperature. While SnO ad-molecule desorption at TS = 450 °C was growth-rate limiting, the SnO films did not desorb at this temperature after growth in vacuum. The SnO (001) thin films are transparent and unintentionally p-type doped, with hole concentrations and mobilities in the range of 0.9-6.0 × 1018 cm-3 and 2.0-5.5 cm2 V-1 s-1, respectively. These p-type SnO films obtained at low substrate temperatures are promising for back-end-of-line (BEOL) compatible applications and for integration with n-type oxides in pn heterojunctions and field-effect transistors
Origin of defect luminescence in ultraviolet emitting AlGaN diode structures.
Light emitting diode structures emitting in the ultraviolet spectral range are investigated. The samples exhibit defect luminescence bands. Synchrotron-based photoluminescence excitation spectroscopy of the complicated multi-layer stacks is employed to assign the origin of the observed defect luminescence to certain layers. In the case of quantum well structures emitting at 320 and 290 nm, the n-type contact AlGaN:Si layer is found to be the origin of defect luminescence bands between 2.65 and 2.8 eV. For 230 nm emitters without such n-type contact layer, the origin of a defect double structure at 2.8 and 3.6 eV can be assigned to the quantum wells.
A part of this research was carried out at the light source DORIS III at DESY. DESY is a member of the Helmholtz Association (HGF). We would like to thank A. Kotlov for excellent assistance in using beamline I at DESY. This work was partially supported by the Federal Ministry of Education and Research (BMBF), under Contract No. 13N9933 and Berlin WideBase initiative under Contract No. 03WKBT01D and the German Research Council within the Collaborative Research Center 787.pre-print465 K
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