322 research outputs found

    Critical velocity for a toroidal Bose-Einstein condensate flowing through a barrier

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    We consider the setup employed in a recent experiment (Ramanathan et al 2011 Phys. Rev. Lett. 106 130401) devoted to the study of the instability of the superfluid flow of a toroidal Bose-Einstein condensate in presence of a repulsive optical barrier. Using the Gross-Pitaevskii mean-field equation, we observe, consistently with what we found in Piazza et al (2009 Phys. Rev. A 80 021601), that the superflow with one unit of angular momentum becomes unstable at a critical strength of the barrier, and decays through the mechanism of phase slippage performed by pairs of vortex-antivortex lines annihilating. While this picture qualitatively agrees with the experimental findings, the measured critical barrier height is not very well reproduced by the Gross-Pitaevskii equation, indicating that thermal fluctuations can play an important role (Mathey et al 2012 arXiv:1207.0501). As an alternative explanation of the discrepancy, we consider the effect of the finite resolution of the imaging system. At the critical point, the superfluid velocity in the vicinity of the obstacle is always of the order of the sound speed in that region, vbarr=clv_{\rm barr}=c_{\rm l}. In particular, in the hydrodynamic regime (not reached in the above experiment), the critical point is determined by applying the Landau criterion inside the barrier region. On the other hand, the Feynman critical velocity vfv_{\rm f} is much lower than the observed critical velocity. We argue that this is a general feature of the Gross-Pitaevskii equation, where we have vf=ϵ clv_{\rm f}=\epsilon\ c_{\rm l} with ϵ\epsilon being a small parameter of the model. Given these observations, the question still remains open about the nature of the superfluid instability.Comment: Extended versio

    FlyRNAi.org—the database of the Drosophila RNAi screening center: 2012 update

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    FlyRNAi (http://www.flyrnai.org), the database and website of the Drosophila RNAi Screening Center (DRSC) at Harvard Medical School, serves a dual role, tracking both production of reagents for RNA interference (RNAi) screening in Drosophila cells and RNAi screen results. The database and website is used as a platform for community availability of protocols, tools, and other resources useful to researchers planning, conducting, analyzing or interpreting the results of Drosophila RNAi screens. Based on our own experience and user feedback, we have made several changes. Specifically, we have restructured the database to accommodate new types of reagents; added information about new RNAi libraries and other reagents; updated the user interface and website; and added new tools of use to the Drosophila community and others. Overall, the result is a more useful, flexible and comprehensive website and database

    Benzofuran-fused Phosphole: Synthesis, Electronic, and Electroluminescence Properties

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    International audienceA synthetic route to novel benzofuran-fused phosphole derivatives 3-5 is described. These compounds showed optical and electrochemical properties that differ from their benzothiophene analog. Preliminary results show that 4 can be used as an emitter in OLEDs, illustrating the potential of these new compounds for opto-electronic applications

    Cancer Appetite and Symptom Questionnaire (CASQ) for Brazilian Patients: Cross-Cultural Adaptation and Validation Study

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    Background Appetite and symptoms, conditions generally reported by the patients with cancer, are somewhat challenging for professionals to measure directly in clinical routine (latent conditions). Therefore, specific instruments are required for this purpose. This study aimed to perform a cultural adaptation of the Cancer Appetite and Symptom Questionnaire (CASQ), into Portuguese and evaluate its psychometric properties on a sample of Brazilian cancer patients. Methods This is a validation study with Brazilian cancer patients. The face, content, and construct (factorial and convergent) validities of the Cancer Appetite and Symptom Questionnaire, the study tool, were estimated. Further, a confirmatory factor analysis (CFA) was conducted. The ratio of chi-square and degrees of freedom (χ2 /df), comparative fit index (CFI), goodness of fit index (GFI) and root mean square error of approximation (RMSEA) were used for fit model assessment. In addition, the reliability of the instrument was estimated using the composite reliability (CR) and Cronbach’s alpha coefficient (α), and the invariance of the model in independent samples was estimated by a multigroup analysis (Δχ2). Results Participants included 1,140 cancer patients with a mean age of 53.95 (SD = 13.25) years; 61.3% were women. After the CFA of the original CASQ structure, 2 items with inadequate factor weights were removed. Four correlations between errors were included to provide adequate fit to the sample (χ2 /df = 8.532, CFI = .94, GFI = .95, and RMSEA = .08). Themodel exhibited a low convergent validity (AVE = .32). The reliability was adequate (CR = .82 α = .82). The refined model showed strong invariance in two independent samples (Δχ2 : λ: p = .855; i: p = .824; Res: p = .390). A weak stability was obtained between patients undergoing chemotherapy and radiotherapy (Δχ2 : λ: p = .155; i: p < .001; Res: p < .001), and between patients undergoing chemotherapy combined with radiotherapy and palliative care (Δχ2 : λ: p = .058; i: p < .001; Res: p < .001). Conclusion The Portuguese version of the CASQ had good face and construct validity and reliability. However, the CASQ still presented invariance in independent samples of Brazilian patients with cancer. However, the tool has low convergent validity and weak invariance in samples with different treatment

    Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel SBUs upon Hydration

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    Instability of most prototypical metal organic frameworks (MOFs) in the presence of moisture is always a limita- tion for industrial scale development. In this work, we examine the dissociation mechanism of microporous paddle wheel frameworks M(bdc)(ted)0.5 [M=Cu, Zn, Ni, Co; bdc= 1,4-benzenedicarboxylate; ted= triethylenediamine] in controlled humidity environments. Combined in-situ IR spectroscopy, Raman, and Powder x-ray diffraction measurements show that the stability and modification of isostructual M(bdc)(ted)0.5 compounds upon exposure to water vapor critically depend on the central metal ion. A hydrolysis reaction of water molecules with Cu-O-C is observed in the case of Cu(bdc)(ted)0.5. Displacement reactions of ted linkers by water molecules are identified with Zn(bdc)(ted)0.5 and Co(bdc)(ted)0.5. In contrast,. Ni(bdc)(ted)0.5 is less suscept- ible to reaction with water vapors than the other three compounds. In addition, the condensation of water vapors into the framework is necessary to initiate the dissociation reaction. These findings, supported by supported by first principles theoretical van der Waals density functional (vdW-DF) calculations of overall reaction enthalpies, provide the necessary information for de- termining operation conditions of this class of MOFs with paddle wheel secondary building units and guidance for developing more robust units

    InfoSyll: A Syllabary Providing Statistical Information on Phonological and Orthographic Syllables

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    here is now a growing body of evidence in various languages supporting the claim that syllables are functional units of visual word processing. In the perspective of modeling the processing of polysyllabic words and the activation of syllables, current studies investigate syllabic effects with subtle manipulations. We present here a syllabary of the French language aiming at answering new constraints when designing experiments on the syllable issue. The InfoSyll syllabary provides exhaustive characteristics and statistical information for each phonological syllable (e.g. /fi/) and for its corresponding orthographic syllables (e.g. fi, phi, phy, fee, fix, fis). Variables such as the type and token positional frequencies, the number and frequencies of the correspondences between orthographic and phonological syllables are provided. As discussed, such computations should allow precise controls, manipulations and quantitative descriptions of syllabic variables in the field of psycholinguistic research.SCOPUS: ar.jinfo:eu-repo/semantics/publishe
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