A domain of spacetime intervals in general relativity

Beginning from only a countable dense set of events and the causality relation, it is possible to reconstruct a globally hyperbolic spacetime in a purely order theoretic manner. The ultimate reason for this is that globally hyperbolic spacetimes belong to a category that is equivalent to a special category of domains called interval domains.Comment: 25 page

Infrared gluons, intrinsic transverse momentum and rising total cross-sections

We discuss the infrared limit for soft gluon kt-resummation and relate it to physical observables such as the intrinsic transverse momentum and the high energy limit of total cross-sections.Comment: 8 pages, 6 figures, Presented at Hadron Structure '09, Tatranska Strba, September 2009, Slovacchia, to be published in the Conference Proceeding

Site-selective introduction of thiols in unprotected glycosides

Thioglycosides or S-linked-glycosides are important glycomimetics. These thioglycosides are often prepared by glycosylating deoxythio sugar acceptors, which are synthesized via elaborate protecting group manipulations. We discovered that a carbonyl group, formed by site-selective oxidation of unprotected saccharides, can be converted into a thiol moiety. The transformation involves SN1-substitution of a chloro-azo intermediate, formed by oxidation of the corresponding trityl hydrazone, with a thiol. The prepared deoxythio sugars provide, in combination with the recently developed protecting group-free glycosylation of glycosyl fluorides, a protecting group-free synthesis of thioglycosides.</p

From Problems to Potentials - The Urban Energy Transition of Gruž, Dubrovnik

In the challenge for a sustainable society, carbon-neutrality is the critical objective for all cities in the coming decades. In the EU City-zen project, academic partners collaborate to develop an urban energy transition methodology, which supports cities in making the energy transition to sustainable lifestyles and carbon neutrality. As part of the project, so-called Roadshows are organised in cities that wish to take the first step toward zero-energy living. Each Roadshow being methodologically composed to allow sustainability experts from across Europe to co-create designs, strategies and timelines with local stakeholders in order to reach this vital goal. Following a precursory investigative student workshop (the SWAT Studio) Dubrovnik would be third city to host the Roadshow in November 2016. During these events the characteristics of Dubrovnik, and the district of Gruž in particular, were systematically analysed, leading to good insights into the current problems and potentials of the city. In close collaboration with local stakeholders, the team proposed a series of interventions that would help make Gruž, and in its wake the whole city of Dubrovnik, net zero energy and zero carbon, by validation of carbon emission calculations. The vision presented to the inhabitants and its key city decision makers encompassed a pathway towards an attainable sustainable future. The strategies and solutions proposed for the Dubrovnik district of Gruž turned out to be capable of reducing the current carbon sequestration compensation of 1,200 hectares of forestland to 67 hectares only, an area achievable by urban reforestation projects. This paper presents the City-zen methodology of urban energy transition and that of the City-zen Roadshow, the analysis of the city of Dubrovnik, proposed interventions and the carbon impact, as calculated by means of a carbon accounting method discussed in the paper

Relocating croplands could drastically reduce the environmental impacts of global food production

Agricultural production has replaced natural ecosystems across the planet, becoming a major driver of carbon emissions, biodiversity loss, and freshwater consumption. Here we combined global crop yield and environmental data in a ~1-million-dimensional mathematical optimisation framework to determine how optimising the spatial distribution of global croplands could reduce environmental impacts whilst maintaining current crop production levels. We estimate that relocating current croplands to optimal locations, whilst allowing ecosystems in then-abandoned areas to regenerate, could simultaneously decrease the current carbon, biodiversity, and irrigation water footprint of global crop production by 71%, 87%, and 100%, respectively, assuming high-input farming on newly established sites. The optimal global distribution of crops is largely similar for current and end-of-century climatic conditions across emission scenarios. Substantial impact reductions could already be achieved by relocating only a small proportion of worldwide crop production, relocating croplands only within national borders, and assuming less intensive farming systems. © 2022, The Author(s)R.M.B. and A.M. were supported by ERC Consolidator Grant 647797 “LocalAdaptation”. This work benefited from conversations with América P. Durán, Catherine Tayleur, Sharon E. Brooks, David Coomes, Paul F. Donald, and Fiona J. Sanderson during a separate research projec

The Tevatron Higgs exclusion limits and theoretical uncertainties: a critical appraisal

We examine the exclusion limits set by the CDF and D0 experiments on the Standard Model Higgs boson mass from their searches at the Tevatron in the light of large theoretical uncertainties on the signal and background cross sections. We show that when these uncertainties are consistently taken into account, the sensitivity of the experiments becomes significantly lower and the currently excluded mass range $M_H=158$-175 GeV would be entirely reopened. The necessary luminosity required to recover the current sensitivity is found to be a factor of two higher than the present one.Comment: 11 pages, 5 Figures. Version published in Physics Letter B, including an erratu

Nutritional status of Lusitano broodmares on extensive feeding systems: body condition, live weight and metabolic indicators

Articles in International JournalsThe present research aimed to evaluate the effects of foaling season and feeding management in extensive systems on the nutritional status of Lusitano broodmares throughout the gestation/lactation cycle, by assessment of body condition (BC), body weight (BW), and some blood metabolic indicators. Four groups of Lusitano broodmares (A, B, C, D) were monitored during four years, in a total of 119 gestation/lactation cycles. All mares were kept on pasture, and A and B mares were daily supplemented. Monthly, mares were weighed and BC evaluated. Suckling foals from these mares were also monitored for BW and withers height. Glucose, non-esterified fatty acids, urea and albumin concentrations were determined in blood. BW changes were influenced by reproductive stage and foaling season (P<0.001), reflecting also pasture availability. Changes on BC were observed (P<0.05), although with small amplitudes within each group. Higher scores were reached at the end of spring, decreasing 0.25 point until late summer. Early foaling had also a marked effect, hindering the recovery of BC along the cycle. Glucose values decreased from late gestation to early lactation (P<0.05) and lower levels were recorded during the summer months. Uremia was mainly influenced by the reproductive stage (P<0.05). Under nutrition was not detected. Foals born in February-March had higher average daily gain than those born in April-May (P<0.05), probably reflecting differences in milk production of the mares. BC and BW changes and, particularly, blood indicators showed an overall balanced nutritional status, reflecting an adaptation to feed availability and climate.Portuguese Foundation for Science and Technolog

Impact of 2050 climate change on North American wildfire: consequences for ozone air quality

We estimate future area burned in the Alaskan and Canadian forest by the mid-century (2046–2065) based on the simulated meteorology from 13 climate models under the A1B scenario. We develop ecoregion-dependent regressions using observed relationships between annual total area burned and a suite of meteorological variables and fire weather indices, and apply these regressions to the simulated meteorology. We find that for Alaska and western Canada, almost all models predict significant (p < 0.05) increases in area burned at the mid-century, with median values ranging from 150 to 390 %, depending on the ecoregion. Such changes are attributed to the higher surface air temperatures and 500 hPa geopotential heights relative to present day, which together lead to favorable conditions for wildfire spread. Elsewhere the model predictions are not as robust. For the central and southern Canadian ecoregions, the models predict increases in area burned of 45–90 %. Except for the Taiga Plain, where area burned decreases by 50 %, no robust trends are found in northern Canada, due to the competing effects of hotter weather and wetter conditions there. Using the GEOS-Chem chemical transport model, we find that changes in wildfire emissions alone increase mean summertime surface ozone levels by 5 ppbv for Alaska, 3 ppbv for Canada, and 1 ppbv for the western US by the mid-century. In the northwestern US states, local wildfire emissions at the mid-century enhance surface ozone by an average of 1 ppbv, while transport of boreal fire pollution further degrades ozone air quality by an additional 0.5 ppbv. The projected changes in wildfire activity increase daily summertime surface ozone above the 95th percentile by 1 ppbv in the northwestern US, 5 ppbv in the high latitudes of Canada, and 15 ppbv in Alaska, suggesting a greater frequency of pollution episodes in the future atmosphere

Impact of 2050 climate change on North American wildfire: consequences for ozone air quality

We estimate future area burned in the Alaskan and Canadian forest by the mid-century (2046–2065) based on the simulated meteorology from 13 climate models under the A1B scenario. We develop ecoregion-dependent regressions using observed relationships between annual total area burned and a suite of meteorological variables and fire weather indices, and apply these regressions to the simulated meteorology. We find that for Alaska and western Canada, almost all models predict significant (p < 0.05) increases in area burned at the mid-century, with median values ranging from 150 to 390 %, depending on the ecoregion. Such changes are attributed to the higher surface air temperatures and 500 hPa geopotential heights relative to present day, which together lead to favorable conditions for wildfire spread. Elsewhere the model predictions are not as robust. For the central and southern Canadian ecoregions, the models predict increases in area burned of 45–90 %. Except for the Taiga Plain, where area burned decreases by 50 %, no robust trends are found in northern Canada, due to the competing effects of hotter weather and wetter conditions there. Using the GEOS-Chem chemical transport model, we find that changes in wildfire emissions alone increase mean summertime surface ozone levels by 5 ppbv for Alaska, 3 ppbv for Canada, and 1 ppbv for the western US by the mid-century. In the northwestern US states, local wildfire emissions at the mid-century enhance surface ozone by an average of 1 ppbv, while transport of boreal fire pollution further degrades ozone air quality by an additional 0.5 ppbv. The projected changes in wildfire activity increase daily summertime surface ozone above the 95th percentile by 1 ppbv in the northwestern US, 5 ppbv in the high latitudes of Canada, and 15 ppbv in Alaska, suggesting a greater frequency of pollution episodes in the future atmosphere

Prompt atmospheric neutrinos and muons: dependence on the gluon distribution function

We compute the next-to-leading order QCD predictions for the vertical flux of atmospheric muons and neutrinos from decays of charmed particles, for different PDF's (MRS-R1, MRS-R2, CTEQ-4M and MRST) and different extrapolations of these at small partonic momentum fraction x. We find that the predicted fluxes vary up to almost two orders of magnitude at the largest energies studied, depending on the chosen extrapolation of the PDF's. We show that the spectral index of the atmospheric leptonic fluxes depends linearly on the slope of the gluon distribution function at very small x. This suggests the possibility of obtaining some bounds on this slope in ``neutrino telescopes'', at values of x not reachable at colliders, provided the spectral index of atmospheric leptonic fluxes could be determined.Comment: 20 pages including 8 figure