Proton magnetic resonance and polarographic studies of some aminated naphthoquinones

Variable temperature n.m.r. and polarographic measurements have been performed on a series of cyclic secondary aminonaphthoquinones. The results indicate that ring strain is not the only factor which would explain the order of effective electron donation by the various amines to the quinone nucleus

Instantons in N=2{\cal N}=2 Sp(N)Sp(N) Superconformal Gauge Theories and the AdS/CFT Correspondence

We study, using ADHM construction, instanton effects in an {\CN}=2 superconformal $Sp(N)$ gauge theory, arising as effective field theory on a system of $N$ D-3-branes near an orientifold 7-plane and 8 D-7-branes in type I' string theory. We work out the measure for the collective coordinates of multi-instantons in the gauge theory and compare with the measure for the collective coordinates of $(-1)$-branes in the presence of 3- and 7-branes in type I' theory. We analyse the large-N limit of the measure and find that it admits two classes of saddle points: In the first class the space of collective coordinates has the geometry of $AdS_5\times S^3$ which on the string theory side has the interpretation of the D-instantons being stuck on the 7-branes and therefore the resulting moduli space being $AdS_5\times S^3$, In the second class the geometry is $AdS_5\times S^5/Z_2$ and on the string theory side it means that the D-instantons are free to move in the 10-dimensional bulk. We discuss in detail a correlator of four O(8) flavour currents on the Yang-Mills side, which receives contributions from the first type of saddle points only, and show that it matches with the correlator obtained from $F^4$ coupling on the string theory side, which receives contribution from D-instantons, in perfect accord with the AdS/CFT correspondence. In particular we observe that the sectors with odd number of instantons give contribution to an O(8)-odd invariant coupling, thereby breaking O(8) down to SO(8) in type I' string theory. We finally discuss correlators related to $R^4$, which receive contributions from both saddle points.Comment: 28 pages, no figures, typos corrected, a reference adde

Local costs of conservation exceed those borne by the global majority

Cost data are crucial in conservation planning to identify more efficient and equitable land use options. However, many studies focus on just one cost type and neglect others, particularly those borne locally. We develop, for a high priority conservation area, spatial models of two local costs that arise from protected areas: foregone agricultural opportunities and increased wildlife damage. We then map these across the study area and compare them to the direct costs of reserve management, finding that local costs exceed management costs. Whilst benefits of conservation accrue to the global community, significant costs are borne by those living closest. Where livelihoods depend upon opportunities forgone or diminished by conservation intervention, outcomes are limited. Activities can be displaced (leakage); rules can be broken (intervention does not work); or the intervention forces a shift in livelihood profiles (potentially to the detriment of local peoples’ welfare). These raise concerns for both conservation and development outcomes and timely consideration of local costs is vital in conservation planning tools and processes

Remarks on self-interaction correction to black hole radiation

In the work [P. Kraus and F. Wilczek, \textit{Self-interaction correction to black hole radiation, Nucl. Phys.} B433 (1995) 403], it has been pointed out that the self-gravitation interaction would modify the black hole radiation so that it is no longer thermal, where it is, however, corrected in an approximate way and therefore is not established its relationship with the underlying unitary theory in quantum theory. In this paper, we revisit the self-gravitation interaction to Hawking radiation of the general spherically symmetric black hole, and find that the precisely derived spectrum is not only deviated from the purely thermal spectrum, but most importantly, is related to the change of the Bekenstein-Hawking entropy and consistent with an underlying unitary theory.Comment: 14 page

On the universality of anomalous one-dimensional heat conductivity

In one and two dimensions, transport coefficients may diverge in the thermodynamic limit due to long--time correlation of the corresponding currents. The effective asymptotic behaviour is addressed with reference to the problem of heat transport in 1d crystals, modeled by chains of classical nonlinear oscillators. Extensive accurate equilibrium and nonequilibrium numerical simulations confirm that the finite-size thermal conductivity diverges with the system size $L$ as $\kappa \propto L^\alpha$. However, the exponent $\alpha$ deviates systematically from the theoretical prediction $\alpha=1/3$ proposed in a recent paper [O. Narayan, S. Ramaswamy, Phys. Rev. Lett. {\bf 89}, 200601 (2002)].Comment: 4 pages, submitted to Phys.Rev.

Dissociating the semantic function of two neighbouring subregions in the left lateral anterior temporal lobe

AbstractWe used fMRI in 35 healthy participants to investigate how two neighbouring subregions in the lateral anterior temporal lobe (LATL) contribute to semantic matching and object naming. Four different levels of processing were considered: (A) recognition of the object concepts; (B) search for semantic associations related to object stimuli; (C) retrieval of semantic concepts of interest; and (D) retrieval of stimulus specific concepts as required for naming. During semantic association matching on picture stimuli or heard object names, we found that activation in both subregions was higher when the objects were semantically related (mug–kettle) than unrelated (car–teapot). This is consistent with both LATL subregions playing a role in (C), the successful retrieval of amodal semantic concepts. In addition, one subregion was more activated for object naming than matching semantically related objects, consistent with (D), the retrieval of a specific concept for naming. We discuss the implications of these novel findings for cognitive models of semantic processing and left anterior temporal lobe function

Constraining the primordial spectrum of metric perturbations from gravitino and moduli production

We consider the production of gravitinos and moduli fields from quantum vacuum fluctuations induced by the presence of scalar metric perturbations at the end of inflation. We obtain the corresponding occupation numbers, up to first order in perturbation theory, in terms of the power spectrum of the metric perturbations. We compute the limits imposed by nucleosynthesis on the spectral index $n_s$ for different models with constant $n_s$. The results show that, in certain cases, such limits can be as strong as $n_s<1.12$, which is more stringent than those coming from primordial black hole production.Comment: 16 pages, LaTeX, 5 figures. Corrected figures, new references included. Final version to appear in Phys. Rev.

High-resolution maps show that rubber causes substantial deforestation

Understanding the effects of cash crop expansion on natural forest is of fundamental importance. However, for most crops there are no remotely sensed global maps1, and global deforestation impacts are estimated using models and extrapolations. Natural rubber is an example of a principal commodity for which deforestation impacts have been highly uncertain, with estimates differing more than fivefold1,2,3,4. Here we harnessed Earth observation satellite data and cloud computing5 to produce high-resolution maps of rubber (10 m pixel size) and associated deforestation (30 m pixel size) for Southeast Asia. Our maps indicate that rubber-related forest loss has been substantially underestimated in policy, by the public and in recent reports6,7,8. Our direct remotely sensed observations show that deforestation for rubber is at least twofold to threefold higher than suggested by figures now widely used for setting policy4. With more than 4 million hectares of forest loss for rubber since 1993 (at least 2 million hectares since 2000) and more than 1 million hectares of rubber plantations established in Key Biodiversity Areas, the effects of rubber on biodiversity and ecosystem services in Southeast Asia could be extensive. Thus, rubber deserves more attention in domestic policy, within trade agreements and in incoming due-diligence legislation

String Theory, Unification and Quantum Gravity

An overview is given of the way in which the unification program of particle physics has evolved into the proposal of superstring theory as a prime candidate for unifying quantum gravity with the other forces and particles of nature. A key concern with quantum gravity has been the problem of ultraviolet divergences, which is naturally solved in string theory by replacing particles with spatially extended states as the fundamental excitations. String theory turns out, however, to contain many more extended-object states than just strings. Combining all this into an integrated picture, called M-theory, requires recognition of the r\^ole played by a web of nonperturbative duality symmetries suggested by the nonlinear structures of the field-theoretic supergravity limits of string theory.Comment: 29 pages, 13 figures, 3 tables; Lectures given at the 6th Aegean Summer School "Quantum Gravity and Quantum Cosmology", Chora, Naxos Island, Greece, 12-17 September 201

До питання підготовки музейної експозиції з історії культури первісного суспільства

In Europe, water management is moving from flood defense to a risk management approach, which takes both the probability and the potential consequences of flooding into account. In this report, we will look at Directives and (non-)EU- initiatives in place to deal with flood risk in Europe indirectly and directly. Emphasis will lie on the two Directives most specifically aimed at floods: the Water Framework Directive (WFD) and the Floods Directive (FD) – how are they related and how they have been or are implemented in the Member States (MSs)? In February 1995, the Netherlands and France took the initiative for a discussion on streamlining the water legislation of the European Union (EU) which resulted in the creation of the WFD in 2000. The WFD provided a new system for the protection and improvement of Europe’s water environment – its rivers, lakes, estuaries, coastal waters and groundwaters. Its main innovation is the requirement that water be managed in an integrated way, with river basin management as leading managing unit. Since flood protection is not explicitly addressed in the WFD, the need to clarify the role of the WFD in flood protection was put on the European agenda as early as 2003, and in 2007, the FD became a fact. The FD is to be implemented in coordination with the WFD, notably by coordinating Flood Risk Management Plans (FRMPs) and River Basin Management Plans (RBMPs). Both the WFD and the FD reflect a shift in EU-governance. Instead of the more traditional top-down legalistic approach they emphasise the importance of more bottom up initiatives from the actors who have to implement the Directives. Combined with the expanded freedom and flexibility for national and local governments, with this new approach, the FD is the first Water Directive in EU law that does not offer an equal minimum level of protection for EU citizens. While both Directives are meant to harmonise European legislation, much flexibility on objectives and measures in the FD is left to the MSs, justified by the nature of flooding and the subsidiarity principle. This creates multi-actor, multi-level and multi-sector challenges addressed in report D1.1.2 (Hegger et al. 2013). For instance, the FD sets out general obligations for transboundary cooperation, but at the national level, the scope and distributions of duties, rights and powers of the various organizations involved should be set out in law. Other challenges identified in the literature are concrete issues related to mandatory flood risks assessments, flood risk maps, and Flood Risk Management plans, but also the involvement of the public and stakeholders, the science-policy interface, uncertainties related to climate change predictions and effects, the coordination with the WFD, the lack of safety standards, the lack of possibilities for EU citizens to rely on substantive provisions before the administrative courts and finally, transboundary aspects such as issues of scale, mismatches between national policies, the assessment of transboundary effects and division of costs related to this. In sum, this report has clarified the development, content and implementation of the current European flood risk governance policies, possible synergies between the two most important Directives linked to floods, and identified topics and questions for more in-depth questions relevant for the next work packages, pertaining to, in no particular order, a) the level of implementation and level of ambition as well as the competent authorities in the case study countries; b) the transboundary nature of floods; c) synergies and conflicts between FD and WFD and other issues not mentioned in these Directives; d) the degree of harmonization, for instance when it comes to flood safety standards and e) the subsidiarity principle – is this conform the requirements set out in the FD? Because while current European flood regulation specified in the WFD and FD provides several potential opportunities for improving flood risk governance, it is not self-evident that all of these opportunities will materialise in all MSs