21,934 research outputs found

    Magnetic transitions in Pr2NiO4 single crystal

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    The magnetic properties of a stoichiometric Pr2NiO4 single crystal have been examined by means of the temperature dependence of the complex ac susceptibility and the isothermal magnetization in fields up to 200 kOe at T=4.2 K. Three separate phases have been identified and their anisotropic character has been analyzed. A collinear antiferromagnetic phase appears first between TN = 325 K and Tc1 = 115 K, where the Pr ions are polarized by an internal magnetic field. At Tc1 a first modification of the magnetic structure occurs in parallel with a structural phase transition (Bmab to P42/ncm). This magnetic transition has a first‐order character and involves both the out‐of‐plane and the in‐plane spin components (magnetic modes gx and gxcyfz, respectively). A second magnetic transition having also a first‐order character is also clearly identified at Tc2 = 90 K which corresponds to a spin reorientation process (gxcyfz to cxgyaz magnetic modes). It should be noted as well that the out‐of‐phase component of χac shows a peak around 30 K which reflects the coexistence of both magnetic configurations in a wide temperature interval. Finally, two field‐induced transitions have been observed at 4.2 K when the field is directed along the c axis. We propose that the high‐field anomaly arises from a metamagnetic transition of the weak ferromagnetic component, similarly to La2CuO4

    The gaseous extent of galaxies and the origin of Lyman alpha absorption systems. IV: Lyman alpha absorbers arising in a galaxy group

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    We present new GHRS observations of Lyman alpha absorption lines associated with a group of galaxies towards the QSO 1545+2101. We have identified eight distinct Lyman alpha absorption features in the spectrum of QSO 1545+2101 at a mean redshift of z=0.2648 with a velocity dispersion of 163 km/s. A group of galaxies is detected in the vicinity of this QSO at a mean redshift of z=0.2645 and velocity dispersion 239 km/s. The identification of discrete absorption systems indicates that they arise in clouds of neutral hydrogen rather than in a diffuse intragroup medium. Our analysis suggests that the Lyman alpha absorption lines are associated with individual galaxies in the group, although a one-to-one relationship between absorbers and galaxies is difficult to establish in such a dense environment.Comment: 16 pages, 3 figures. Accepted for publication in Ap

    Unexpected differences between thermal and photoinitiated cationic curing of a diglycidyl ether of bisphenol A modified with a multiarm star poly(styrene)-b-poly(ε-caprolactone) polymer

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    The effect of adding a multiarm star poly(styrene)-b-poly(ε-caprolactone) polymer on the cationic thermal and photoinitiated curing of diglycidyl ether of bisphenol A was studied. This star-polymer decelerated the thermal curing of diglycidyl ether of bisphenol A and modified the final structure of the epoxy matrix. The photocuring was influenced significantly by the addition of the multiarm star. When the proportion of this modifier added was 5%, much more time was necessary for complete photocuring (160 min at 40ºC). In the presence of 10% of modifier, the degree of photocuring reached was very low (0.196 at 120°C). A subsequent thermal post-curing was necessary to cure completely the system. During photocuring in presence of poly(styrene)-b-poly(ε-caprolactone), the formation of dormant species, which are reactivated when the temperature increases, takes places. The kinetics of the thermal curing and the photocuring was analyzed using an isoconversional method due to the complexity of the reactive process. Applying this method, it has been confirmed the dependence of activation energy on the degree of conversion. The fracture morphology analyzed by scanning electron microscopy exhibited a second phase originated during photocuring by the presence of the modifier

    Bs0η()η()B_s^0 \to \eta^{(\prime)} \eta^{(\prime)} decays in the pQCD approach

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    We calculate the CP averaged branching ratios and CP-violating asymmetries for Bs0ηη,ηηB_s^0 \to \eta \eta, \eta \eta^\prime and ηη\eta^\prime \eta^\prime decays in the perturbative QCD (pQCD) approach here. The pQCD predictions for the CP-averaged branching ratios are Br(B_s^0 \to \eta \eta) = \left (14.2^{+18.0}_{-7.5}) \times 10^{-6}, Br(B_s^0 \to \eta \eta^\prime)= \left (12.4 ^{+18.2}_{-7.0}) \times 10^{-6}, and Br(B_s^0 \to \eta^{\prime} \eta^{\prime}) = \left (9.2^{+15.3}_{-4.9}) \times 10^{-6}, which agree well with those obtained by employing the QCD factorization approach and also be consistent with available experimental upper limits. The gluonic contributions are small in size: less than 7% for BsηηB_s \to \eta \eta and ηη \eta \eta^\prime decays, and around 18% for BsηηB_s \to \eta' \eta' decay. The CP-violating asymmetries for three decays are very small: less than 3% in magnitude.Comment: 11 pages, 1 ps figure, Revte

    Influence of adsorption and anaerobic granular sludge characteristics on long chain fatty acids inhibition process

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    The impact of LCFA adsorption on the methanogenic activity was evaluated in batch assays for two anaerobic granular sludges in the presence and absence of bentonite as synthetic adsorbent. A clear inhibitory effect at an oleate (C18:1) concentration of 0.5 g(C18:1) L(-1) was observed for both sludges. Palmitate (C16:0) was confirmed to be the main intermediate of C18:1 degradation in not adapted sludge and its accumulation was further evidenced by fluorescence staining and microscopy techniques. LCFA inhibition could be decreased by the addition of bentonite, reducing the lag-phase and accelerating the kinetics of LCFA degradation, concluding in the importance of the adsorptive nature of the LCFA inhibitory process. Granule morphology and molecular profiling of predominant microorganisms revealed that biomass adaptation to LCFA could modify the intermediates accumulation profiles and process rates.This work was funded by the Spanish Ministry of Science and Innovation (projects ENE 2007-65850 and CTM 2010-18212), and was partially supported by a grand from the Department of Universities, Research and Media Society of Catalonia Government (BE-DGR 2008 BE1 00261). We would like to thank Lucia Neves, Ana Nicolau, Madalena Vieira, and Ana Julia Cavaleiro, from University of Minho, for their assistance in microscopic observations and analytical methods. We also thank Miriam Guivernau (IRTA) for assistance in the PCR-DGGE profiling and ribotype sequencing. We are also grateful to David Bedoya (MWH) and Francesc Prenafeta (IRTA) for the revision and critical reading of the manuscript

    Reducing the risk of heart disease among Indian Australians: knowledge, attitudes, and beliefs regarding food practices - a focus group study

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    BACKGROUND: Australia has a growing number of Asian Indian immigrants. Unfortunately, this population has an increased risk for coronary heart disease (CHD). Dietary adherence is an important strategy in reducing risk for CHD. This study aimed to gain greater understanding of the knowledge, attitudes and beliefs relating to food practices in Asian Indian Australians. METHODS: Two focus groups with six participants in each were recruited using a convenience sampling technique. Verbatim transcriptions were made and thematic content analysis undertaken. RESULTS: Four main themes that emerged from the data included: migration as a pervasive factor for diet and health; importance of food in maintaining the social fabric; knowledge and understanding of health and diet; and elements of effective interventions. DISCUSSION: Diet is a complex constructed factor in how people express themselves individually, in families and communities. There are many interconnected factors influencing diet choice that goes beyond culture and religion to include migration and acculturation. CONCLUSIONS: Food and associated behaviors are an important aspect of the social fabric. Entrenched and inherent knowledge, attitudes, beliefs and traditions frame individuals\u27 point of reference around food and recommendations for an optimal diet

    Crystal-fields in YbInNi4 determined with magnetic form factor and inelastic neutron scattering

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    The magnetic form factor of YbInNi4 has been determined via the flipping ratios R with polarized neutron diffraction and the scattering function S(Q,w) was measured in an inelastic neutron scattering experiment. Both experiments were performed with the aim to determine the crystal-field scheme. The magnetic form factor clearly excludes the possibility of a \Gamma7 doublet as the ground state. The inelastic neutron data exhibit two, almost equally strong peaks at 3.2 meV and 4.4 meV which points, in agreement with earlier neutron data, towards a \Gamma8 quartet ground state. Further possibilities like a quasi-quartet ground state are discussed.Comment: 7 pages, 5 figures, 2 tables, submitted to PR
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