The Feasibility of Reclaiming Shell Material from Investment Casting

This report examines the feasibility of investment shell component reclamation. Shell material components and their compositions are investigated with an industry survey, a study of the available literature, and analysis of specimen shell materials. physical properties and factors related to the reclamation and reuse of shell materials are described. Well known mineral processing methods are capable of producing concentrates of the various shell components. The theory and techniques of some applicable processes are discussed to assist with the development of reclamation operations. The recommended methods are; comminution by roll crushing, component concentration by screening, gravity settling or heavy medium separation. Aluminosilicate stucco (a major component of many investment shells) can be recovered in a form suitable for reuse as backup stucco. Zircon (a minor component in many shell compositions) -can be concentrated in an impure form, and subsequent caustic liberation treatments can remove the intermixed silica phases. Reuse of such zircon in investment casting may be possible but will require careful qualification testing. Fused and crystalline silica (major components of most shell compositions) are not reusable for investment casting. The feasibility of reclamation will be influenced by individual foundry choices of materials, composition and shell practice.HWRIC Project No. RRT-10NTIS PB92-16219

Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs

The modular synthesis of a series of nitrogen-rich polydentate ligands that feature a common pincer-type framework is reported. These ligands allow for site-selective installation of palladium and platinum to give rise to bi- and trimetallic complexes that have d^(8)–d^(8) interactions

An ab-initio study of the electron-phonon coupling within a Cr(001)-surface

It is experimentally well established that the Cr(001)-surface exhibits a sharp resonance around the Fermi level. However, there is no consensus about its physical origin. It is proposed to be either due to a single particle dz2 surface state renormalised by electron-phonon coupling or the orbital Kondo effect involving the degenerate dxz/dyz states. In this work we examine the electron-phonon coupling of the Cr(001)-surface by means of ab-initio calculations in the form of density functional perturbation theory. More precisely, the electron-phonon mass-enhancement factor of the surface layer is investigated for the 3d states. For the majority and minority spin dz2 surface states we find values of 0.19 and 0.16. We show that these calculated electron-phonon mass-enhancement factors are not in agreement with the experimental data even if we use realistic values for the temperature range and surface Debye frequency for the fit of the experimental data. More precisely, then experimentally an electron-phonon mass-enhancement factor of 0.70~0.10 is obtained, which is not in agreement with our calculated values of 0.19 and 0.16. Therefore, we conclude that the experimentally observed resonance at the Cr(001)-surface is not due to polaronic effects, but due to electron-electron correlation effects

Estimating normal mixture parameters from the distribution of a reduced feature vector

A FORTRAN computer program was written and tested. The measurements consisted of 1000 randomly chosen vectors representing 1, 2, 3, 7, and 10 subclasses in equal portions. In the first experiment, the vectors are computed from the input means and covariances. In the second experiment, the vectors are 16 channel measurements. The starting covariances were constructed as if there were no correlation between separate passes. The biases obtained from each run are listed

Fractal Markets Hypothesis and the Global Financial Crisis: Scaling, Investment Horizons and Liquidity

We investigate whether fractal markets hypothesis and its focus on liquidity and invest- ment horizons give reasonable predictions about dynamics of the financial markets during the turbulences such as the Global Financial Crisis of late 2000s. Compared to the mainstream efficient markets hypothesis, fractal markets hypothesis considers financial markets as com- plex systems consisting of many heterogenous agents, which are distinguishable mainly with respect to their investment horizon. In the paper, several novel measures of trading activity at different investment horizons are introduced through scaling of variance of the underlying processes. On the three most liquid US indices - DJI, NASDAQ and S&P500 - we show that predictions of fractal markets hypothesis actually fit the observed behavior quite well.Comment: 11 pages, 3 figure

Capturing, using, and managing quality assurance knowledge for shuttle post-MECO flight design

Ascent initialization values used by the Shuttle's onboard computer for nominal and abort mission scenarios are verified by a six degrees of freedom computer simulation. The procedure that the Ascent Post Main Engine Cutoff (Post-MECO) group uses to perform quality assurance (QA) of the simulation is time consuming. Also, the QA data, checklists and associated rationale, though known by the group members, is not sufficiently documented, hindering transfer of knowledge and problem resolution. A new QA procedure which retains the current high level of integrity while reducing the time required to perform QA is needed to support the increasing Shuttle flight rate. Documenting the knowledge is also needed to increase its availability for training and problem resolution. To meet these needs, a knowledge capture process, embedded into the group activities, was initiated to verify the existing QA checks, define new ones, and document all rationale. The resulting checks were automated in a conventional software program to achieve the desired standardization, integrity, and time reduction. A prototype electronic knowledge base was developed with Macintosh's HyperCard to serve as a knowledge capture tool and data storage

Spin effects in gravitational radiation backreaction II. Finite mass effects

A convenient formalism for averaging the losses produced by gravitational radiation backreaction over one orbital period was developed in an earlier paper. In the present paper we generalize this formalism to include the case of a closed system composed from two bodies of comparable masses, one of them having the spin S. We employ the equations of motion given by Barker and O'Connell, where terms up to linear order in the spin (the spin-orbit interaction terms) are kept. To obtain the radiative losses up to terms linear in the spin, the equations of motion are taken to the same order. Then the magnitude L of the angular momentum L, the angle kappa subtended by S and L and the energy E are conserved. The analysis of the radial motion leads to a new parametrization of the orbit. From the instantaneous gravitational radiation losses computed by Kidder the leading terms and the spin-orbit terms are taken. Following Apostolatos, Cutler, Sussman and Thorne, the evolution of the vectors S and L in the momentary plane spanned by these vectors is separated from the evolution of the plane in space. The radiation-induced change in the spin is smaller than the leading-order spin terms in the momentary angular momentum loss. This enables us to compute the averaged losses in the constants of motion E, L and L_S=L cos kappa. In the latter, the radiative spin loss terms average to zero. An alternative description using the orbital elements a,e and kappa is given. The finite mass effects contribute terms, comparable in magnitude, to the basic, test-particle spin terms in the averaged losses.Comment: 12 pages, 1 figure, Phys.Rev.D15, March, 199

BBO and the Neutron-Star-Binary Subtraction Problem

The Big Bang Observer (BBO) is a proposed space-based gravitational-wave (GW) mission designed primarily to search for an inflation-generated GW background in the frequency range 0.1-1 Hz. The major astrophysical foreground in this range is gravitational radiation from inspiraling compact binaries. This foreground is expected to be much larger than the inflation-generated background, so to accomplish its main goal, BBO must be sensitive enough to identify and subtract out practically all such binaries in the observable universe. It is somewhat subtle to decide whether BBO's current baseline design is sufficiently sensitive for this task, since, at least initially, the dominant noise source impeding identification of any one binary is confusion noise from all the others. Here we present a self-consistent scheme for deciding whether BBO's baseline design is indeed adequate for subtracting out the binary foreground. We conclude that the current baseline should be sufficient. However if BBO's instrumental sensitivity were degraded by a factor 2-4, it could no longer perform its main mission. It is impossible to perfectly subtract out each of the binary inspiral waveforms, so an important question is how to deal with the "residual" errors in the post-subtraction data stream. We sketch a strategy of "projecting out" these residual errors, at the cost of some effective bandwidth. We also provide estimates of the sizes of various post-Newtonian effects in the inspiral waveforms that must be accounted for in the BBO analysis.Comment: corrects some errors in figure captions that are present in the published versio

Nonconventional screening of the Coulomb interaction in FexOy clusters: An ab-initio study

From microscopic point-dipole model calculations of the screening of the Coulomb interaction in non-polar systems by polarizable atoms, it is known that screening strongly depends on dimensionality. For example, in one dimensional systems the short range interaction is screened, while the long range interaction is anti-screened. This anti-screening is also observed in some zero dimensional structures, i.e. molecular systems. By means of ab-initio calculations in conjunction with the random-phase approximation (RPA) within the FLAPW method we study screening of the Coulomb interaction in FexOy clusters. For completeness these results are compared with their bulk counterpart magnetite. It appears that the onsite Coulomb interaction is very well screened both in the clusters and bulk. On the other hand for the intersite Coulomb interaction the important observation is made that it is almost contant throughout the clusters, while for the bulk it is almost completely screened. More precisely and interestingly, in the clusters anti-screening is observed by means of ab-initio calculations