141 research outputs found
Modified torsion coefficients for a 3-D brick Cosserat point element
A simple deformation field associated with an exact torsion-like solution of the equilibrium equations of linear elasticity is shown to provide a good approximation of the deformation field in interior elements of a mesh that models pure torsion of a right cylindrical bar with rectangular cross-section. Using this solution, modified torsion coefficients are proposed for a 3-D brick Cosserat point element (CPE) which are shown to improve convergence properties for solutions of pure torsio
An Aminopyrrolidinyl PhosphonatesâA New Class of Antibiotics: Facile Synthesis and Predicted Biological Activity
A novel class of aminopyrrolidinyl phosphonates was synthesized in 74% -
80% isolated yield by the addition of three-fold excess of primary amines to
diethyl 4-chloro-1-butynylphosphonates. The reaction was carried out at
room temperature and in the absence of solvent or catalyst to give solely
compounds which showed predicted biological activity based on PASS program.
Some of the synthesized derivatives of antibiotics exhibit properties for
the treatment of stroke, the treatment of acute neurological disorders, and
can also be acetyl esterase inhibitors
The determinants of social sustainability in work integration social enterprises: the effect of entrepreneurship
Work integration social enterprises (WISEs) exist to fight poverty and social exclusion. They offer support and guidance to those at risk of exclusion to help these individuals join the labour market. This study examines the relationship between social enterprises (specifically, work integration social enterprises) and their social impact, considered here in the form of social sustainability. This article presents the results of empirical analysis of 62 Spanish work integration social enterprises using fuzzy-set qualitative comparative analysis. The article focuses on the entrepreneurial characteristics of the companiesâ founders and managers as drivers of social value creation. Specifically, the study examines their entrepreneurial traits, capabilities, orientation, and behaviour. The results show the importance of the training that social entrepreneurs receive, as well as the structure and planning of social enterprises
Urban land planning: The role of a Master Plan in influencing local temperatures
Land use planning (LUP) is central for managing issues related to climatic variation in urban environments. However, Master Plans (MPs) usually do not include climatic aspects, and few studies have addressed climate change at the urban scale, especially in developing countries. This paper proposes a framework with ten categories for assessment of climatic variation in urban LUP. Each category comprises attributes that describe a complex of relationships in influencing local temperature variations. They are analyzed for the case of the Master Plan of Porto Alegre (MPPA), the Southernmost metropolis of Brazil. It is concluded that the MPPA is strongly grounded in climate-related land and zoning coordination, but exhibits weaknesses in building, cartographical and social aspects considered synergistically relevant for tackling problems related to urban climate variation. Furthermore, the MPPA does not contain provisions related to monitoring of local climate and greenhouse gases (GHG) emissions and it is ineffective for improving energy efficiency. Specific MPPA failures stemming from these weaknesses include: an increase of 21.79% in the city's urbanized area from 1986 to 2011 to accommodate a similar increase in population, with significant horizontal sprawl; average temperature rise of 0.392. °C from 1991-2000 to 2001-2010, with statistically significant increases in temperature found since 1931; significant vehicle traffic increases, especially since 2007. From these findings, it is possible to conclude that the MPPA does not offer answers to all the imbalances related to land use, and therefore gives insufficient support to tackle the issue of rising temperatures
Does the planning system in England deliver a sustainable and resilient built environment? A study of the experience of town planners
The case has been made in the reports of the Intergovernmental Panel on Climate Changes for the crucial role of the built environment in mitigating the worst excesses of a warming global climate and in protecting people through adaptation. Town planners are essential actors in delivering sustainable and resilient urbanism. Given that legislation is implemented by people, the study aimed to examine how town planners experienced and thought about the changing legislation and how they understood the concepts of âsustainabilityâ and âresilienceâ in the built environment. Semi-structured interviews were conducted with 19 planners working in England who had at least seven yearsâ experience. In the analysis, we explored meanings of sustainability and of resilience, and how these concepts were seen as incorporated in legislation. Sustainability was seen by the participants as embedded in regulations but its realisation varied substantially. Tensions were evident between the three pillars of environment, society and economy. âResilienceâ as a concept was poorly understood and legislative support was patchy at best: while flooding features extensively in local plans, wider issues of climate impact such as overheating are not comprehensively addressed. The conclusions are that planners are often frustrated in their attempts to develop a more sustainable built environment and that the current planning system is inadequate to deliver consistently sustainable and resilient outcomes. However, alignment between sustainability goals and professional identity were also noted, offering avenues to explore beyond the institutional constraints of legislation
Activism and Legitimation in Israel's Jurisprudence of Occupation
Colonial law need not exclude the colonized in order to subordinate them, and âactivistâ courts can advance the effect of subordination no less than âpassiveâ courts. As a case study, this article examines the jurisprudential legacy of the Israeli Supreme Court in the context of the prolonged Israeli occupation of Palestine. Applying insights from legal realist, law and society, and critical legal studies scholarship, the article questions the utility of using the activist and passive labels. It illustrates how the Israeli activist court, through multiple legal and discursive moves, has advanced and legitimated the colonization of Palestine; that the court is aware of its role; and that arguments that focus on the courtâs informal role do not mitigate this legitimating effect. Unlike other scholars, the article shows that the Israeli courtâs roleâby extending the power of judicial review to the militaryâs actions in the occupied areasâis neither novel nor unique or benevolent, as the British colonization of India and the US colonization of Puerto Rico show
A model for the compressible, viscoelastic behavior of human amnion addressing tissue variability through a single parameter
A viscoelastic, compressible model is proposed to rationalize the recently reported response of human amnion in multiaxial relaxation and creep experiments. The theory includes two viscoelastic contributions responsible for the short- and long-term time- dependent response of the material. These two contributions can be related to physical processes: water flow through the tissue and dissipative characteristics of the collagen fibers, respectively. An accurate agreement of the model with the mean tension and kinematic response of amnion in uniaxial relaxation tests was achieved. By variation of a single linear factor that accounts for the variability among tissue samples, the model provides very sound predictions not only of the uniaxial relaxation but also of the uniaxial creep and strip-biaxial relaxation behavior of individual samples. This suggests that a wide range of viscoelastic behaviors due to patient-specific variations in tissue composition
Modelling Co-Creation Ecosystem for Public Open Spaces
Co-creation can be defined as the involvement of citizens in the
initiation and/or the design process of public services in order to (co)create
beneficial outcomes and value for society. Mediated public open spaces are ideal
environments for co-creation to emerge due to the involvement of the community
and ICT in the knowledge creation. The aims of the research presented
in the chapter are two-fold: to conduct a mapping activity in order to collect the
insights on civic technologies promoting the creation of open public spaces
through the use of ICT and to define the critical dimensions in designing cocreative
ecosystems. The mapping strategy was conducted by evaluating the
civic technologies in Lithuania and Bulgaria. The insights from the empirical
exercise allow to draw managerial and organizational recommendations for
strengthening the collective efforts of citizens, IT developers, public and governmental
institutions in creating open, inclusive and reflective open public
spaces
A people-centred perspective on climate change, environmental stress, and livelihood resilience in Bangladesh
The GangesâBrahmaputra delta enables Bangladesh to sustain a dense population, but it also exposes people to natural hazards. This article presents findings from the Gibika project, which researches livelihood resilience in seven study sites across Bangladesh. This study aims to understand how people in the study sites build resilience against environmental stresses, such as cyclones, floods, riverbank erosion, and drought, and in what ways their strategies sometimes fail. The article applies a new methodology for studying peopleâs decision making in risk-prone environments: the personal Livelihood History interviews (N = 28). The findings show how environmental stress, shocks, and disturbances affect peopleâs livelihood resilience and why adaptation measures can be unsuccessful. Floods, riverbank erosion, and droughts cause damage to agricultural lands, crops, houses, and properties. People manage to adapt by modifying their agricultural practices, switching to alternative livelihoods, or using migration as an adaptive strategy. In the coastal study sites, cyclones are a severe hazard. The study reveals that when a cyclone approaches, people sometimes choose not to evacuate: they put their lives at risk to protect their livelihoods and properties. Future policy and adaptation planning must use lessons learned from people currently facing environmental stress and shocks
Effects of composition and transesterification catalysts on the physico-chemical and dynamic properties of PC/PET blends rich in PC
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