Neutrino physics with multi-ton scale liquid xenon detectors

We study the sensitivity of large-scale xenon detectors to low-energy solar neutrinos, to coherent neutrino-nucleus scattering and to neutrinoless double beta decay. As a concrete example, we consider the xenon part of the proposed DARWIN (Dark Matter WIMP Search with Noble Liquids) experiment. We perform detailed Monte Carlo simulations of the expected backgrounds, considering realistic energy resolutions and thresholds in the detector. In a low-energy window of 2-30 keV, where the sensitivity to solar pp and $^7$Be-neutrinos is highest, an integrated pp-neutrino rate of 5900 events can be reached in a fiducial mass of 14 tons of natural xenon, after 5 years of data. The pp-neutrino flux could thus be measured with a statistical uncertainty around 1%, reaching the precision of solar model predictions. These low-energy solar neutrinos will be the limiting background to the dark matter search channel for WIMP-nucleon cross sections below $\sim$2$\times$10$^{-48}$ cm$^2$ and WIMP masses around 50 GeV$\cdot$c$^{-2}$, for an assumed 99.5% rejection of electronic recoils due to elastic neutrino-electron scatters. Nuclear recoils from coherent scattering of solar neutrinos will limit the sensitivity to WIMP masses below $\sim$6 GeV$\cdot$c$^{-2}$ to cross sections above $\sim$4$\times$10$^{-45}$cm$^2$. DARWIN could reach a competitive half-life sensitivity of 5.6$\times$10$^{26}$ y to the neutrinoless double beta decay of $^{136}$Xe after 5 years of data, using 6 tons of natural xenon in the central detector region.Comment: 17 pages, 4 figure

Scintillation efficiency of liquid argon in low energy neutron-argon scattering

Experiments searching for weak interacting massive particles with noble gases such as liquid argon require very low detection thresholds for nuclear recoils. A determination of the scintillation efficiency is crucial to quantify the response of the detector at low energy. We report the results obtained with a small liquid argon cell using a monoenergetic neutron beam produced by a deuterium-deuterium fusion source. The light yield relative to electrons was measured for six argon recoil energies between 11 and 120 keV at zero electric drift field.Comment: 21 pages, 19 figures, 4 table

Circular solar: Evaluating the profitability of a photovoltaic panel recycling plant

Photovoltaic (PV) panels have a crucial role in coping with the global warming mitigation and the energetic crisis currently affecting the European Community. However, from the circular perspective of end-of-life (EoL) management, there are still big issues to be solved in order to recover materials from this kind of e-wastes. Because of several reasons (e.g. type of embedded materials, illegal shipments, location of manufacturers) EoL businesses do not have the interest in approaching them. This poses a significant environmental concern in terms of their management. This work wants to assess the profitability of a specific PV module recycling plant, by evaluating several market contexts in which multiple scenarios of material price, investment and process costs will be considered. The results for a 3000 tonnes plant show that profitability is not verified in the absence of an avoided landfill cost. Instead, when a value of 200 euro/tonnes is applied, the net present value is positive in 35.2% of the scenarios and at 87.6% when a value of 350 euro/tonnes is considered. The policy choice of this value requires linking the PV module disposal fee to the circular benefits associated with its recovery

A feasibility study for a circular approach in oil refining: Metals recovery from hydrodesulphurization catalysts

The paper deals with a profitability analysis developed for a plant that recycles spent hydrodesulphurization (HDS) catalysts. Such catalysts contain molybdenum (Mo), nickel (Ni), and vanadium (V), supported by an alumina (Al2O3) carrier. The recycling process is based on a double thermal pre-treatment stage, followed by a series of hydrometallurgical steps that allow recovering Mo and V and a Ni concentrate that need further refining for separation and recovery of the metals. The economic analysis is based on the discounted cash flow method, and the baseline case analyses show that the net present value (NPV) is 14,877 thousand EUR. The selling price of vanadium pentoxide strongly influences the results. Alternative scenarios are also studied to strengthen the results obtained, considering the sensitivity, scenario and risk analyses. Profitability is confirmed in 87% of the considered scenarios, and in about 81.5%, the NPV of the baseline scenario is achieved. Circular economy models can be realized if products are recovered and if there are technologies that can recover metals. This study confirms that an example of a circular economy is met from the proposed viability analysis, and the economic benefits can be significant

Gator: a low-background counting facility at the Gran Sasso Underground Laboratory

A low-background germanium spectrometer has been installed and is being operated in an ultra-low background shield (the Gator facility) at the Gran Sasso underground laboratory in Italy (LNGS). With an integrated rate of ~0.16 events/min in the energy range between 100-2700 keV, the background is comparable to those of the world's most sensitive germanium detectors. After a detailed description of the facility, its background sources as well as the calibration and efficiency measurements are introduced. Two independent analysis methods are described and compared using examples from selected sample measurements. The Gator facility is used to screen materials for XENON, GERDA, and in the context of next-generation astroparticle physics facilities such as DARWIN.Comment: 14 pages, 6 figures, published versio

Design of a mobile neutron spectrometer for the Laboratori Nazionali del Gran Sasso (LNGS)

Environmental neutrons are a source of background for rare event searches (e.g., dark matter direct detection and neutrinoless double beta decay experiments) taking place in deep underground laboratories. The overwhelming majority of these neutrons are produced in the cavern walls by means of intrinsic radioactivity of the rock and concrete. Their flux and spectrum depend on time and location. Precise knowledge of this background is necessary to devise sufficient shielding and veto mechanisms, improving the sensitivity of the neutron-susceptible underground experiments. In this report, we present the design and the expected performance of a mobile neutron detector for the LNGS underground laboratory. The detector is based on capture-gated spectroscopy technique and comprises essentially a stack of plastic scintillator bars wrapped with gadolinium foils. The extensive simulation studies demonstrate that the detector will be capable of measuring ambient neutrons at low flux levels (~$10^{-6}$ n/cm$^2$/s) at LNGS, where the ambient gamma flux is by about 5 orders of magnitude larger

Study of nuclear recoils in liquid argon with monoenergetic neutrons

For the development of liquid argon dark matter detectors we assembled a setup in the laboratory to scatter neutrons on a small liquid argon target. The neutrons are produced mono-energetically (E_kin=2.45 MeV) by nuclear fusion in a deuterium plasma and are collimated onto a 3" liquid argon cell operating in single-phase mode (zero electric field). Organic liquid scintillators are used to tag scattered neutrons and to provide a time-of-flight measurement. The setup is designed to study light pulse shapes and scintillation yields from nuclear and electronic recoils as well as from {\alpha}-particles at working points relevant to dark matter searches. Liquid argon offers the possibility to scrutinise scintillation yields in noble liquids with respect to the populations of the two fundamental excimer states. Here we present experimental methods and first results from recent data towards such studies.Comment: 9 pages, 8 figures, proceedings of TAUP 2011, to be published in Journal of Physics: Conference Series (JCPS

Effect of Crude Oil Vanadyl Porphyrin Content and Blending on Heat Exchanger Fouling

Fouling in the pre-heat train of crude oil distillation unit is a normal occurrence in oil refineries. With the increasing trend of heavy crude oil processing, blending of oils becomes a norm practice in a refinery. Fouling could be enhanced if incompatible oils were blended together. Also, heavy oils typically contain high trace metals composition and their effect towards fouling is yet to be explored. This study has been looking into the effect of changes in the original composition and inter-molecular stability of crude oils towards fouling. A batch system was designed and developed to produce a deposit sample from 3 crude oils of industrial interest. The reactor was successfully commissioned and an operating procedure was established. In the first part of the work, various concentrations of Vanadium were added to crude oils and subjected to high temperature in the test section. The resultant deposits and liquid products were analysed for their molecular structure and weight distribution. Analysis by Inductively Coupled Plasma Mass Spectrometer (ICP-MS) shows the added Vanadium are largely concentrated in the deposits. The amount of deposits produced increases with the concentration of Vanadium in the original samples. Analyses by Size Exclusion Chromatogram (SEC), Gas Chromatography (GC) and UV-Fluorescence Spectroscopy (UVF) show larger and more complex molecules in deposits from oils with high concentration of Vanadium. In the second part, the compatibility regions of crude oil blends were established prior to analysis in the reactor. More deposits were produced from incompatible oil blends though these were lighter and less complex than that of compatible blends. Also, oils that were blended from the incompatible region produced deposits of bigger molecular weight distributions and more complex structures. Results of Thermo-Gravimetric Analysis (TGA) confirmed those of SEC’s and UVF’s of which more volatile components were recorded in active blended deposit samples.Open Acces

Adsorption of CO2 by synthetic zeolites

The paper reports on a possible way to recycle fluid catalytic cracking catalysts (FCCCs), widely used in oil refining operations. This research proposes a novel approach that leads to a near zero-waste process. The spent FCCC was leached by 1.5 mol/L of HNO3, HCl and H2SO4 solutions at 80°C, for 3 h with a solid to liquid ratio of 20 %wt/vol. The leaching yields for cerium and lanthanum were in the range 69-82 %. The solid residues from the leaching stage were used as base material for the synthesis of the zeolites by means of a combined thermal-hydrothermal treatment. The characterization of the zeolites demonstrated that the Na-A phase was predominant over the Na-X phase. The zeolites were tested as sorbent material for CO2 separation from CH4, in order to simulate the upgrading of biogas to biomethane. The maximum adsorption rate of CO2 was 0.778 mol CO2/kg of zeolite at 3 bar, with a resulting CH4 recovery of 62 % and purity of 97 %vol. The zeolites synthesized from spent FCCC represent a feasible solution to recover such industrial waste

3D Position Sensitive XeTPC for Dark Matter Search

The technique to realize 3D position sensitivity in a two-phase xenon time projection chamber (XeTPC) for dark matter search is described. Results from a prototype detector (XENON3) are presented.Comment: Presented at the 7th UCLA Symposium on "Sources and Detection of Dark Matter and Dark Energy in the Universe