103 research outputs found
A schlieren method for ultra-low angle light scattering measurements
We describe a self calibrating optical technique that allows to perform
absolute measurements of scattering cross sections for the light scattered at
extremely small angles. Very good performances are obtained by using a very
simple optical layout similar to that used for the schlieren method, a
technique traditionally used for mapping local refraction index changes. The
scattered intensity distribution is recovered by a statistical analysis of the
random interference of the light scattered in a half-plane of the scattering
wave vectors and the main transmitted beam. High quality data can be obtained
by proper statistical accumulation of scattered intensity frames, and the
static stray light contributions can be eliminated rigorously. The
potentialities of the method are tested in a scattering experiment from non
equilibrium fluctuations during a free diffusion experiment. Contributions of
light scattered from length scales as long as Lambda=1 mm can be accurately
determined.Comment: 7 pages, 3 figure
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Salinity Gradients for Sustainable Energy: Primer, Progress, and Prospects
Combining two solutions of different composition releases the Gibbs free energy of mixing. By using engineered processes to control the mixing, chemical energy stored in salinity gradients can be harnessed for useful work. In this critical review, we present an overview of the current progress in salinity gradient power generation, discuss the prospects and challenges of the foremost technologies â pressure retarded osmosis (PRO), reverse electrodialysis (RED), and capacitive mixing (CapMix) and provide perspectives on the outlook of salinity gradient power generation. Momentous strides have been made in technical development of salinity gradient technologies and field demonstrations with natural and anthropogenic salinity gradients (for example, seawaterâriver water and desalination brine-wastewater, respectively), but fouling persists to be a pivotal operational challenge that can significantly ebb away cost-competitiveness. Natural hypersaline sources (e.g., hypersaline lakes and salt domes) can achieve greater concentration difference and, thus, offer opportunities to overcome some of the limitations inherent to seawaterâriver water. Technological advances needed to fully exploit the larger salinity gradients are identified. While seawater desalination brine is a seemingly attractive high salinity anthropogenic stream that is otherwise wasted, actual feasibility hinges on the appropriate pairing with a suitable low salinity stream. Engineered solutions are foulant-free and can be thermally regenerative for application in low-temperature heat utilization. Alternatively, PRO, RED, and CapMix can be coupled with their analog separation process (reverse osmosis, electrodialysis, and capacitive deionization, respectively) in salinity gradient flow batteries for energy storage in chemical potential of the engineered solutions. Rigorous techno-economic assessments can more clearly identify the prospects of low-grade heat conversion and large-scale energy storage. While research attention is squarely focused on efficiency and power improvements, efforts to mitigate fouling and lower membrane and electrode cost will be equally important to reduce levelized cost of salinity gradient energy production and, thus, boost PRO, RED, and CapMix power generation to be competitive with other renewable technologies. Cognizance of the recent key developments and technical progress on the different technological fronts can help steer the strategic advancement of salinity gradient as a sustainable energy source
Shear-induced quench of long-range correlations in a liquid mixture
A static correlation function of concentration fluctuations in a (dilute)
binary liquid mixture subjected to both a concentration gradient and uniform
shear flow is investigated within the framework of fluctuating hydrodynamics.
It is shown that a well-known long-range correlation at
large wave numbers crosses over to a weaker divergent one for wave numbers
satisfying , while an asymptotic shear-controlled
power-law dependence is confirmed at much smaller wave numbers given by , where , , and are the
mass concentration, the rate of the shear, the mass diffusivity and the
kinematic viscosity of the mixture, respectively. The result will provide for
the first time the possibility to observe the shear-induced suppression of a
long-range correlation experimentally by using, for example, a low-angle light
scattering technique.Comment: 8pages, 2figure
Variability of selected trace elements of different meat cuts determined by ICP-MS and DRC-ICPMS
The aim of this study was to determine the levels of cadmium, lead, iron, zinc, selenium, manganese, copper and molybdenum in different cuts of beef, pork, lamb, chicken and foal collected from supermarkets and butcheries in Switzerland. The concentrations of manganese, copper, molybdenum, zinc, iron, selenium, cadmium and lead were determined by inductively coupled plasma mass spectrometry (ICP-MS) after microwave digestion. Mean values and their respective coefficients of variation were calculated from the measured concentrations. The concentrations found for cadmium and lead ranged from 0.6 to 3.9 ÎŒg/100 g and 1.0 to 2.1 ÎŒg/100 g, respectively. Concentrations ranged between 0.5 and 3.3 mg/100 g for iron, 0.7 and 5.1 mg/100 g for zinc, 9 and 44 ÎŒg/100 g for selenium, 3.1 and 16.7 ÎŒg/100 g for manganese, 0.3 and 132 ÎŒg/100 g for copper and 0.9 and 3.2 ÎŒg/100 g for molybdenum. Differences found for the concentrations in meat from different species as well as between the individual meat cuts were notable for iron, zinc, selenium and copper. Manganese concentrations were found to vary unsystematically within muscles and species. Molybdenum concentrations were higher in chicken meat in comparison with the mammalian meats. The highest coefficients of variation were found for manganese (13% to 142%) and copper (13% to 224%), while the lowest was found for zinc (4% to 45%). In conclusion, in order to provide an accurate overview and to be able to calculate reliable dietary intakes, it is important to include the variability in food composition dat
Real-Time Wavelet-transform spectrum analyzer for the investigation of 1/f^\alpha noise
A wavelet transform spectrum analyzer operating in real time within the
frequency range 3X10^(-5) - 1.3X10^5 Hz has been implemented on a low-cost
Digital Signal Processing board operating at 150MHz. The wavelet decomposition
of the signal allows to efficiently process non-stationary signals dominated by
large amplitude events fairly well localized in time, thus providing the
natural tool to analyze processes characterized by 1/f^alpha power spectrum.
The parallel architecture of the DSP allows the real-time processing of the
wavelet transform of the signal sampled at 0.3MHz. The bandwidth is about
220dB, almost ten decades. The power spectrum of the scattered intensity is
processed in real time from the mean square value of the wavelet coefficients
within each frequency band. The performances of the spectrum analyzer have been
investigated by performing Dynamic Light Scattering experiments on colloidal
suspensions and by comparing the measured spectra with the correlation
functions data obtained with a traditional multi tau correlator. In order to
asses the potentialities of the spectrum analyzer in the investigation of
processes involving a wide range of timescales, we have performed measurements
on a model system where fluctuations in the scattered intensities are generated
by the number fluctuations in a dilute colloidal suspension illuminated by a
wide beam. This system is characterized by a power-law spectrum with exponent
-3/2 in the scattered intensity fluctuations. The spectrum analyzer allows to
recover the power spectrum with a dynamic range spanning about 8 decades. The
advantages of wavelet analysis versus correlation analysis in the investigation
of processes characterized by a wide distribution of time scales and
non-stationary processes are briefly discussed.Comment: 12 pages, 6 figure
Materials selection for optimum energy production by double layer expansion methods
NOTICE: this is the authorâs version of a work that was accepted for publication in Journal of Power Sources. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Power Sources (2014) DOI:http://dx.doi.org/10.1016/j.jpowsour.2013.12.125The capacitive mixing procedure for energy extraction based on Double Layer Expansion (CDLE) belongs to the group of so-called CAPMIX techniques, which aim at obtaining energy from the salinity difference between fresh and sea waters. Specifically, the CDLE technique takes advantage of the voltage rise that occurs when sea water is exchanged for river water in a pair of porous electrodes which jointly behave as an electrical double layer supercapacitor. In this article, we deal with some experimental aspects that are key for optimizing the extracted energy, and have not been analyzed yet with sufficient detail. This investigation will help in evaluating those parameters which we need to be fixed in a future CDLE device. These include the charging potential, the durations of the different cycle steps, the load resistance used, and the porosity and hydrophilicity of the carbon.Departamento de FĂsica Aplicada, Universidad de GranadaThe research leading to these results received funding from the European Union 7th Framework Programme (FP7/2007-2013) under agreement No. 256868. Further financial support from Junta de AndalucĂa (Spain), project PE-2008-FQM3993 is also gratefully acknowledged
Fluctuations in fluids in thermal nonequilibrium states below the convective Rayleigh-Benard instability
Starting from the linearized fluctuating Boussinesq equations we derive an
expression for the structure factor of fluids in stationary convection-free
thermal nonequilibrium states, taking into account both gravity and finite-size
effects. It is demonstrated how the combined effects of gravity and finite size
causes the structure factor to go through a maximum value as a function of the
wave number . The appearance of this maximum is associated with a crossover
from a dependence for larger to a dependence for very small
. The relevance of this theoretical result for the interpretation of light
scattering and shadowgraph experiments is elucidated. The relationship with
studies on various aspects of the problem by other investigators is discussed.
The paper thus provides a unified treatment for dealing with fluctuations in
fluid layers subjected to a stationary temperature gradient regardless of the
sign of the Rayleigh number , provided that is smaller than the critical
value associated with the appearance of Rayleigh-B\'{e}nard
convection.Comment: 33 pages, 6 figures, accepted for publication: Physica
Polyelectrolyte-coated carbons used in the generation of blue energy from salinity differences
This is the unedited version of this manuscript. The publisher's edited version can be reached at this URL: http://pubs.rsc.org/en/content/articlelanding/2014/cp/c4cp03527e#!divAbstractIn this work we present a method for the production of
clean, renewable electrical energy from the exchange of
solutions with different salinities. Activated carbon films
are coated with negatively or positively charged polyelectrolytes
by well-established adsorption methods. When
two oppositely charged coated films are placed in contact
with an ionic solution, the potential difference between
them will be equal to the difference between their Donnan
potentials, and hence, energy can be extracted by building
an electrochemical cell with such electrodes. A model is
elaborated on the operation of the cell, based on the electrokinetic
theory of soft particles. All the features of the
model are experimentally reproduced, although a small
quantitative difference concerning the maximum opencircuit
voltage is found, suggesting that the coating is the
key point to improve the efficiency. In the used experimental
conditions, we obtain a power of 12.1 mW/m2. Overall,
the method proves to be a fruitful and simple approach to
salinity-gradient energy production.
Obtaining energy from salinity differences asDepartamento de FĂsica AplicadaThe research leading to these results received funding from the European Union 7th Framework Programme (FP7/2007-2013) under agreement No. 256868. Further financial sup-
ports from Junta de AndalucĂa, project PE2012-FQM694, and Ministerio de EconomĂa y Competitividad (Spain), project
FIS2013-47666-C3-1-R
Equilibrium and nonequilibrium fluctuations at the interface between two fluid phases
We have performed small-angle light-scattering measurements of the static
structure factor of a critical binary mixture undergoing diffusive partial
remixing. An uncommon scattering geometry integrates the structure factor over
the sample thickness, allowing different regions of the concentration profile
to be probed simultaneously. Our experiment shows the existence of interface
capillary waves throughout the macroscopic evolution to an equilibrium
interface, and allows to derive the time evolution of surface tension.
Interfacial properties are shown to attain their equilibrium values quickly
compared to the system's macroscopic equilibration time.Comment: 10 pages, 5 figures, submitted to PR
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