INTELLIGENT DISCRIMINATION MODEL TO IDENTIFY INFLUENTIAL PARAMETERS DURING CRYSTALLISATION FOULING

The introduction of redundant independent variables into any function approximation model, or the neglect of important variables, may result in a correlation with poor prediction and reduced reliability. This paper demonstrates that a novel integrated model of neural networks and genetic algorithms can deal with this problem robustly with good accuracy, while be far less time-consuming compared to lengthy conventional models Furthermore, a redundant variable input was imposed to the model to discern if the approach could identify it among other important variables. Genetic algorithms were exploited as a powerful optimisation tool for the selection of best set of inputs with the help of process “prior knowledge” rules. A comprehensive databank of crystallisation fouling under subcooled flow boiling was used. The resulting model was capable of handling the data and successfully discriminated among several independent inputs if there is any redundant input. The technique may be regarded as a robust method to prevent data over-fitting as well as processes where a large number of inputs are involved such as crude oil fouling

EXPERIMENTAL INVESTIGATION OF CRYSTALLIZATION FOULING ON GROOVED STAINLESS STEEL SURFACES DURING CONVECTIVE HEAT TRANSFER

The beneficial aspects of enhanced or extended heat transfer surfaces may be off-set if operated under fouling conditions. In the present paper, preliminary experimental results for crystallization fouling of CaSO4 solutions onto surfaces with different structures are reported. Flat stainless steel plates (50 mm x 59 mm) with \u27V\u27 shaped grooves on the side of fluid flow were used as heat transfer surfaces. Experiments were carried out both under clean and fouling conditions to discern how the same surface structures perform under such circumstances. In addition, the impact of both, the direction of grooves with respect to fluid flow (crossed, longitudinal and mixed flow grooves) and the groove dimensions has also been investigated. Fouling trends are discussed in terms of delay time and fouling rate. Significant differences have been found for the various flow conditions

Tunneling spectra of submicron Bi2_2Sr2_2CaCu2_2O8+δ_{8+\delta} intrinsic Josephson junctions: evolution from superconducting gap to pseudogap

Tunneling spectra of near optimally doped, submicron Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ intrinsic Josephson junctions are presented, and examined in the region where the superconducting gap evolves into pseudogap. The spectra are analyzed using a self-energy model, proposed by Norman {\it et al.}, in which both quasiparticle scattering rate $\Gamma$ and pair decay rate $\Gamma_{\Delta}$ are considered. The density of states derived from the model has the familiar Dynes' form with a simple replacement of $\Gamma$ by $\gamma_+$ = ($\Gamma$ + $\Gamma_{\Delta}$)/2. The $\gamma_+$ parameter obtained from fitting the experimental spectra shows a roughly linear temperature dependence, which puts a strong constraint on the relation between $\Gamma$ and $\Gamma_{\Delta}$. We discuss and compare the Fermi arc behavior in the pseudogap phase from the tunneling and angle-resolved photoemission spectroscopy experiments. Our results indicate an excellent agreement between the two experiments, which is in favor of the precursor pairing view of the pseudogap.Comment: 7 pages, 6 figure

Разработка и изготовление действующей модели роликовой транспортной системы для ГПС

There is increased interest in the potential protective role of dietary Ca in the development of metabolic disorders related to the metabolic syndrome. Ca-induced intestinal precipitation of fatty acids and bile acids as well as systemic metabolic effects of Ca on adipose tissue is proposed to play a causal role. In this experiment, we have studied all these aspects to validate the suggested protective effect of Ca supplementation, independent of other dietary changes, on the development of diet-induced obesity and insulin resistance. In our diet intervention study, C57BL/6J mice were fed high-fat diets differing in Ca concentrations (50 v. 150 mmol/kg). Faecal excretion analyses showed an elevated precipitation of intestinal fatty acids (2.3-fold;

The Structure of D2-Branes in the Presence of an RR field

A Born--Infeld theory describing a $D2$--brane coupled to a 3--form RR potential is reconsidered and a new type of static solution is obtained which is even stable.Comment: 11 pages, 2 postscript figures, v2 a significantly revised including title, v3 expression of energy for D2 brane is improved, version to appear in JHE

Field-induced quasi-particle tunneling in the nodal-line semimetal HfSiS revealed by de Haas-van Alphen quantum oscillations

Contains fulltext : 283653.pdf (Publisher’s version ) (Open Access

Stability of Asn_n [n=4, 8, 20, 28, 32, 36, 60] Cage Structures

We present all-electron density functional study of the geometry, electronic structure, vibrational modes, polarizabilities as well as the infrared and Raman spectra of fullerene-like arsenic cages. The stability of As$_n$ cages for sizes 4, 8, 20, 28, 32, 36, and 60 wherein each As atom is three-fold coordinated is examined. We find that all the cages studied are vibrationally stable and while all the clusters are energetically stable with respect to isolated arsenic atoms, only As$_{20}$ is energetically stable against dissociation into As$_4$. We suggest that the Raman spectra might be a means for observing the As$_{20}$ molecule in gas phase.Comment: Uses elsart.cls (Elsevier Science), (Better pictures can be obtained from authors); Manuscript to appear in Chemical Physics Letter

The oxygen isotope evolution of parent body aqueous solutions as recorded by multiple carbonate generations in the Lonewolf Nunataks 94101 CM2 carbonaceous chondrite

The CM2 carbonaceous chondrite LON 94101 contains aragonite and two generations of calcite that provide snapshots of the chemical and isotopic evolution of aqueous solutions during parent body alteration. Aragonite was the first carbonate to crystallize. It is rare, heterogeneously distributed within the meteorite matrix, and its mean oxygen isotope values are δ18O 39.9±0.6‰, Δ17O -0.3±1.0‰ (1σ). Calcite precipitated very soon afterwards, and following a fall in solution Mg/Ca ratios, to produce small equant grains with a mean oxygen isotope value of δ18O 37.5±0.7‰, Δ17O 1.4±1.1‰ (1σ). These grains were partially or completely replaced by serpentine and tochilinite prior to precipitation of the second generation of calcite, which occluded an open fracture to form a millimeter-sized vein, and replaced anhydrous silicates within chondrules and the matrix. The vein calcite has a mean composition of δ18O 18.4±0.3‰, Δ17O -0.5±0.5‰ (1σ). Petrographic and isotopic results therefore reveal two discrete episodes of mineralization that produced Ca-carbonates with contrasting δ18O, but whose Δ17O values are indistinguishable within error. The aragonite and equant calcite crystallized over a relatively brief period early in the aqueous alteration history of the parent body, and from static fluids that were evolving chemically in response to mineral dissolution and precipitation. The second calcite generation crystallized from solutions of a lower Δ17O, and a lower δ18O and/or higher temperature, which entered LON 9410 via a fracture network. As two generations of calcite whose petrographic characteristics and oxygen isotopic compositions are similar to those in LON 94101 occur in at least one other CM2, multiphase carbonate mineralization could be the typical outcome of the sequence of chemical reactions during parent body aqueous alteration. It is equally possible however that the second generation of calcite in formed in response to an event such as impact fracturing and concomitant fluid mobilisation that affected a large region of the common parent body of several CM2 meteorites. These findings show that integrated petrographic, chemical and isotopic studies can provide new insights into the mechanisms of parent body alteration including the spatial and temporal dynamics of the aqueous system

A characterization of the multivariate excess wealth ordering

In this paper, some new properties of the upper-corrected orthant of a random vector are proved. The univariate right-spread or excess wealth function, introduced by Fernández-Ponce et al. (1996), is extended to multivariate random vectors, and some properties of this multivariate function are studied. Later, this function was used to define the excess wealth ordering by Shaked and Shanthikumar (1998) and Fernández-Ponce et al. (1998). The multivariate excess wealth function enable us to define a new stochastic comparison which is weaker than the multivariate dispersion orderings. Also, some properties relating the multivariate excess wealth order with stochastic dependence are describe