Morphological and microstructural characterization of laser-glazedplasma-sprayed thermal barrier coatings

Laser glazing has been revealing a high potential for the improvement of plasma-sprayed (PS) thermal barrier coatings (TBCs) by reducing surface roughness, eliminating open porosity on the surface and generating a controlled segmented crack network, although the relationship of the processing parameters with the resultant properties has not yet been completely established. In this investigation, TBCs consisting of atmospheric plasma-sprayed (APS) ZrO2–8wt.%Y2O3 were subjected to a CO2 continuous wave laser-glazing process in order to seal its surface porosity, generating an external dense layer. For that purpose, different amounts of radiation resulting from different scanning speeds were applied to the specimens as well as different track overlapping. Results have shown a significant decrease of the surface roughness after the laser treatment. All specimens presented a fully dense and porous free external layer with a polyfaceted columnar microstructure highly adherent to the plasma-sprayed coating. Controlled surface crack networks, extremely dependent on the laser scanning speed and track overlapping, were achieved for each set of processing parameters. The cracks were found to have a tendency to be oriented in two perpendicular directions, one in the direction of the laser-beam travel direction, the other perpendicular to it. Moreover, the cracks parallel to the beam travel direction are found to be on the overlapping zone, coinciding with the edge of the subsequent track. The cracks are perpendicular to the surface along the densified layer and tend to branch and deviate from the vertical direction below it, within the porous PS coating. XRD results revealed mainly tV nontransformable tetragonal zirconia with a small percentage of residual monoclinic zirconia for the as-sprayed coating. All glazed coatings presented only tV nontransformable tetragonal zirconia with some variations on preferable crystal orientation. Grain sizes varied from 26 to 52 nm, increasing with an increase of laserirradiated energy; microstrain behaved inversely.Fundação para a Ciência e a Tecnologia (FCT) - Project POCTI/CTM/44590/2002.União Europeia (UE). Fundo Europeu de Desenvolvimento Regional (FEDER)

Cyclic fatigue effect in particulate ceramic composites

A new model is presented that provides an improved understanding of the time dependent fatigue behavior of two phase brittle particulate ceramic composites under static and cyclic loading conditions. The proposed model takes into consideration cyclic fatigue effects, which are responsible for the accelerated fatigue crack propagation in the cyclic loading as compared to the static loading. It also takes into account the effect of both thermal residual stresses and bridging stresses acting in the composite during time dependent crack propagation. Experimental results for the fatigue behavior of ZrB2–45 vol%SiC ceramic composite were used as a case study to valid the proposed model. The model gives insight both into the time dependent mechanical behavior of ceramic composites and, at the same time, allows determination of important structural parameter, such as, size of the bridging zone in the material under cycling loading

Accumulation of stress in constrained assemblies: novel Satoh test configuration

A common test used to study the response of a transforming material to external constraint is due to Satoh and involves the cooling of a rigidly constrained tensile specimen while monitoring the stress that accumulates. Such tests are currently common in the invention of welding alloys which on phase transformation lead to a reduction in residual stresses in the final assembly. The test suffers from the fact that the whole of the tensile specimen is not maintained at a uniform temperature, making it difficult to interpret the data. To eliminate this problem, the authors report here a novel Satoh test in which the material investigated is a part of a composite sample. It is demonstrated that this helps avoid some of the complications of the conventional tests and gives results which are consistent with independent tests

In-situ neutron diffraction of LaCoO3 perovskite under uniaxial compression. I. Crystal structure analysis and texture development

The dynamics of texture formation, changes in crystal structure, and stress accommodation mechanisms have been studied in perovskite-type R (3) over barc rhombohedral LaCoO3 during uniaxial compression using in-situ neutron diffraction. The in-situ neutron diffraction revealed the complex crystallographic changes causing the texture formation and significant straining along certain crystallographic directions during compression, which are responsible for the appearance of hysteresis and non-linear ferroelastic deformation in the LaCoO3 perovskite. The irreversible strain after the first loading was connected with the appearance of non-recoverable changes in the intensity ratio of certain crystallographic peaks, causing non-reversible texture formation. However, in the second loading/unloading cycle, the hysteresis loop was closed and no further irrecoverable strain appeared after deformation. The significant texture formation is responsible for an increase in the Young\u27s modulus of LaCoO3 at high compressive stresses, ranging from 76 GPa at the very beginning of the loading to 194 GPa at 900 MPa at the beginning of the unloading curve

In-situ neutron diffraction of LaCoO3 perovskite under uniaxial compression. II. Elastic properties

Calculations of elastic constants and development of elastic anisotropy under uniaxial compression in originally isotropic polycrystalline LaCoO3 perovskite are reported. The lattice strains in individual (hkl) planes as well as average lattice strain were determined both for planes oriented perpendicular and parallel to the loading direction using in-situ neutron diffraction. Utilizing average lattice strains as well as lattice strains along the a and c crystallographic directions, an attempt was made to determine Poisson\u27s ratio of LaCoO3, which was then compared with that measured using an impulse excitation technique. The elastic constants were calculated and Young\u27s moduli of LaCoO3 single crystal in different crystallographic directions were estimated

Non-congruence of high-temperature mechanical and structural behaviors of LaCoO3 based perovskites

Funding: This work was supported by the National Science Foundation [grant numbers: 0968911, 1030833, 0748364]. A portion of this research at ORNL's High Flux Isotope Reactor and Spallation Neutron Source, was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy

A numerical study of crack shielding and deflection under extensive plasticity

Experimentally observed crack deflection events in multi-layered material systems, occurring even under pure mode-I loading, are here simulated and explained through elasto-plastic finite element modelling. The crack tip opening displacement is adopted as the crack driving force and estimated along crack paths whose deflection is predicted using the maximum tangential strain criterion. Shielding conditions that promote deflection and bifurcation are evaluated. It is shown that, under conditions of extended plasticity, CTOD evolution as a crack approaches an interface can reveal crack shielding and amplification, and that crack deflection and growth can be assessed from the variation of tangential strains around the crack tip