Evolving fracture patterns: columnar joints, mud cracks, and polygonal terrain

When cracks form in a thin contracting layer, they sequentially break the layer into smaller and smaller pieces. A rectilinear crack pattern encodes information about the order of crack formation, as later cracks tend to intersect with earlier cracks at right angles. In a hexagonal pattern, in contrast, the angles between all cracks at a vertex are near 120$^\circ$. However, hexagonal crack patterns are typically only seen when a crack network opens and heals repeatedly, in a thin layer, or advances by many intermittent steps into a thick layer. Here it is shown how both types of pattern can arise from identical forces, and how a rectilinear crack pattern evolves towards a hexagonal one. Such an evolution is expected when cracks undergo many opening cycles, where the cracks in any cycle are guided by the positions of cracks in the previous cycle, but when they can slightly vary their position, and order of opening. The general features of this evolution are outlined, and compared to a review of the specific patterns of contraction cracks in dried mud, polygonal terrain, columnar joints, and eroding gypsum-sand cementsComment: 19 pages, 9 figures, accepted for publication in Phil. Trans. R. Soc. A; theme issue on Geophysical Pattern Formation (to appear 2013

Nuclear spin polarization transfer across an organic-semiconductor interface

Motivated by Tycko’s proposal to harness optically pumped nuclear spinpolarization for the enhancement of nuclear magnetic resonance(NMR) signals from biological macromolecules, we investigate the transfer of thermal nuclear spinpolarization between 1H or 19F in an organic overlayer and 31P at the surface of micron-sized InP particles by Hartmann–Hahn cross polarization. Comparison with analytic and numerical models indicates that the total quantity of polarization transferred across the semiconductor-organic interface is limited by the relatively short room-temperature 1H T1ρ (11 ms) and the slow diffusion of nuclear spinpolarization in the semiconductor.Models and spin-counting experiments indicate that we are able to transfer approximately 20% of the total nuclear spinpolarization originating in the organic overlayer to the semiconductor, supporting the feasibility of transferred optically pumped NMR

Formation of shear bands in drying colloidal dispersions

In directionally dried colloidal dispersions regular bands can appear behind the drying front, inclined at ±45° to the drying line. Although these features have been noted to share visual similarities with shear bands in metal, no physical mechanism for their formation has ever been suggested, until very recently. Here, through microscopy of silica and polystyrene dispersions, dried in Hele-Shaw cells, we demonstrate that the bands are indeed associated with local shear strains. We further show how the bands form, that they scale with the thickness of the drying layer, and that they are eliminated by the addition of salt to the drying dispersions. Finally, we reveal the origins of these bands in the compressive forces associated with drying

Drying and cracking mechanisms in a starch slurry

Starch-water slurries are commonly used to study fracture dynamics. Drying starch-cakes benefit from being simple, economical, and reproducible systems, and have been used to model desiccation fracture in soils, thin film fracture in paint, and columnar joints in lava. In this paper, the physical properties of starch-water mixtures are studied, and used to interpret and develop a multiphase transport model of drying. Starch-cakes are observed to have a nonlinear elastic modulus, and a desiccation strain that is comparable to that generated by their maximum achievable capillary pressure. It is shown that a large material porosity is divided between pore spaces between starch grains, and pores within starch grains. This division of pore space leads to two distinct drying regimes, controlled by liquid and vapor transport of water, respectively. The relatively unique ability for drying starch to generate columnar fracture patterns is shown to be linked to the unusually strong separation of these two transport mechanisms.Comment: 9 pages, 8 figures [revised in response to reviewer comments

Drying and cracking mechanisms in a starch slurry

Starch-water slurries are commonly used to study fracture dynamics. Drying starch-cakes benefit from being simple, economical, and reproducible systems, and have been used to model desiccation fracture in soils, thin film fracture in paint, and columnar joints in lava. In this paper, the physical properties of starch-water mixtures are studied, and used to interpret and develop a multiphase transport model of drying. Starch-cakes are observed to have a nonlinear elastic modulus, and a desiccation strain that is comparable to that generated by their maximum achievable capillary pressure. It is shown that a large material porosity is divided between pore spaces between starch grains, and pores within starch grains. This division of pore space leads to two distinct drying regimes, controlled by liquid and vapor transport of water, respectively. The relatively unique ability for drying starch to generate columnar fracture patterns is shown to be linked to the unusually strong separation of these two transport mechanisms.Comment: 9 pages, 8 figures [revised in response to reviewer comments

An Experimental Investigation of the Scaling of Columnar Joints

Columnar jointing is a fracture pattern common in igneous rocks in which cracks self-organize into a roughly hexagonal arrangement, leaving behind an ordered colonnade. We report observations of columnar jointing in a laboratory analog system, desiccated corn starch slurries. Using measurements of moisture density, evaporation rates, and fracture advance rates as evidence, we suggest an advective-diffusive system is responsible for the rough scaling behavior of columnar joints. This theory explains the order of magnitude difference in scales between jointing in lavas and in starches. We investigated the scaling of average columnar cross-sectional areas due to the evaporation rate, the analog of the cooling rate of igneous columnar joints. We measured column areas in experiments where the evaporation rate depended on lamp height and time, in experiments where the evaporation rate was fixed using feedback methods, and in experiments where gelatin was added to vary the rheology of the starch. Our results suggest that the column area at a particular depth is related to both the current conditions, and hysteretically to the geometry of the pattern at previous depths. We argue that there exists a range of stable column scales allowed for any particular evaporation rate.Comment: 12 pages, 11 figures, for supporting online movies, go to http://www.physics.utoronto.ca/nonlinear/movies/starch_movies.htm

Interface propagation in fiber bundles: local, mean-field and intermediate range-dependent statistics

The fiber bundle model is essentially an array of elements that break when sufficient load is applied on them. With a local loading mechanism, this can serve as a model for a one-dimensional interface separating the broken and unbroken parts of a solid in mode-I fracture. The interface can propagate through the system depending on the loading rate and disorder present in the failure thresholds of the fibers. In the presence of a quasi-static drive, the intermittent dynamics of the interface mimic front propagation in disordered media. Such situations appear in diverse physical systems such as mode-I crack propagation, domain wall dynamics in magnets, charge density waves, contact lines in wetting etc. We study the effect of the range of interaction, i.e. the neighborhood of the interface affected following a local perturbation, on the statistics of the intermittent dynamics of the front. There exists a crossover from local to global behavior as the range of interaction grows and a continuously varying 'universality' in the intermediate range. This means that the interaction range is a relevant parameter of any resulting physics. This is particularly relevant in view of the fact that there is a scatter in the experimental observations of the exponents, in even idealized experiments on fracture fronts, and also a possibility in changing the interaction range in real samples

Crack patterns over uneven substrates

Cracks in thin layers are influenced by what lies beneath them. From buried craters to crocodile skin, crack patterns are found over an enormous range of length scales. Regardless of absolute size, their substrates can dramatically influence how cracks form, guiding them in some cases, or shielding regions from them in others. Here we investigate how a substrate’s shape affects the appearance of cracks above it, by preparing mud cracks over sinusoidally varying surfaces. We find that as the thickness of the cracking layer increases, the observed crack patterns change from wavy to ladder-like to isotropic. Two order parameters are introduced to measure the relative alignment of these crack networks, and, along with Fourier methods, are used to characterise the transitions between crack pattern types. Finally, we explain these results with a model, based on the Griffith criteria of fracture, that identifies the conditions for which straight or wavy cracks will be seen, and predicts how well-ordered the cracks will be. Our metrics and results can be applied to any situation where connected networks of cracks are expected, or found

Structural anisotropy of directionally dried colloids

Aqueous colloidal dispersions of silica particles become anisotropic when they are dried through evaporation. This anisotropy is generated by a uniaxial strain of the liquid dispersions as they are compressed by the flow of water toward a solidification front. Part of the strain produced by the compression is relaxed, and part of it is stored and transferred to the solid. This stored elastic strain has consequences for the properties of the solid, where it may facilitate the growth of shear bands, and generate birefringence

Impact of spatially correlated pore-scale heterogeneity on drying porous media

We study the effect of spatially-correlated heterogeneity on isothermal drying of porous media. We combine a minimal pore-scale model with microfluidic experiments with the same pore geometry. Our simulated drying behavior compares favorably with experiments, considering the large sensitivity of the emergent behavior to the uncertainty associated with even small manufacturing errors. We show that increasing the correlation length in particle sizes promotes preferential drying of clusters of large pores, prolonging liquid connectivity and surface wetness and thus higher drying rates for longer periods. Our findings improve our quantitative understanding of how pore-scale heterogeneity impacts drying, which plays a role in a wide range of processes ranging from fuel cells to curing of paints and cements to global budgets of energy, water and solutes in soils