Low energy electron scattering from DNA and RNA bases: shape resonances and radiation damage

Calculations are carried out to determine elastic scattering cross sections and resonance energies for low energy electron impact on uracil and on each of the DNA bases (thymine, cytosine, adenine, guanine), for isolated molecules in their equilibrium geometry. Our calculations are compared with available theory and experiment. We also attempt to correlate this information with experimental dissociation patterns through an analysis of the temporary anion structures that are formed by electron capture in shape resonances.Comment: 20 pages, 12 figures, submitted to J. Chem. Phy

Light-Level Geolocation Reveals The Migration Route And Non-Breeding Location Of An Antillean Nighthawk (Chordeiles Gundlachii)

The Antillean Nighthawk’s (Chordeiles gundlachii) migration routes and non-breeding location were previously unknown. We deployed a geolocator on a female Antillean Nighthawk found breeding on the Lesser Antilles island of Guadeloupe and tracked her annual movements between 2013 and 2014. Her journey included a 2-month stopover on Isla La Tortuga, Venezuela, during southward migration, and a non-breeding season in the remote forestlands of the state of Amazonas, Brazil, approximately 2,100 km south of her breeding grounds. Her migration route was geographically similar in both the fall and spring, following a north-south trajectory, but lacked a prolonged stopover in the spring

Red Supergiants in the Andromeda Galaxy (M31)

Red supergiants are a short-lived stage in the evolution of moderately massive stars (10-25Mo), and as such their location in the H-R diagram provides an exacting test of stellar evolutionary models. Since massive star evolution is strongly affected by the amount of mass-loss a star suffers, and since the mass-loss rates depend upon metallicity, it is highly desirable to study the physical properties of these stars in galaxies of various metallicities. Here we identify a sample of red supergiants in M31 (the most metal-rich of the Local Group galaxies) and derive their physical properties by fitting MARCS atmosphere models to moderate resolution optical spectroscopy, and from V-K photometry.Comment: Accepted for publication in the Astrophysical Journa

The Physical Properties of the Red Supergiant WOH G64: The Largest Star Known?

WOH G64 is an unusual red supergiant (RSG) in the Large Magellanic Cloud (LMC), with a number of properties that set it apart from the rest of the LMC RSG population, including a thick circumstellar dust torus, an unusually late spectral type, maser activity, and nebular emission lines. Its reported physical properties are also extreme, including the largest radius for any star known and an effective temperature that is much cooler than other RSGs in the LMC, both of which are at variance with stellar evolutionary theory. We fit moderate-resolution optical spectrophotometry of WOH G64 with the MARCS stellar atmosphere models, determining an effective temperature of 3400 +/- 25 K. We obtain a similar result from the star's broadband V - K colors. With this effective temperature, and taking into account the flux contribution from the aysmmetric circumstellar dust envelope, we calculate log(L/L_sun) = 5.45 +/- 0.05 for WOH G64, quite similar to the luminosity reported by Ohnaka and collaborators based on their radiative transfer modeling of the star's dust torus. We determine a radius of R/R_sun = 1540, bringing the size of WOH G64 and its position on the H-R diagram into agreement with the largest known Galactic RSGs, although it is still extreme for the LMC. In addition, we use the Ca II triplet absorption feature to determine a radial velocity of 294 +/- 2 km/s for the star; this is the same radial velocity as the rotating gas in the LMC's disk, which confirms its membership in the LMC and precludes it from being an unusual Galactic halo giant. Finally, we describe the star's unusual nebula emission spectrum; the gas is nitrogen-rich and shock-heated, and displays a radial velocity that is significantly more positive than the star itself by 50 km/s.Comment: 25 pages, 5 figures; accepted for publication in The Astronomical Journa

The impact of mass-loss on the evolution and pre-supernova properties of red supergiants

The post main-sequence evolution of massive stars is very sensitive to many parameters of the stellar models. Key parameters are the mixing processes, the metallicity, the mass-loss rate and the effect of a close companion. We study how the red supergiant lifetimes, the tracks in the Hertzsprung-Russel diagram (HRD), the positions in this diagram of the pre-supernova progenitor as well as the structure of the stars at that time change for various mass-loss rates during the red supergiant phase (RSG), and for two different initial rotation velocities. The surface abundances of RSGs are much more sensitive to rotation than to the mass-loss rates during that phase. A change of the RSG mass-loss rate has a strong impact on the RSG lifetimes and therefore on the luminosity function of RSGs. At solar metallicity, the enhanced mass-loss rate models do produce significant changes on the populations of blue, yellow and red supergiants. When extended blue loops or blue ward excursions are produced by enhanced mass-loss, the models predict that a majority of blue (yellow) supergiants are post RSG objects. These post RSG stars are predicted to show much smaller surface rotational velocities than similar blue supergiants on their first crossing of the HR gap. The position in the HRD of the end point of the evolution depends on the mass of the hydrogen envelope. More precisely, whenever, at the pre-supernova stage, the H-rich envelope contains more than about 5\% of the initial mass, the star is a red supergiant, and whenever the H-rich envelope contains less than 1\% of the total mass the star is a blue supergiant. For intermediate situations, intermediate colors/effective temperatures are obtained. Yellow progenitors for core collapse supernovae can be explained by the enhanced mass-loss rate models, while the red progenitors are better fitted by the standard mass-loss rate models.Comment: 19 pages, 11 figures, 6 tables, accepted for publication in Astronomy and Astrophysic

Molecular Density Functional Theory of Water describing Hydrophobicity at Short and Long Length Scales

We present an extension of our recently introduced molecular density functional theory of water [G. Jeanmairet et al., J. Phys. Chem. Lett. 4, 619, 2013] to the solvation of hydrophobic solutes of various sizes, going from angstroms to nanometers. The theory is based on the quadratic expansion of the excess free energy in terms of two classical density fields, the particle density and the multipolar polarization density. Its implementation requires as input a molecular model of water and three measurable bulk properties, namely the structure factor and the k-dependent longitudinal and transverse dielectric susceptibilities. The fine three-dimensional water structure around small hydrophobic molecules is found to be well reproduced. In contrast the computed solvation free-energies appear overestimated and do not exhibit the correct qualitative behavior when the hydrophobic solute is grown in size. These shortcomings are corrected, in the spirit of the Lum-Chandler-Weeks theory, by complementing the functional with a truncated hard-sphere functional acting beyond quadratic order in density. It makes the resulting functional compatible with the Van-der-Waals theory of liquid-vapor coexistence at long range. Compared to available molecular simulations, the approach yields reasonable solvation structure and free energy of hard or soft spheres of increasing size, with a correct qualitative transition from a volume-driven to a surface-driven regime at the nanometer scale.Comment: 24 pages, 8 figure