Understanding the hydrogeology and surface flow in the Cuatrocienegas Basin (NE Mexico) using stable isotopes

In this paper we present surface water oxygen (δ18O), hydrogen (δD) and inorganic carbon (δ13CDIC) isotope data to gain a better understanding of the modern day hydrogeology of Cuatrociénegas Basin, a semi-arid region in northeastern Mexico. Our study focuses on 26 water samples collected in March 2008 to investigate: 1) current provenance and flow pathways of surface waters, 2) the use of stable isotopes in identifying water loss and environmental degradation, and 3) human influence on hydrogeology. δ18O for Cuatrociénegas water samples ranged from −7.99 to +4.97‰ (mean −5.23 ± 3.13‰), δD from −54.8 to +0.3‰ (mean −42.4 ± 14.4‰), and δ13CTDICfrom −21.6 to −9.2‰ (mean −14.3 ± 3.4‰). Samples collected progressively away from their respective spring lines display increasing δ18O and δD values. Isotope data suggest that where the residence time of the groundwater is long and/or the system is hydrologically open, δ18O may not be a reliable indicator of water loss and environmental degradation. Our data suggest the central ciénega (area W(b)) is the most viable area for palaeoenvironmental study and long term monitoring is an essential tool in the identification of ecosystem damage and response, allowing for better future management of the complex and fragile CCB ecosystem

Extensive primary production promoted the recovery of the Ediacaran Shuram excursion

Member IV of the Ediacaran Doushantuo Formation records the recovery from the most negative carbon isotope excursion in Earth history. However, the main biogeochemical controls that ultimately drove this recovery have yet to be elucidated. Here, we report new carbon and nitrogen isotope and concentration data from the Nanhua Basin (South China), where δ13C values of carbonates (δ13Ccarb) rise from - 7‰ to -1‰ and δ15N values decrease from +5.4‰ to +2.3‰. These trends are proposed to arise from a new equilibrium in the C and N cycles where primary production overcomes secondary production as the main source of organic matter in sediments. The enhanced primary production is supported by the coexisting Raman spectral data, which reveal a systematic difference in kerogen structure between depositional environments. Our new observations point to the variable dominance of distinct microbial communities in the late Ediacaran ecosystems, and suggest that blooms of oxygenic phototrophs modulated the recovery from the most negative δ13Ccarb excursion in Earth history

Recent palaeolimnological change recorded in Lake Xiaolongwan, northeast China: Climatic versus anthropogenic forcing

Lake Xiaolongwan is a closed maar lake located in the Long Gang Volcanic Field, northeast China. Core XLW2 was collected in 2007 from the central region of the lake and provides a palaeoecological reconstruction over the past ca. 130 years (dated using radiometric methods: 210Pb and 137Cs). Diatom floristic changes and catchment productivity (carbon isotope ratios) were analysed within the core. Indicators of atmospheric pollution (XRF and SCP inventories) were also measured. Results show a marked transition from a dominant benthic assemblage to a planktonic one (increasing P:B ratios) starting after ca. 1940 AD, becoming most prominent after ca. 1980 AD (P:B > 1). Most notable floristic changes result from the increase in the planktonic species Discostella woltereckii. These changes are concomitant with increased temperature trends from the region and reconstructed temperature anomalies of the Northern Hemisphere. SCP concentrations and flux rates also increase after ca. 1950 AD, with highest values seen at ca. 1980 AD after which values decline. Normalised elemental geochemistry (e.g. Pb/Ti) also show marked changes after ca. 1970 AD, most likely derived from atmospheric deposition of Pb. The recent increase in D. woltereckii precedes anthropogenic contamination (Pb/Ti) at the site and persists after the decline in SCP concentrations. This suggests that the recent increases are driven by increased mean annual temperature trends. These temperature trends may be manifested as changes in ice cover persistence, a longer growing season and/or increased DOC at Lake Xiaolongwan: conditions for which planktonic species have a more competitive advantage

Vertical distribution and diurnal migration of atlantid heteropods

© Inter-Research 201 Understanding the vertical distribution and migratory behaviour of shelled holoplanktonic gastropods is essential in determining the environmental conditions to which they are exposed. This is increasingly important in understanding the effects of ocean acidification and climate change. Here we investigated the vertical distribution of atlantid heteropods by collating data from publications and collections and using the oxygen isotope (? 18 O) composition of single aragonitic shells. Data from publications and collections show 2 patterns of migration behaviour: small species that reside in shallow water at all times, and larger species that make diurnal migrations from the surface at night to deep waters during the daytime. The ? 18 O data show that all species analysed (n = 16) calcify their shells close to the deep chlorophyll maximum. This was within the upper 110 m of the ocean for 15 species, and down to 146 m for a single species. These findings confirm that many atlantid species are exposed to large environmental variations over a diurnal cycle and may already be well adapted to face ocean changes. However, all species analysed rely on aragonite supersaturated waters in the upper < 150 m of the ocean to produce their shells, a region that is projected to undergo the earliest and greatest changes in response to increased anthropogenic CO 2

Silicic acid cycling in the Bering Sea during the Mid‐Pleistocene Transition

This is the final version. Available from Wiley via the DOI in this record. Data Availability Statement: The data presented in this paper are stored in the Pangaea data repository (https://doi.pangaea.de/10.1594/ PANGAEA.933139)The rate of deep-ocean carbon burial is considered important for modulating glacial-interglacial atmospheric CO2 concentrations and global climate during the Quaternary. It has been suggested that glacial iron fertilization and increased efficiency of the biological pump in the Southern Ocean since the Mid-Pleistocene Transition (MPT) was key in lowering atmospheric pCO2 and facilitating rapid land ice accumulation. There is growing evidence that a similar mechanism may have existed in the subarctic Pacific Ocean, although this has not yet been assessed. Here, the silicon isotope composition of diatoms (δ30Sidiatom) from the Bering Sea upwelling region is used to assess the role of nutrient cycling on the subarctic Pacific biological pump during the MPT. Results show that during and after the “900 kyr event,” the high productivity green belt zone was characterized by low silicic acid utilization but high supply, coincident with the dominance of diatom resting spores. We posit that as nutrient upwelling was suppressed following pack ice growth and expansion of glacial North Pacific Intermediate Water (GNPIW), primary productivity became nitrate-limited and enhanced opal remineralization caused a relative increase in silicic acid supply. However, preferential preservation and higher cellular carbon content of diatom resting spores, as well as increased supply of iron from expanded sea ice, likely sustained the net efficiency of the Bering Sea biological pump through the MPT. Remnant iron and silicic acid may also have propagated into the lower subarctic Pacific Ocean through GNPIW, aiding a regionally efficient biological pump at 900 kyr and during post-MPT glacials.Natural Environment Research CouncilBritish Geological SurveyNatural Environment Research CouncilNatural Environment Research Counci

Reduced upwelling of nutrient and carbon-rich water in the subarctic Pacific during the Mid-Pleistocene Transition

This is the author accepted manuscript. The final version is available from the publisher via the DOI in this recordReduction in atmosphericpCO2has been hypothesised as a causal mechanism for the Mid-Pleistocene Transition(MPT), which saw global cooling and increased duration of glacials between 0.6 and 1.2 Ma. Sea ice-modulatedhigh latitude upwelling and ocean-atmospheric CO2flux is considered a potential mechanism forpCO2decline,although there are no long-term nutrient upwelling records from high latitude regions to test this hypothesis.Using nitrogen isotopes and opal mass accumulation rates from 0 to 1.2 Ma, we calculate a continuous highresolution nutrient upwelling index for the Bering Sea and assess possible changes to regional CO2fluxes and tothe relative control of sea ice, sea level and glacial North Pacific Intermediate Water (GNPIW) on deep mixingand nutrient upwelling in the region. Wefind nutrient upwelling in the Bering Sea correlates with global icevolume and air temperature throughout the study interval. From ~1 Ma, and particularly during the 900 kaevent, suppressed nutrient upwelling would have lowered oceanicfluxes of CO2to the atmosphere supporting areduction in globalpCO2during the MPT. This timing is consistent with a pronounced increase in sea ice duringthe early Pleistocene and restriction offlow through the Bering Strait during glacials after ~900 ka, both ofwhich would have acted to suppress upwelling. We suggest that sea-level modulated GNPIW expansion duringglacials after 900 ka was the dominant control on subarctic Pacific upwelling strength during the mid-latePleistocene, while sea ice variability played a secondary role.Natural Environment Research Council (NERC

People and climate: holocene sediment records of environmental change in Middle Egypt: fieldwork report and initial results

The aim of this project is to reveal more about the history of Lake Qarun through a multidisciplinary environmental study. This approach primarily concerns the examination of sediment records, but also includes collection of data from archaeological sites in the Faiyum. The sedimentary history of Lake Qarun will be compared with (i) independent palaeoclimate records for the East African Highlands and the eastern Mediterranean; (ii) local evidence (including Nile alluvial and palaeo-shoreline sequences and Holocene playa deposits); and (iii) the cultural history of the Faiyum. This report describes the fieldwork performed to obtain long sediment cores for palaeolimnological analysis and presents initial results from those cores. Results will be used to construct a Geographical Information System (GIS)

Hydrological (in)stability in Southern Siberia during the Younger Dryas and early Holocene

Southern Siberia is currently undergoing rapid warming, inducing changes in vegetation, loss of permafrost, and impacts on the hydrodynamics of lakes and rivers. Lake sediments are key archives of environmental change and contain a record of ecosystem variability, as well as providing proxy indicators of wider environmental and climatic change. Investigating how hydrological systems have responded to past shifts in climate can provide essential context for better understanding future ecosystem changes in Siberia. Oxygen isotope ratios within lacustrine records provide fundamental information on past variability in hydrological systems. Here we present a new oxygen isotope record from diatom silica (ẟ18Odiatom) at Lake Baunt (55°11′15″N, 113°01,45″E), in the southern part of eastern Siberia, and consider how the site has responded to climate changes between the Younger Dryas and Early to Mid Holocene (ca. 12.4 to 6.2 ka cal BP). Excursions in ẟ18Odiatom are influenced by air temperature and the seasonality, quantity, and source of atmospheric precipitation. These variables are a function of the strength of the Siberian High, which controls temperature, the proportion and quantity of winter versus summer precipitation, and the relative dominance of Atlantic versus Pacific air masses. A regional comparison with other Siberian ẟ18Odiatom records, from lakes Baikal and Kotokel, suggests that ẟ18Odiatom variations in southern Siberia reflect increased continentality during the Younger Dryas, delayed Early Holocene warming in the region, and substantial climate instability between ~10.5 to ~8.2 ka cal BP. Unstable conditions during the Early Holocene thermal optimum most likely reflect localised changes from glacial melting. Taking the profiles from three very different lakes together, highlight the influence of site specific factors on the individual records, and how one site is not indicative of the region as a whole. Overall, the study documents how sensitive this important region is to both internal and external forcing