844 research outputs found
Vibrational Excitons in CH-Stretching Fundamental and Overtone Vibrational Circular Dichroism Spectra
A set of vibrational circular dichroism (VCD) spectra in the CH-stretching fundamental
region for about twenty compounds belonging to the class of essential oils was empirically analyzed by
the use of a sort of vibrational exciton mechanism, involving three centers. Through a general formula
applicable to many coupled dipole oscillators, the rotational strengths of the previously identified
vibrational excitons are evaluated. The results are then critically reviewed by the use of recent ab
initio methodology, as applied to selected molecules of the original set. Further insight is gained by
model calculations adding up the contribution of the coupling between electric dipole moments associated
with normal mode behavior and that of the polarizability from polarizable groups. The former
part is responsible for the excitonic behavior of the VCD spectra. For the same selected molecules we
have also investigated whether some excitonic behavior is taking place in the second overtone region,
and have concluded that this is not the case
Development and Validation of the Mental Health Professionals\u27 Attitude Towards People Living with HIV/AIDS Scale (MHP-PLHIV-AS)
This study focused on the creation and validation of an instrument to measure mental health professionals\u27 attitudes towards people living with HIV/AIDS. Rasch analyses (Rash, 1960, 1980) provided evidence to support a two-dimensional (societal and personal dimensions) measurement of this attitude construct
Far-infrared induced current in a ballistic channel -- potential barrier structure
We consider electron transport in a ballistic multi-mode channel structure in
the presence of a transversely polarized far-infrared (FIR) field. The channel
structure consists of a long resonance region connected to an adiabatic
widening with a potential barrier at the end. At frequencies that match the
mode energy separation in the resonance region we find distinct peaks in the
photocurrent, caused by Rabi oscillations in the mode population. For an
experimental situation in which the width of the channel is tunable via gates,
we propose a method for reconstructing the spectrum of propagating modes,
without having to use a tunable FIR source. With this method the change in the
spectrum as the gate voltage is varied can be monitored.Comment: Submitted to Phys. Rev.
Optimal light harvesting structures at optical and infrared frequencies
One-dimensional light harvesting structures with a realistic geometry
nano-patterned on an opaque metallic film are optimized to render high
transmission efficiencies at optical and infrared frequencies. Simple design
rules are developed for the particular case of a slit-groove array with a given
number of grooves that are symmetrically distributed with respect to a central
slit. These rules take advantage of the hybridization of Fabry-Perot modes in
the slit and surface modes of the corrugated metal surface. Same design rules
apply for optical and infrared frequencies. The parameter space of the groove
array is also examined with a conjugate gradient optimization algorithm that
used as a seed the geometries optimized following physical intuition. Both
uniform and nonuniform groove arrays are considered. The largest transmission
enhancement, with respect to a uniform array, is obtained for a chirped groove
profile. Such enhancement is a function of the wavelength. It decreases from
39% in the optical part of the spectrum to 15% at the long wavelength infrared.Comment: 13 pages, 5 figure
On the Non-invasive Measurement of the Intrinsic Quantum Hall Effect
With a model calculation, we demonstrate that a non-invasive measurement of
intrinsic quantum Hall effect defined by the local chemical potential in a
ballistic quantum wire can be achieved with the aid of a pair of voltage leads
which are separated by potential barriers from the wire. B\"uttiker's formula
is used to determine the chemical potential being measured and is shown to
reduce exactly to the local chemical potential in the limit of strong potential
confinement in the voltage leads. Conditions for quantisation of Hall
resistance and measuring local chemical potential are given.Comment: 16 pages LaTex, 2 post-script figures available on reques
Radiative association and inverse predissociation of oxygen atoms
The formation of \mbox{O}_2 by radiative association and by inverse
predissociation of ground state oxygen atoms is studied using
quantum-mechanical methods. Cross sections, emission spectra, and rate
coefficients are presented and compared with prior experimental and theoretical
results. At temperatures below 1000~K radiative association occurs by approach
along the state of \mbox{O}_2 and above 1000~K inverse
predissociation through the \mbox{B}\,{}^3\Sigma_u^- state is the dominant
mechanism. This conclusion is supported by a quantitative comparison between
the calculations and data obtained from hot oxygen plasma spectroscopy.Comment: submitted to Phys. Rev. A (Sept. 7., 1994), 19 pages, 4 figures,
latex (revtex3.0 and epsf.sty
Far-infrared absorption in parallel quantum wires with weak tunneling
We study collective and single-particle intersubband excitations in a system
of quantum wires coupled via weak tunneling. For an isolated wire with
parabolic confinement, the Kohn's theorem guarantees that the absorption
spectrum represents a single sharp peak centered at the frequency given by the
bare confining potential. We show that the effect of weak tunneling between two
parabolic quantum wires is twofold: (i) additional peaks corresponding to
single-particle excitations appear in the absorption spectrum, and (ii) the
main absorption peak acquires a depolarization shift. We also show that the
interplay between tunneling and weak perpendicular magnetic field drastically
enhances the dispersion of single-particle excitations. The latter leads to a
strong damping of the intersubband plasmon for magnetic fields exceeding a
critical value.Comment: 18 pages + 6 postcript figure
Characterization of aluminum, aluminum oxide and titanium dioxide nanomaterials using a combination of methods for particle surface and size analysis
International audienceThe application of appropriate analytical techniques is essential for nanomaterial (NM) characterization. In this study, we compared different analytical techniques for NM analysis. Regarding possible adverse health effects, ionic and particulate NM effects have to be taken into account. As NMs behave quite differently in physiological media, special attention was paid to techniques which are able to determine the biosolubility and complexation behavior of NMs. Representative NMs of similar size were selected: aluminum (Al 0) and aluminum oxide (Al 2 O 3), to compare the behavior of metal and metal oxides. In addition, titanium dioxide (TiO 2) was investigated. Characterization techniques such as dynamic light scattering (DLS) and nanoparticle tracking analysis (NTA) were evaluated with respect to their suitability for fast characterization of nanoparticle dispersions regarding a particle's hydrodynamic diameter and size distribution. By application of inductively coupled plasma mass spectrometry in the single particle mode (SP-ICP-MS), individual nanoparticles were quantified and characterized regarding their size. SP-ICP-MS measurements were correlated with the information gained using other characterization techniques, i.e. transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS). The particle surface as an important descriptor of NMs was analyzed by X-ray diffraction (XRD). NM impurities and their co-localization with biomolecules were determined by ion beam microscopy (IBM) and confocal Raman microscopy (CRM). We conclude advantages and disadvantages of the different techniques applied and suggest options for their complementation. Thus, this paper may serve as a practical guide to particle characterization techniques
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