185 research outputs found

    Distribution of Glycerol Dialkyl Glycerol Tetraethers (GDGTs) in Microbial Mats From Holocene and Miocene Sabkha Sediments

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    Sabkhas are important settings for understanding early earth biological environments, and the algal mats associated with them are thought to be potential source rocks for hydrocarbon production. In this study we compare the sedimentological facies and distribution of branched, and isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) in modern and mid-Holocene sabkha sediments from Abu Dhabi with well-preserved Miocene (12–13 Ma) sabkha sediments recently recovered at IODP site U1464 off the north coast of Australia. We show that the facies of the Miocene sediments is very similar to Holocene and modern sabkhas. Furthermore, we show that there are distinct patterns of isoprenoid GDGT distributions in the modern sabkha and that these patterns are well preserved in both the buried Holocene and the Miocene algal mats. The sabkha sediments analyzed are characterized by high %GDGT-0 and methane index, dominance of branched GDGTs over crenarchaeol (high BIT index), an unusual distribution of isoprenoid GDGTs 1–3, and also low abundance of archeol. The distribution of branched GDGT differs between modern and Miocene sabkhas and is similar in Miocene sabkha and non-sabkha sediments suggesting that they may be of limited use to distinguish paleo-sabkha sediments. Overall, isoprenoid GDGT distributions appear to be different from those found in modern soils, lakes and marine sediments, as well as from those found in Miocene shallow water sediments right below the sabkha, therefore they could be used in combination with facies analysis to identify paleo-sabkha environments in sedimentary sequences

    ΠšΡ€ΠΈΡ‚Π΅Ρ€ΠΈΠΈ ΠΈ срСдства развития ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½ΠΎΠ³ΠΎ обСспСчСния для модСлирования Π½Π΅Ρ„Ρ‚Π΅Π³Π°Π·ΠΎΠ²Ρ‹Ρ… мСстороТдСний

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    ΠžΠ±ΡΡƒΠΆΠ΄Π°ΡŽΡ‚ΡΡ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹ Π°Π½Π°Π»ΠΈΠ·Π° примСнимости ΠΈ эффСктивности ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½Ρ‹Ρ… систСм Π²Π΅Π΄ΡƒΡ‰ΠΈΡ… Π·Π°Ρ€ΡƒΠ±Π΅ΠΆΠ½Ρ‹Ρ… ΠΈ отСчСствСнных ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΡ‚Π΅Π»Π΅ΠΉ, ΠΊΡƒΠ»ΡŒΡ‚ΠΈΠ²ΠΈΡ€ΡƒΠ΅ΠΌΡ‹Ρ… Π½Π° Ρ€Ρ‹Π½ΠΊΠ΅ ΠΈΠ½Ρ„ΠΎΡ€ΠΌΠ°Ρ†ΠΈΠΎΠ½Π½Ρ‹Ρ… Ρ‚Π΅Ρ…Π½ΠΎΠ»ΠΎΠ³ΠΈΠΉ для модСлирования Π½Π΅Ρ„Ρ‚Π΅Π³Π°Π·ΠΎΠ²Ρ‹Ρ… мСстороТдСний. Π‘Ρ„ΠΎΡ€ΠΌΡƒΠ»ΠΈΡ€ΠΎΠ²Π°Π½Ρ‹ ΠΊΡ€ΠΈΡ‚Π΅Ρ€ΠΈΠΈ ΠΎΡ†Π΅Π½ΠΊΠΈ Π±Π°Π·ΠΎΠ²Ρ‹Ρ… ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½Ρ‹Ρ… систСм, ΠΊΠΎΡ‚ΠΎΡ€Ρ‹ΠΌΠΈ слСдуСт Ρ€ΡƒΠΊΠΎΠ²ΠΎΠ΄ΡΡ‚Π²ΠΎΠ²Π°Ρ‚ΡŒΡΡ ΠΏΡ€ΠΈ обосновании Π²Ρ‹Π±ΠΎΡ€Π°. Π”Π°Π½ΠΎ Ρ„ΠΎΡ€ΠΌΠ°Π»ΠΈΠ·ΠΎΠ²Π°Π½Π½ΠΎΠ΅ описаниС слоТных процСссов гСологичСского ΠΈ гидродинамичСского модСлирования Π½Π΅Ρ„Ρ‚Π΅Π³Π°Π·ΠΎΠ²Ρ‹Ρ… мСстороТдСний с использованиСм Ρ†ΠΈΡ„Ρ€ΠΎΠ²Ρ‹Ρ… 3D-ΠΌΠΎΠ΄Π΅Π»Π΅ΠΉ ΠΈ ΠΏΠΎΠ΄Π΄Π΅Ρ€ΠΆΠΈΠ²Π°ΡŽΡ‰ΠΈΡ… ΠΈΡ… ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ½Ρ‹Ρ… систСм

    Анализ ΠΈ интСрпрСтация гидродинамичСских исслСдований для Π΄Π²ΡƒΡ…Ρ„Π°Π·Π½ΠΎΠ³ΠΎ ΠΏΠΎΡ‚ΠΎΠΊΠ° (Π²ΠΎΠ΄Π°-Π½Π΅Ρ„Ρ‚ΡŒ)

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    ΠŸΠΎΠΊΠ°Π·Π°Π½Ρ‹ ΠΏΡ€ΠΎΠ±Π»Π΅ΠΌΡ‹, Π²ΠΎΠ·Π½ΠΈΠΊΠ°ΡŽΡ‰ΠΈΠ΅ ΠΏΡ€ΠΈ ΠΈΠ½Ρ‚Π΅Ρ€ΠΏΡ€Π΅Ρ‚Π°Ρ†ΠΈΠΈ ΠΈ Π°Π½Π°Π»ΠΈΠ·Π΅ Π΄Π°Π½Π½Ρ‹Ρ… гидродинамичСских исслСдований, ΠΏΡ€ΠΎΠ²Π΅Π΄Π΅Π½Π½Ρ‹Ρ… Π½Π° скваТинах с ΠΎΠ±Π²ΠΎΠ΄Π½Π΅Π½Π½ΠΎΡΡ‚ΡŒΡŽ, ΠΎΡ‚Π»ΠΈΡ‡Π½ΠΎΠΉ ΠΎΡ‚ нуля. Π Π°Π·ΠΎΠ±Ρ€Π°Π½Ρ‹ прСимущСства ΠΈ нСдостатки примСняСмых ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ² ΠΈΠ½Ρ‚Π΅Ρ€ΠΏΡ€Π΅Ρ‚Π°Ρ†ΠΈΠΈ ΠΈ Π°Π½Π°Π»ΠΈΠ·Π°. ΠŸΡ€Π΅Π΄ΡΡ‚Π°Π²Π»Π΅Π½ Π½ΠΎΠ²Ρ‹ΠΉ ΠΌΠ΅Ρ‚ΠΎΠ΄ Π½ΠΎΡ€ΠΌΠ°Π»ΠΈΠ·Π°Ρ†ΠΈΠΈ подвиТности для Π°Π½Π°Π»ΠΈΠ·Π° Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚ΠΎΠ² гидродинамичСских исслСдований скваТин

    ЭлСктроосаТдСниС сплава свинСц-ΠΎΠ»ΠΎΠ²ΠΎ ΠΈΠ· ΠΌΠ΅Ρ‚Π°Π½ΡΡƒΠ»ΡŒΡ„ΠΎΠ½Π°Ρ‚Π½Ρ‹Ρ… растворов

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    ДослідТСно Π²ΠΏΠ»ΠΈΠ² Ρ€Ρ–Π·Π½ΠΈΡ… Ρ‡ΠΈΠ½Π½ΠΈΠΊΡ–Π² Π½Π° склад сплаву ΡΠ²ΠΈΠ½Π΅Ρ†ΡŒ-ΠΎΠ»ΠΎΠ²ΠΎ, Ρ‰ΠΎ осадТСний Π· Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ»Ρ–Ρ‚Ρƒ Π½Π° основі ΠΌΠ΅Ρ‚Π°Π½ΡΡƒΠ»ΡŒΡ„ΠΎΠ½Π°Ρ‚Π½ΠΎΡ— кислоти. ΠœΠ΅Ρ‚ΠΎΠ΄ΠΎΠΌ ΠΏΠΎΠ²Π½ΠΎΠ³ΠΎ Ρ„Π°ΠΊΡ‚ΠΎΡ€Π½ΠΎΠ³ΠΎ СкспСримСнту ΠŸΠ€Π•2Β³ ΠΎΡ‚Ρ€ΠΈΠΌΠ°Π½Ρ– рівняння рСгрСсії, Ρ‰ΠΎ Π°Π΄Π΅ΠΊΠ²Π°Ρ‚Π½ΠΎ ΠΎΠΏΠΈΡΡƒΡŽΡ‚ΡŒ Π·Π°Π»Π΅ΠΆΠ½Ρ–ΡΡ‚ΡŒ вмісту ΠΎΠ»ΠΎΠ²Π° Π² сплаві Π²Ρ–Π΄ ΡƒΠΌΠΎΠ² осадТСння Π· Π΅Π»Π΅ΠΊΡ‚Ρ€ΠΎΠ»Ρ–Ρ‚Ρ–Π² Ρ–Π· ΠΎΡ€Π³Π°Π½Ρ–Ρ‡Π½ΠΈΠΌΠΈ Π΄ΠΎΠ±Π°Π²ΠΊΠ°ΠΌΠΈ Ρ– Π±Π΅Π· Π½ΠΈΡ….Effect of different factors on content of lead-tin alloys obtained from an electrolyte on the base of methanesulfonic acid is investigated. The method of full factor experiment FFE 2Β³ is used for obtaining of regression equations which adequately describe the relation between the electrodeposition condition and the contents of tin in alloys from electrolytes with and without some organic additives

    Nano- to Millimeter Scale Morphology of Connected and Isolated Porosity in the Permo-Triassic Khuff Formation of Oman

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    Carbonate reservoirs form important exploration targets for the oil and gas industry in many parts of the world. This study aims to differentiate and quantify pore types and their relation to petrophysical properties in the Permo-Triassic Khuff Formation, a major carbonate reservoir in Oman. For that purpose, we have employed a number of laboratory techniques to test their applicability for the characterization of respective rock types. Consequently, a workflow has been established utilizing a combined analysis of petrographic and petrophysical methods which provide the best results for pore-system characterization. Micro-computed tomography (ΞΌCT) analysis allows a representative 3D assessment of total porosity, pore connectivity, and effective porosity of the ooid-shoal facies but it cannot resolve the full pore-size spectrum of the highly microporous mud-/wackestone facies. In order to resolve the smallest pores, combined mercury injection capillary pressure (MICP), nuclear magnetic resonance (NMR), and BIB (broad ion beam)-SEM analyses allow covering a large pore size range from millimeter to nanometer scale. Combining these techniques, three different rock types with clearly discernible pore networks can be defined. Moldic porosity in combination with intercrystalline porosity results in the highest effective porosities and permeabilities in shoal facies. In back-shoal facies, dolomitization leads to low total porosity but well-connected and heterogeneously distributed vuggy and intercrystalline pores which improves permeability. Micro- and nanopores are present in all analyzed samples but their contribution to effective porosity depends on the textural context. Our results confirm that each individual rock type requires the application of appropriate laboratory techniques. Additionally, we observe a strong correlation between the inverse formation resistivity factor and permeability suggesting that pore connectivity is the dominating factor for permeability but not pore size. In the future, this relationship should be further investigated as it could potentially be used to predict permeability from wireline resistivity measured in the flushed zone close to the borehole wall

    ВСнтиляция ΡˆΠ°Ρ…Ρ‚ ΠΈ Ρ€ΡƒΠ΄Π½ΠΈΠΊΠΎΠ²

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    РассмотрСны структура ΠΈ основныС элСмСнты ΡˆΠ°Ρ…Ρ‚Π½Ρ‹Ρ… вСнтиляционных систСм, способы ΠΈ схСмы провСтривания ΡˆΠ°Ρ…Ρ‚, Ρ€ΡƒΠ΄Π½ΠΈΠΊΠΎΠ², ΠΊΠ°Ρ€ΡŒΠ΅Ρ€ΠΎΠ², вСнтиляции Π²Ρ‹Π΅ΠΌΠΎΡ‡Π½Ρ‹Ρ… участков ΠΈ Ρ‚ΡƒΠΏΠΈΠΊΠΎΠ²Ρ‹Ρ… Π²Ρ‹Ρ€Π°Π±ΠΎΡ‚ΠΎΠΊ. Π—Π°Ρ‚Ρ€ΠΎΠ½ΡƒΡ‚Ρ‹, исслСдованы вопросы обоснования ΠΈ Π²Ρ‹Π±ΠΎΡ€Π° ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² систСм вСнтиляции, характСристик тСхничСских срСдств, ΠΎΠ±Π΅ΡΠΏΠ΅Ρ‡ΠΈΠ²Π°ΡŽΡ‰ΠΈΡ… ΠΈΡ… расчСтныС значСния ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€ΠΎΠ² систСм вСнтиляции. ПособиС соотвСтствуСт ΠΏΡ€ΠΎΠ³Ρ€Π°ΠΌΠΌΠ΅ курса «ВСнтиляция ΡˆΠ°Ρ…Ρ‚ ΠΈ Ρ€ΡƒΠ΄Π½ΠΈΠΊΠΎΠ²Β» для студСнтов ΡΠΏΠ΅Ρ†ΠΈΠ°Π»ΡŒΠ½ΠΎΡΡ‚ΠΈ Β«Π Π°Π·Ρ€Π°Π±ΠΎΡ‚ΠΊΠ° мСстороТдСний ΠΈ Π΄ΠΎΠ±Ρ‹Ρ‡Π° ΠΏΠΎΠ»Π΅Π·Π½Ρ‹Ρ… ископаСмых» ΠΈ ΠΌΠΎΠΆΠ΅Ρ‚ Π±Ρ‹Ρ‚ΡŒ использовано ΠΏΡ€ΠΈ ΠΏΠΎΠ΄Π³ΠΎΡ‚ΠΎΠ²ΠΊΠ΅ ΠΈ ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΠΈ ΠΊΠ²Π°Π»ΠΈΡ„ΠΈΠΊΠ°Ρ†ΠΈΠΈ ΠΈΠ½ΠΆΠ΅Π½Π΅Ρ€Π½ΠΎ-тСхничСских Ρ€Π°Π±ΠΎΡ‚Π½ΠΈΠΊΠΎΠ² Π³ΠΎΡ€Π½Ρ‹Ρ… прСдприятий, Π° Ρ‚Π°ΠΊΠΆΠ΅ студСнтами Π΄Ρ€ΡƒΠ³ΠΈΡ… ΡΠΏΠ΅Ρ†ΠΈΠ°Π»ΡŒΠ½ΠΎΡΡ‚Π΅ΠΉ, ΠΎΠ±ΡƒΡ‡Π°ΡŽΡ‰ΠΈΡ…ΡΡ ΠΏΠΎ Π½Π°ΠΏΡ€Π°Π²Π»Π΅Π½ΠΈΡŽ Β«Π“ΠΎΡ€Π½ΠΎΠ΅ Π΄Π΅Π»ΠΎΒ»

    Two-dimensional X-ray diffraction as a tool for the rapid, non-destructive detection of low calcite quantities in aragonitic corals

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    Paleoclimate reconstructions based on reef corals require precise detection of diagenetic alteration. Secondary calcite can significantly affect paleotemperature reconstructions at very low amounts of ~1%. X-ray powder diffraction is routinely used to detect diagenetic calcite in aragonitic corals. This procedure has its limitations as single powder samples might not represent the entire coral heterogeneity. A conventional and a 2-D X-ray diffractometer were calibrated with gravimetric powder standards of high and low magnesium calcite (0.3% to 25% calcite). Calcite contents <1% can be recognized with both diffractometer setups based on the peak area of the calcite [104] reflection. An advantage of 2-D-XRD over convenient 1-D-XRD methods is the nondestructive and rapid detection of calcite with relatively high spatial resolution directly on coral slabs. The calcite detection performance of the 2-D-XRD setup was tested on thin sections from fossil Porites sp. samples that, based on powder XRD measurements, showed <1% calcite. Quantification of calcite contents for these thin sections based on 2-D-XRD and digital image analysis showed very similar results. This enables spot measurements with diameters of ∼4 mm, as well as systematic line scans along potential tracks previous to geochemical proxy sampling. In this way, areas affected by diagenetic calcite can be avoided and alternative sampling tracks can be defined. Alternatively, individual sampling positions that show dubious proxy results can later be checked for the presence of calcite. The presented calibration and quantification method can be transferred to any 2-D X-ray diffractometer

    Modern and sub-fossil corals suggest reduced temperature variability in the eastern pole of the Indian Ocean Dipole during the medieval climate anomaly

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    We present two 40 year records of monthly coral Sr/Ca ratios from the eastern pole of the Indian Ocean Dipole. A modern coral covers the period from 1968 to 2007. A sub-fossil coral derives from the medieval climate anomaly (MCA) and spans 1100–1140 ad. The modern coral records SST variability in the eastern pole of the Indian Ocean Dipole. A strong correlation is also found between coral Sr/Ca and the IOD index. The correlation with ENSO is asymmetric: the coral shows a moderate correlation with El NiΓ±o and a weak correlation with La NiΓ±a. The modern coral shows large interannual variability. Extreme IOD events cause cooling > 3 Β°C (1994, 1997) or ~ 2 Β°C (2006). In total, the modern coral indicates 32 warm/cool events, with 16 cool and 16 warm events. The MCA coral shows 24 warm/cool events, with 14 cool and 10 warm events. Only one cool event could be comparable to the positive Indian Ocean Dipole in 2006. The seasonal cycle of the MCA coral is reduced (< 50% of to the modern) and the skewness of the Sr/Ca data is lower. This suggests a deeper thermocline in the eastern Indian Ocean associated with a La NiΓ±a-like mean state in the Indo-Pacific during the MCA

    Indonesian Throughflow drove Australian climate from humid Pliocene to arid Pleistocene

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    Late Miocene to mid-Pleistocene sedimentary proxy records reveal that northwest Australia underwent an abrupt transition from dry to humid climate conditions at 5.5 million years (Ma), likely receiving year-round rainfall, but after ~3.3 Ma, climate shifted toward an increasingly seasonal precipitation regime. The progressive constriction of the Indonesian Throughflow likely decreased continental humidity and transferred control of northwest Australian climate from the Pacific to the Indian Ocean, leading to drier conditions punctuated by monsoonal precipitation. The northwest dust pathway and fully established seasonal and orbitally controlled precipitation were in place by ~2.4 Ma, well after the intensification of Northern Hemisphere glaciation. The transition from humid to arid conditions was driven by changes in Pacific and Indian Ocean circulation and regional atmospheric moisture transport, influenced by the emerging Maritime Continent. We conclude that the Maritime Continent is the switchboard modulating teleconnections between tropical and high-latitude climate systems
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