195 research outputs found
Directional Doppler bloodflow meter Progress report
Ultrasonic blood flowmeter using Doppler effect in acoustic scattering from moving corpuscle
Preliminary evaluation of infrared and radar imagery, Washington and Oregon coasts
Airborne infrared and radar photography of Oregon and Washington coastal region
Variability in sonic-boom signatures measured along an 8000-foot linear array
Variability in sonic boom signatures measured along 8000 foot linear microphone arra
Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene
Indexación: ScieloThis work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072009000300014&lng=es&nrm=is
Hydrocarbon oxidation catalyzed by iron and manganese porphyrins anchored on aminofunctionalized supports
The second-generation metalloporphyrins (MePs) [5,10,15,20-tetrakis(pentafluorophenyl)porphyrin iron(III)] chloride, FeP, and [5,10,15,20-tetrakis(pentafluorophenyl)porphyrin manganese(III)] chloride, MnP, were covalently attached to aminofunctionalized supports, with a view to preparing selective solid catalysts for the oxidation of organic compounds. Montmorillonite K10 functionalized with 3-aminopropyltriethoxysilane (Mont1) or modified with 3-chloropropyltriethoxysilane followed by reaction with 1,6-diaminohexane (Mont2), and silica gel functionalized with 3-aminopropyltriethoxysilane (Sil1) or modified with 3-chloropropyltriethoxysilane followed by reaction with 1,6-diaminohexane (Sil2) were synthesized and characterized by UV-Vis and IR spectroscopies, EPR, TGA, and X-ray diffractometry. The catalytic activities of the MePs immobilized on these supports were investigated for the oxidation of (Z)-cyclooctene, cyclohexane and styrene by PhIO or H2O2. The studied systems were efficient catalysts for the oxidation of all substrates, especially when PhIO was the oxidant. There was no MeP leaching from the supports, indicating that covalent binding is a very efficient method for catalyst immobilization. The immobilized FePs were more efficient catalysts than the corresponding MnPs, even when imidazole was employed as a cocatalyst for the supported MnPs. Although the yields of oxidized products obtained with H2O2 were lower than those achieved with PhIO, some heterogeneous MeP systems were more efficient than the parent MePs in solution, both in terms of product yield and selectivity.As metaloporfirinas de segunda geração (MePs), cloreto de [5,10,15,20-tetraquis(pentafluorofenil)porfirinaferro(III)], FeP, e cloreto de [5,10,15,20-tetraquis(pentafluorofenil)porfirinamanganês(III)], MnP, foram covalentemente ancoradas em suportes aminofuncionalizados, com o objetivo de preparar catalisadores sólidos seletivos para a oxidação de compostos orgânicos. Montmorillonita K10 funcionalizada com 3-aminopropiltrietoxissilano (Mont1) ou com 3-cloropropiltrietoxissilano seguida por reação com 1,6-diaminoexano (Mont2), e sílica gel funcionalizada com 3-aminopropiltrietoxissilano (Sil1) ou modificada com 3-cloropropiltrietoxissilano seguida por reação com 1,6-diaminoexano (Sil2) foram preparadas e caracterizadas por UV-Vis, IR, EPR, TGA e difratometria de raios X. As atividades catalíticas das MePs imobilizadas nestes suportes foram investigadas na oxidação de (Z)-cicloocteno, cicloexano e estireno por iodosilbenzeno (PhIO) ou H2O2. Os sistemas estudados foram catalisadores eficientes da oxidação de todos os substratos, especialmente utilizando PhIO como oxidante. Não se observou lixiviamento das MePs dos suportes, indicando que a ligação covalente é um método muito eficiente para a imobilização de catalisadores. As FePs imobilizadas foram catalisadores mais eficientes que as correspondentes MnPs, mesmo quando imidazol foi empregado como um co-catalisador para as MnPs ancoradas. Embora os rendimentos de produtos oxidados utilizando H2O2 tenham sido mais baixos que aqueles obtidos com PhIO, alguns sistemas heterogêneos envolvendo MePs foram mais eficientes que as correspondentes MePs em solução, tanto em termos de rendimento de produto quanto de seletividade.FAPESPCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)CNP
Stationary Kolmogorov Solutions of the Smoluchowski Aggregation Equation with a Source Term
In this paper we show how the method of Zakharov transformations may be used
to analyze the stationary solutions of the Smoluchowski aggregation equation
for arbitrary homogeneous kernel. The resulting massdistributions are of
Kolmogorov type in the sense that they carry a constant flux of mass from small
masses to large. We derive a ``locality criterion'', expressed in terms of the
asymptotic properties of the kernel, that must be satisfied in order for the
Kolmogorov spectrum to be an admissiblesolution. Whether a given kernel leads
to a gelation transition or not can be determined by computing the mass
capacity of the Kolmogorov spectrum. As an example, we compute the exact
stationary state for the family of
kernels, which includes both gelling and
non-gelling cases, reproducing the known solution in the case .
Surprisingly, the Kolmogorov constant is the same for all kernels in this
family.Comment: This article is an expanded version of a talk given at IHP workshop
"Dynamics, Growth and Singularities of Continuous Media", Paris July 2003.
Updated 01/04/04. Revised version with additional discussion, references
added, several typographical errors corrected. Revised version accepted for
publication by Phys. Rev.
Scientific Objectives of Einstein Telescope
The advanced interferometer network will herald a new era in observational
astronomy. There is a very strong science case to go beyond the advanced
detector network and build detectors that operate in a frequency range from 1
Hz-10 kHz, with sensitivity a factor ten better in amplitude. Such detectors
will be able to probe a range of topics in nuclear physics, astronomy,
cosmology and fundamental physics, providing insights into many unsolved
problems in these areas.Comment: 18 pages, 4 figures, Plenary talk given at Amaldi Meeting, July 201
Correction: A european spectrum of pharmacogenomic biomarkers: Implications for clinical pharmacogenomics (PLoS ONE (2016) 11:9 (e0162866) DOI: 10.1371/journal.pone.0162866)
The thirty-Third author's name is spelled incorrectly. The correct name is: Jadranka Sertić
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