32 research outputs found
Magnetic fullerenes inside single-wall carbon nanotubes
C59N magnetic fullerenes were formed inside single-wall carbon nanotubes by
vacuum annealing functionalized C59N molecules encapsulated inside the tubes. A
hindered, anisotropic rotation of C59N was deduced from the temperature
dependence of the electron spin resonance spectra near room temperature.
Shortening of spin-lattice relaxation time, T_1, of C59N indicates a reversible
charge transfer toward the host nanotubes above K. Bound C59N-C60
heterodimers are formed at lower temperatures when C60 is co-encapsulated with
the functionalized C59N. In the 10-300 K range, T_1 of the heterodimer shows a
relaxation dominated by the conduction electrons on the nanotubes
Testing the Elliott-Yafet spin-relaxation mechanism in KC8; a model system of biased graphene
Temperature dependent electron spin resonance (ESR) measurements are reported
on stage 1 potassium doped graphite, a model system of biased graphene. The ESR
linewidth is nearly isotropic and although the g-factor has a sizeable
anisotropy, its majority is shown to arise due to macroscopic magnetization.
Albeit the homogeneous ESR linewidth shows an unusual, non-linear temperature
dependence, it appears to be proportional to the resistivity which is a
quadratic function of the temperature. These observations suggests the validity
of the Elliott-Yafet relaxation mechanism in KC8 and allows to place KC8 on the
empirical Beuneu-Monod plot among ordinary elemental metals.Comment: 6 pages, 4 figures, submitted to Phys. Rev.
Enhanced thermal stability and spin-lattice relaxation rate of N@C60 inside carbon nanotubes
We studied the temperature stability of the endohedral fullerene molecule,
N@C60, inside single-wall carbon nanotubes using electron spin resonance
spectroscopy. We found that the nitrogen escapes at higher temperatures in the
encapsulated material as compared to its pristine, crystalline form. The
temperature dependent spin-lattice relaxation time, T_1, of the encapsulated
molecule is significantly shorter than that of the crystalline material, which
is explained by the interaction of the nitrogen spin with the conduction
electrons of the nanotubes.Comment: 5 pages, 4 figures, 1 tabl
PtOx-SnOx-TiO2 catalyst system for methanol photocatalytic reforming: Influence of cocatalysts on the hydrogen production
Effects of modification of PtOx-TiO2 photocatalysts by tin were elucidated by exploring relationships between the structural properties of variously prepared tin-loaded catalysts and their catalytic activity in methanol photocatalytic reforming. Tin free and amorphous tin-oxide decorated TiO2 samples were prepared by sol-gel method from titanium-isopropoxide. In other approach, Sn was loaded onto the sol-gel prepared TiO2 by impregnation followed by calcination. Pt was introduced by impregnation followed by either reduction in H2 at 400 °C or calcination at 300 °C. TEM, XRD and Raman spectroscopic measurements proved that TiO2 existed in the form of aggregates of polycrystalline anatase with primary particle size of 15–20 nm in all samples. Photocatalytic hydrogen production was influenced by the combined effect of many parameters. Both the presence of Sn and the way of Pt co-catalyst formation played important role in the activity of these photocatalysts. The Sn introduction by both sol-gel method and impregnation clearly enhanced the photocatalytic activity. 1H MAS NMR measurements revealed that the Sn introduction reduced the amount of the terminal Ti-OH groups of relatively basic character considered to be unfavorable for the photocatalytic reaction. Presence of SnOx decreased the signal of the undesirable vacancies observed by ESR. Furthermore surface SnOx enhanced the dispersion of Pt. Formation of the Pt co-catalyst by calcination was more favorable than by H2 treatment. In case of the calcined samples in situ reduction of the Pt nanoparticles at the beginning of the photocatalytic reaction was found to be favorable for the hydrogen production. The relatively modest photocatalytical activity obtained after high temperature H2 treatment could be related to at least two processes in this system: (i) creation of unfavorable oxygen vacancies and (ii) segregation of SnOx to the surface of the Pt cocatalyst as the result of the air exposure of the alloy type Pt-Sn nanoparticles formed during the H2 treatment, resulting in a decreased number of active sites for reduction of H+
Low temperature fullerene encapsulation in single wall carbon nanotubes: synthesis of N@C@SWCNT
High filling of single wall carbon nanotubes (SWCNT) with C and
C fullerenes in solvent is reported at temperatures as low as 69
C. A 2 hour long refluxing in n-hexane of the mixture of the fullerene
and SWCNT results in a high yield of C,C@SWCNT, fullerene peapod,
material. The peapod filling is characterized by TEM, Raman and electron energy
loss spectroscopy and X-ray scattering. We applied the method to synthesize the
temperature sensitive (N@C:C)@SWCNT as proved by electron spin
resonance spectroscopy. The solvent prepared peapod samples can be transformed
to double walled nanotubes enabling a high yield and industrially scalable
production of DWCNT
Relationship between solid state structure and solution stability of copper(ii)-hydroxypyridinecarboxylate complexes
The complementary solid state/solution studies of the systematic series of bioactive ligands 3-hydroxy-
1-methyl-4-pyridinecarboxylate (L1), 3-hydroxy-1,2,6-trimethyl-4-pyridinecarboxylate (L2), 4-hydroxy-1-
methyl-3-pyridinecarboxylate (L3), 4-hydroxy-1,6-dimethyl-3-pyridinecarboxylate (L4), 4-hydroxy-1-(2-
hydroxyethyl)-6-methyl-3-pyridinecarboxylate (L5) and 4-hydroxy-1-(2-carboxyethyl)-6-methyl-3-
pyridinecarboxylate (L6) with copper(II) have been performed in order to design efficient chelating drugs
for the treatment of metal overloading conditions. Single crystals of [Cu(L1)2(H2O)]3H2O (1) (monomer) with
axial water coordination, [Cu2(L2)4]6H2O (2) and [Cu2(L3)4]4H2O (3) (cyclic dimers), where pyridinolato and
carboxylato oxygens, respectively, act as linkers between adjacent copper complexes, [Cu(L4)2]n3H2O (4) (1D
polymer) and [Cu3(L5)6]18H2O (5) (trimer), constructed using two square-pyramidal and one elongated
octahedral Cu(II) complexes have been determined by SXRD. The bidentate coordination mode of the ligands
has been found preferentially with cis arrangements in 1 and 2 and trans arrangements in 3\u20135. The solution
speciation and complex stability of aqueous solutions have been studied by pH-dependent electron
paramagnetic resonance spectroscopy resulting in the detection of solely monomeric [CuL]+ and [CuL2]
complexes. The stability order obtained for the [CuL]+ complexes could be correlated with the deprotonation
constants of their hydroxyl group (log bLH) reflecting that the higher acidity increases the complex stability in
the order L2 o L1 E L6 o L4 E L5 o L3. This stability order elucidates the different axial linkers in the
cyclic dimers 2 and 3. DFT quantum-chemical calculations support the effect of the electron distribution on
the established stability order
Spin-Probe ESR Studies on Nanocomposite Polymer Electrolytes
The possibility of using spin-probe electron spin resonance (ESR) as a tool to study glass transition temperature, T g, of polymer electrolytes is explored in 4 hydroxy 2,2,6,6 tetramethylpiperidine N oxyl (TEMPOL) doped composite polymer electrolyte (PEG)46LiClO4 dispersed with nanoparticles of hydrotalcite. The T g is estimated from the measured values of T 50G, the temperature at which the extrema separation 2A zz of the broad powder spectrum decreases to 50 G. In another method, the correlation time τc for the spin probe dynamics was determined by computer simulation of the ESR spectra and T g has been identified as the temperature at which τc begins to show temperature dependence. While both methods give values of T g close to those obtained from differential scanning calorimetry, it is concluded that more work is required to establish spin-probe ESR as a reliable technique for the determination of T g