Aspectos de la corrosión atmosférica de aceros autopasivables

Se estudia la corrosión de aceros Corten y Corcap en un medio que representa una atmósfera urbana industrial. Se compara el comportamiento frente a un acero al carbono corriente. La pasivación de los aceros especiales se logra mediante un ensayo acelerado de inmersiones y emersiones alternadas, la velocidad de corrosión instantánea se mide mediante técnicas electroquímicas de resistencia de polarización. Se discute el efecto que tiene un tratamiento térmico sobre el comportamiento a la corrosión. la capa de pasivaciónse determina mediante espectroscopia infrarroja y Mössbauer

The quest to slow ageing through drug discovery

Although death is inevitable, individuals have long sought to alter the course of the ageing process. Indeed, ageing has proved to be modifiable; by intervening in biological systems, such as nutrient sensing, cellular senescence, the systemic environment and the gut microbiome, phenotypes of ageing can be slowed sufficiently to mitigate age-related functional decline. These interventions can also delay the onset of many disabling, chronic diseases, including cancer, cardiovascular disease and neurodegeneration, in animal models. Here, we examine the most promising interventions to slow ageing and group them into two tiers based on the robustness of the preclinical, and some clinical, results, in which the top tier includes rapamycin, senolytics, metformin, acarbose, spermidine, NAD+ enhancers and lithium. We then focus on the potential of the interventions and the feasibility of conducting clinical trials with these agents, with the overall aim of maintaining health for longer before the end of life

High flux solar simulators for concentrated solar thermal research: A review

When the availability of solar radiation is not enough to develop experimental investigation in the field of concentrating solar energy, solar simulators are a widely employed solution. They represent a source of artificial light, which can be comparable with concentrated sunlight. Besides, they provide advantages such as better parametric control of the process under study. In this work, it is presented an extensive review of the high flux solar simulators that are available in the different solar energy research centers around the world. Many of them are similarly designed and have common elements. Others are based on different concepts and their particular features are also pointed out. The main applications of solar simulators reported in literature are discussed along the work and remarked then in a specific section.The authors acknowledge the financial support provided by the FONDECYT project number 3150026 of CONICYT (Chile), the Education Ministry of Chile Grant PMI ANT 1201, as well as CONICYT/FONDAP/15110019 "Solar Energy Research Center" SERC-Chile. In addition, the first author wish to thank the University of Almeria and the Plataforma Solar de Almería for the collaboration and assistance devoted to the development of his Ph.D research

A lab-scale rotary kiln for thermal treatment of particulate materials under high concentrated solar radiation: Experimental assessment and transient numerical modeling

Rotary kilns are worldwide used for industrial processes that involve thermal treatments of particulate materials. However, a great amount of fossil fuels is employed in such processes. As alternative, solar rotary kilns are considered for this application due to their versatility and potential to substitute traditional fossil-fuel driven devices. In order to boost the development of this technology, efforts have to be focused on the control of the particle temperature during the treatment. In this context, a lab-scale rotary kiln was built and tested using a 7- kWe high-flux solar simulator at University of Antofagasta. It was conceived to treat particulate materials of different nature and it is able to reach temperatures higher than 800 °C under different operation strategies. Silicon carbide was selected for initial tests because it is inert, endures high temperatures (up to 1600 °C) and it has been proposed as thermal storage vector in several researches on concentrated solar power. In a first stage, the empty kiln was preheated up to about 800 °C, reaching a steady state in less than three hours and with a power of approximately 370 W entering the kiln cavity. Afterwards, 43 g of silicon carbide were introduced in the furnace and the system was heated again up to a second steady state above 800 °C. In this stage, particles showed a fast increment of their temperature and exceeded 700 °C in less than three minutes after loading. A one-dimensional transient numerical model was also developed to perform the thermal analysis of the kiln and the estimation of both the particle temperature and the system efficiency. Numerical results showed good agreement with experimental data and thermal losses could be quantified in detail. Therefore, the model was also used to predict the thermal behavior of a solar rotary kiln working in batch mode.The authors acknowledge the financial support provided by the FONDECYT project number 3150026 of CONICYT (Chile), the Education Ministry of Chile Grant PMI ANT 1201, as well as CONICYT/ FONDAP/15110019 “Solar Energy Research Center” SERC-Chile. The authors also gratefully acknowledge the financial support received from the Sectorial Fund CONACYT-SENER-Energy Sustainability, through grant 207450, Mexican Center for Innovation in Solar Energy (CeMIE-Sol), whithin strategic project P-10 “Solar Fuels and Industrial Processes” (COSOLpi). Special thanks go to the students Lou Cardinale, Rodrigo Méndez, and Daniel Vidal who gave a precious contribution during the experimental trials at LaCoSA of University of Antofagasta

Use of rotary kilns for solar thermal applications: Review of developed studies and analysis of their potential

Rotary kilns have a long history of use in classical industries. They are able to achieve high temperatures with higher thermal efficiencies than other reactor types. Their performance has been widely studied and classified according to different parameters. Since it is a well-known technology, rotary kilns have been selected for high temperature solar processes. This article initially presents a brief review of the rotary kiln technology and it focuses on the employment of these devices for thermal and thermochemical processes conducted by concentrating solar energy. Among the solar devices, a novel rotary kiln prototype for thermochemical processes is presented and compared with a static solar reactor. Finally, some practical conclusions on the design and operation of solar rotary kilns are remarked and an analysis of their main limitations is presented.The authors acknowledge the financial support provided by the FONDECYT project number 3150026 of CONICYT (Chile), the Education Ministry of Chile Grant PMI ANT 1201, as well as CONICYT/FONDAP/ 15110019 ‘‘Solar Energy Research Center” SERC-Chile. Also, the second author wish to thank to the Plataforma Solar de Almería and the University of Almería for the collaboration and assistance devoted to the development of his Ph.D research

Efeitos da propriedade estrangeira e das Normas Internacionais de Relato Financeiro no vencimento da dívida em empresas chilenas

The objective of this article is to determine the effects of foreign ownership and International Financial Reporting Standards (IFRS) on debt maturity in Chilean companies. The study uses a fractional response model (FRM) on 20,586 companies. The results show foreign ownership has a negative and non-linear effect. Foreign ownership in Chilean firms is a substitute control means in relation to long-term debt. IFRS reduces maturity in large companies and extends them in small and medium enterprises (SMEs). These results suggest it is more important for large firms to control agency conflicts, while it is more important for SMEs to reduce information asymmetry.El objetivo de este artículo es determinar los efectos de la propiedad extranjera y de las Normas Internacionales de Información Financiera (NIIF) sobre la madurez de la deuda en las empresas chilenas. En el estudio se utiliza un modelo de respuesta fraccional (MRF) sobre 20.586 empresas. Los resultados demuestran que la propiedad extranjera tiene un efecto negativo y no lineal, transformándose en un medio de control sustituto en relación con la deuda de largo plazo. Las NIIF reducen la madurez en empresas grandes y la extiende en las pequeñas y medianas empresas (Pymes). Estos resultados sugieren que para las firmas grandes es más importante controlar conflictos de agencia, mientras que para las Pymes es más importante reducir las asimetrías de información.O objetivo deste artigo é determinar os efeitos da propriedade estrangeira e das Normas Internacionais de Relato Financeiro (IFRS) no ven- cimento da dívida em empresas chilenas. O estudo utiliza um Modelo de Resposta Fracionária (MRF) em 20.586 empresas. Os resultados mostram que a propriedade estrangeira tem efeito negativo e não linear, tornando-se um meio de controle substituto em relação à dívida de longo prazo. O IFRS reduz a maturidade em grandes empresas e as estende em Pequenas e Médias Empresas (PMEs). Esses resultados sugerem que, para grandes empresas, é mais importante controlar conflitos entre agências, enquanto para as PMEs é mais importante reduzir as assimetrias de informações

VO2 indirect maximum and fitness age of sedentary and non-sedentary

El objetivo es: comparar la edad cronológica con la edad fitness obtenida por medio del VO2 máximo indirecto, de un grupo de personas sedentarias y no sedentarias. Método: 253 personas fueron evaluadas respecto a masa corporal, estatura, perímetro de cintura, frecuencia cardiaca basal y un cuestionario del modelo web "Fitness Calculator". Los resultados demostraron diferencias significativas en las variables antropométricas y fisiológicas entre personas sedentarias y no sedentarias (P<,001). Las personas no sedentarias tienen un mayor VO2máx en comparación con las personas sedentarias. Las personas sedentarias indican que presentan una edad fitness que se encuentra sobre 12 años cronológicos promedio de lo esperado. Conclusión: Las personas sedentarias tienen una mayor edad fitness, esto permite establecer que su cuerpo se deteriora más rápido que los no sedentarios. El bajo VO2 máx es un potente predictor de la capacidad cardiorrespiratoria y se establece como un predictor de enfermedades cardiovascularesThe purpose was to compare chronological age with fitness age obtained through indirect VO2max in a group of sedentary and non-sedentary people. Method: 253 people were evaluated for body mass, height, waist circumference, basal heart rate and a web model questionnaire "Fitness Calculator". The results: showed significant differences in anthropometric and physiological variables between sedentary and non-sedentary people (P <.001). Non- Sedentary people have a greater higher VO2máx group compared to sedentary people. This indicates that sedentary people have a fitness age 12 years over their expected chronological average age. Conclusion: Sedentary people have a higher fitness age; therefore your body deteriorates faster than the nonsedentary people. A low level of VO2máx is a powerful predictor of cardiorespiratory capacity and of cardiovascular diseasesEl estudio fue financiado por la Escuela de Kinesiología de la Universidad Bernardo O`higgin

Identifying Potential Ageing-Modulating Drugs In Silico

Increasing human life expectancy has posed increasing challenges for healthcare systems. As people age, they become more susceptible to chronic diseases, with an increasing burden of multimorbidity, and the associated polypharmacy. Accumulating evidence from work with laboratory animals has shown that ageing is a malleable process that can be ameliorated by genetic and environmental interventions. Drugs that modulate the ageing process may delay or even prevent the incidence of multiple diseases of ageing. To identify novel, anti-ageing drugs, several studies have developed computational drug-repurposing strategies. We review published studies showing the potential of current drugs to modulate ageing. Future studies should integrate current knowledge with multi-omics, health records, and drug safety data to predict drugs that can improve health in late life

Correlation effects in ionic crystals: I. The cohesive energy of MgO

High-level quantum-chemical calculations, using the coupled-cluster approach and extended one-particle basis sets, have been performed for (Mg2+)n (O2-)m clusters embedded in a Madelung potential. The results of these calculations are used for setting up an incremental expansion for the correlation energy of bulk MgO. This way, 96% of the experimental cohesive energy of the MgO crystal is recovered. It is shown that only 60% of the correlation contribution to the cohesive energy is of intra-ionic origin, the remaining part being caused by van der Waals-like inter-ionic excitations.Comment: LaTeX, 20 pages, no figure