Water and nitrogen processes along a typical water flowpath and streamwater exports from a forested catchment and changes after clear-cutting: a modelling study

International audienceA two dimensional model, FEMMA, to describe water and nitrogen (N) fluxes within and from a forested first-order catchment (Kangasvaara in Eastern Finland) was constructed by linking the most significant processes affecting the fluxes of water, ammonium, nitrate and dissolved organic nitrogen along a hillslope from the water divide to the stream. The hillslope represents the average flowpath of water in the catchment and the model was used to estimate the N fluxes for a catchment in eastern Finland before and after clear-cutting. The simulated results were in reasonable agreement with the nitrate, dissolved organic N and dissolved total N measurements from the study catchment and with other results in the literature. According to the simulations, the major sinks of N after clear-cutting were immobilisation by soil microbes, uptake by ground vegetation and sorption to soil. These sinks increased downslope from the clear-cut area, indicating the importance of an uncut buffer zone between the stream and the clear-cut area in reducing N exports. The buffer zone retained 76% of the N flux coming from the clear-cut area. Nitrification was a key process in controlling the N export after clear-cutting and N increases were mainly as nitrate. Most of the annual N export took place during the spring flood, when uptake of N by plants was minimal

Sensitivity of Surface Urban Energy and Water Balance Scheme (SUEWS) to downscaling of reanalysis forcing data

Often the meteorological forcing data required for urban hydrological models are unavailable at the required temporal resolution or for the desired period. Although reanalysis data can provide this information, the spatial resolution is often coarse relative to cities, so downscaling is required prior to use as realistic forcing. In this study, WATCH WFDEI reanalysis data are used to force the Surface Urban Energy and Water Balance Scheme (SUEWS). From sensitivity tests in two cities, Vancouver and London with different orography, we conclude precipitation is the most important meteorological variable to be properly downscaled to obtain reliable surface hydrology results, with relative humidity being the second most important. Overestimation of precipitation in reanalysis data at the three sites gives 6-21% higher annual modelled evaporation, 26-39% higher runoff at one site and 4% lower value at one site when compared to modelled values using observed forcing data. Application of a bias correction method to the reanalysis precipitation reduces the model bias compared to using observed forcing data, when evaluated using eddy covariance evaporation measurements. (c) 2017 Elsevier B.V. All rights reserved.Often the meteorological forcing data required for urban hydrological models are unavailable at the required temporal resolution or for the desired period. Although reanalysis data can provide this information, the spatial resolution is often coarse relative to cities, so downscaling is required prior to use as realistic forcing. In this study, WATCH WFDEI reanalysis data are used to force the Surface Urban Energy and Water Balance Scheme (SUEWS). From sensitivity tests in two cities, Vancouver and London with different orography, we conclude precipitation is the most important meteorological variable to be properly downscaled to obtain reliable surface hydrology results, with relative humidity being the second most important. Overestimation of precipitation in reanalysis data at the three sites gives 6-21% higher annual modelled evaporation, 26-39% higher runoff at one site and 4% lower value at one site when compared to modelled values using observed forcing data. Application of a bias correction method to the reanalysis precipitation reduces the model bias compared to using observed forcing data, when evaluated using eddy covariance evaporation measurements. (c) 2017 Elsevier B.V. All rights reserved.Often the meteorological forcing data required for urban hydrological models are unavailable at the required temporal resolution or for the desired period. Although reanalysis data can provide this information, the spatial resolution is often coarse relative to cities, so downscaling is required prior to use as realistic forcing. In this study, WATCH WFDEI reanalysis data are used to force the Surface Urban Energy and Water Balance Scheme (SUEWS). From sensitivity tests in two cities, Vancouver and London with different orography, we conclude precipitation is the most important meteorological variable to be properly downscaled to obtain reliable surface hydrology results, with relative humidity being the second most important. Overestimation of precipitation in reanalysis data at the three sites gives 6-21% higher annual modelled evaporation, 26-39% higher runoff at one site and 4% lower value at one site when compared to modelled values using observed forcing data. Application of a bias correction method to the reanalysis precipitation reduces the model bias compared to using observed forcing data, when evaluated using eddy covariance evaporation measurements. (c) 2017 Elsevier B.V. All rights reserved.Peer reviewe

Characterization of energy trapping in a bulk acoustic wave resonator

Acoustic wave fields both within the active electrode area of a solidly mounted 1.8 GHz bulk acoustic waveresonator, and around it in the surrounding region, are measured using a heterodyne laser interferometer. Plate-wave dispersion diagrams for both regions are extracted from the measurement data. The experimental dispersion data reveal the cutoff frequencies of the acoustic vibration modes in the region surrounding the resonator, and, therefore, the energy trapping range of the resonator can readily be determined. The measureddispersionproperties of the surrounding region, together with the abruptly diminishing amplitude of the dispersion curves in the resonator, signal the onset of acoustic leakage from the resonator. This information is important for verifying and further developing the simulation tools used for the design of the resonators. Experimental wave field images, dispersion diagrams for both regions, and the threshold for energy leakage are discussed.Peer reviewe

From synchrotrons for XFELs : The soft x-ray near-edge spectrum of the ESCA molecule

A predictive understanding of soft x-ray near-edge absorption spectra of small molecules is an enduring theoretical challenge and of current interest for x-ray probes of molecular dynamics. We report the experimental absorption spectrum for the electron spectroscopy for chemical analysis (ESCA) molecule (ethyl trifluoroacetate) near the carbon 1s absorption edge between 285-300 eV. The ESCA molecule with four chemically distinct carbon sites has previously served as a theoretical benchmark for photoelectron spectra and now for photoabsorption spectra. We report a simple edge-specific approach for systematically expanding standard basis sets to properly describe diffuse Rydberg orbitals and the importance of triple excitations in equation-of-motion coupled-cluster calculations of the energy interval between valence and Rydberg excitations

Extraction of lateral eigenmode properties in thin film bulk acoustic wave resonator from interferometric measurements

A heterodyne laser interferometer is used to study acoustic wave fields excited in a 1.8 GHz AlN thin film bulk acoustic waveresonator. The electrical response of the resonator exhibits a strong thickness resonance onto which spurious modes, caused by lateral standing plate waves, are superposed. Optical interferometermeasurements are used to extract dispersion curves of the laterally propagating waves responsible for the spurious responses. A discrete eigenmode spectrum due to the finite lateral dimensions of the resonator is observed. An equivalent circuit model for a multimode resonator is fitted to the mechanical resonator response extracted along a single curve in the dispersion diagram, and is used to determine properties, such as Q-values, of the individual lateral eigenmodes.Measuredwave field images, extracted dispersion curves, and the eigenmode spectrum with the model fitting results are presented.Peer reviewe

Gliptin-associated Bullous Pemphigoid and the Expression of Dipeptidyl Peptidase-4/CD26 in Bullous Pemphigoid

Dipeptidyl peptidase-4 inhibitors (DPP-4i or gliptins) increase the risk of developing bullous pemphigoid. To clarify, whether gliptin-associated bullous pemphigoid has special features, we analyzed the clinical, histopathological and immunological features of 27 bullous pemphigoid patients, 10 of which previously used gliptin medication. Compared to those who had not previously received gliptins, subjects who had, showed higher BP180-NC16A ELISA (enzyme-linked immunosorbent assay) values, fewer neurological co-morbidities and shorter time to remission, but differences were not statistically significant. The HLA-DQB1* 03: 01 allele was more commonly present among the bullous pemphigoid patients than the control population, but was not more common in those with gliptin history. To determine the effect of gliptins on the expression of the DPP-4/CD-26 protein we performed immunohistochemistry, which showed that the skin expression of DPP-4/CD-26 was increased in bullous pemphigoid patients, but not affected by prior gliptin treatment. We conclude that DPP-4i medication is common among bullous pemphigoid patients and prior gliptin treatment may be associated with some specific features

Variation of size-segregated particle number concentrations in wintertime Beijing

The spatial and temporal variability of the number size distribution of aerosol particles is an indicator of the dynamic behavior of Beijing's atmospheric pollution cocktail. This variation reflects the strength of different primary and secondary sources, such as traffic and new particle formation, as well as the main processes affecting the particle population. In this paper, we report size-segregated particle number concentrations observed at a newly developed Beijing station during the winter of 2018. Our measurements covered particle number size distributions over the diameter range of 1.5 nm-1 mu m (cluster mode, nucleation mode, Aitken mode and accumulation mode), thus being descriptive of a major fraction of the processes taking place in the atmosphere of Beijing. Here we focus on explaining the concentration variations in the observed particle modes, by relating them to the potential aerosol sources and sinks, and on understanding the connections between these modes. We considered haze days and new particle formation event days separately. Our results show that during the new particle formation (NPF) event days increases in cluster mode particle number concentration were observed, whereas during the haze days high concentrations of accumulation mode particles were present. There was a tight connection between the cluster mode and nucleation mode on both NPF event and haze days. In addition, we correlated the particle number concentrations in different modes with concentrations of trace gases and other parameters measured at our station. Our results show that the particle number concentration in all the modes correlated with NOx, which reflects the contribution of traffic to the whole submicron size range. We also estimated the contribution of ion-induced nucleation in Beijing, and we found this contribution to be negligible.Peer reviewe