33 research outputs found
Synthesis and carbene-transfer reactivity of dimeric nickel carbene cations supported by N-heterocyclic carbene ligands
No full textSingle-electron oxidation of N-heterocyclic carbene-supported nickel amides yielding benzylic C–H activation
No full textEthylene oligomerization at coordinatively and electronically unsaturated low-valent nickel
No full text(Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.Link_to_subscribed_fulltex
Ethylene Oligomerization at Coordinatively and Electronically Unsaturated Low-Valent Nickel
No full textNi-Catalyzed Cascade Formation of C(sp3)C(sp3) Bonds by Cyclization and Cross-Coupling Reactions of Iodoalkanes with Alkyl Zinc Halides
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