Application of fullerenes-extracted soot modified with ethylenediamine as a novel adsorbent of hexavalent chromium in water

Fullerenes-extracted soot, the by-product of fullerene synthesis, is a carbon composite. The application of this material for water treatment has not yet been developed. Herein, fullerenes-extracted soot in the form of powder containing amino groups was prepared by reacting the soot with ethylenediamine, and was used as an adsorbent of hexavalent chromium [Cr(VI)] for removing Cr(VI) from aqueous solutions; this removal was studied by batch adsorption experiments. The effect of experimental parameters such as the pH, initial Cr(VI) concentration, and agitation time on the adsorption process was investigated. The adsorption of Cr(VI) was highly pH-dependent and the optimal pH for the adsorption process was 3.0. The data of Cr(VI) adsorption by fullerenes-extracted soot modified with ethylenediamine (FES-ED) fit the Langmuir isotherm equation well. The maximum Cr(VI)-uptake capacity of FES-ED was 93 mg g−1. The desorption of Cr(VI) from the adsorbent was also studied. The adsorbed Cr(VI) was eluted with 20 mL of an aqueous solution with pH 12 and the percentage recovery of Cr(VI) was determined as 75%. The adsorption and desorption test using the same FES-ED powder was repeated in triplicate to examine the reusability of the adsorbent. The adsorption was 97% and the desorption was >70% through the adsorption–desorption cycles. The adsorption of methyl orange onto the FES-ED was also examined. The dye was almost quantitatively removed from the aqueous solution by the adsorbent (the initial concentration of methyl orange: 40 μg mL−1; the adsorbent added: 10 mg/40 mL). Thus, we concluded that the FES-ED can be used as a novel adsorbent for removing pollutants from water.ArticleJournal of Environmental Chemical Engineering. 2(2):1191-1198 (2014)journal articl

Colloidal Composite of Hydroxylated Fullerenes and Gold Nanoparticles

Since bare gold nanoparticles are unstable, they have to be stabilized by protecting with ligands, stabilizing with polymers or immobilizing on solids. Properties of gold nanoparticles depend on the design of their protecting ligands

Systematic Evaluation and Mechanistic Investigation of Antioxidant Activity of Fullerenols Using -Carotene Bleaching Assay

Antioxidant activity of hydroxylated fullerenes, so-called fullerenols, against lipid peroxyl radical was evaluated by -carotene bleaching assay. All samples showed moderate to high antioxidant activity (%AOA), especially for C 60 (OH) 12 (70.1) and C 60 (OH) 44 (66.0) as compared with 8, 24, 26, and 36 hydroxylated ones (31.7-62.8). The detection of the possible products was conducted in the model reaction of both fullerenols and C 60 with methyl linoleate by MALDI-TOF-MS. These results suggested that the two possible mechanisms, such as C-addition to double bonds and H-abstraction from -OH groups, are involved in the present radical scavenging reaction

Effects of Pin-up Oxygen on [60]Fullerene for Enhanced Antioxidant Activity

The introduction of pin-up oxygen on C60, such as in the oxidized fullerenes C60O and C60On, induced noticeable increase in the antioxidant activity as compared to pristine C60. The water-soluble inclusion complexes of fullerenes C60O and C60Onreacted with linoleic acid peroxyl radical 1.7 and 2.4 times faster, respectively

How formation time-scales affect the period dependence of the transition between rocky super-Earths and gaseous sub-Neptunesand implications for η⊕

One of the most significant advances by NASA's ${\mathit Kepler}$ Mission was the discovery of an abundant new population of highly irradiated planets with sizes between the Earth and Neptune. Subsequent analysis showed that at ~1.5 Earth radii there is a transition from a population of predominantly rocky super-Earths to non-rocky sub-Neptunes, which must have substantial volatile envelopes. Determining the origin of these highly irradiated rocky planets will be critical to our understanding of low-mass planet formation and the frequency of potentially habitable Earth-like planets. These short-period rocky super-Earths could simply be the stripped cores of sub-Neptunes, which have lost their envelopes due to atmospheric photo-evaporation or other processes, or they might instead be a separate population of inherently rocky planets, which never had significant envelopes. Using models of atmospheric photo-evaporation, we show that if most bare rocky planets are the evaporated cores of sub-Neptunes then the transition radius should decrease as surveys push to longer orbital periods, since on wider orbits only planets with smaller less massive cores can be stripped. On the other hand, if most rocky planets formed after their disks dissipate then these planets will have formed without initial gaseous envelopes. In this case, we use N-body simulations of planet formation to show that the transition radius should increase with orbital period, due to the increasing solid mass available in their disks. Moreover, we show that distinguishing between these two scenarios should be possible in coming years with radial velocity follow-up of planets found by TESS. Finally, we discuss the broader implications of this work for current efforts to measure $\eta_{\mathrm{\oplus}}$, which may yield significant overestimates if most rocky planets form as evaporated cores.Comment: 8 pages, 4 figures, accepted for publication in the Monthly Notices of the Royal Astronomical Societ

A systematic search for changing-look quasars in SDSS

CLM acknowledges support from the STFC Consolidated Grant (Ref. St/M001229/1). NPR acknowledges support from the STFC and the Ernest Rutherford Fellowship scheme. KH acknowledges support from STFC grant ST/M001296/1. Funding for the SDSS and SDSS-II has been provided by the Alfred P. Sloan Foundation, the Participating Institutions, the National Science Foundation, the US Department of Energy, the National Aeronautics and Space Administration, the Japanese Monbukagakusho, the Max Planck Society, and the Higher Education Funding Council for England.We present a systematic search for changing-look quasars based on repeat photometry from Sloan Digital Sky Survey (SDSS) and Pan-STARRS1, along with repeat spectra from SDSS and SDSS-III Baryon Oscillation Spectroscopic Survey. Objects with large, |Δg| > 1 mag photometric variations in their light curves are selected as candidates to look for changes in broad emission line (BEL) features. Out of a sample of 1011 objects that satisfy our selection criteria and have more than one epoch of spectroscopy, we find 10 examples of quasars that have variable and/or ‘changing-look’ BEL features. Four of our objects have emerging BELs, five have disappearing BELs, and one object shows tentative evidence for having both emerging and disappearing BELs. With redshifts in the range 0.20 15 per cent of strongly variable luminous quasars display changing-look BEL features on rest-frame time-scales of 8 to 10 yr. Plausible time-scales for variable dust extinction are factors of 2–10 too long to explain the dimming and brightening in these sources, and simple dust reddening models cannot reproduce the BEL changes. On the other hand, an advancement such as disc reprocessing is needed if the observed variations are due to accretion rate changes.Publisher PDFPeer reviewe