HEAVY METALS IN CULTIVATED SOIL AND PLANTS OF DAMOUR URBAN AREA - LEBANON

Παρουσιάζονται για πρώτη φορά δεδομένα συγκεντρώσεων βαρέων μετάλλων στο έδαφος και καλλιέργειες της περιοχής Νταμούρ Λιβάνου. Μετρήθηκαν οι ψευδοολικές και κινητοποιήσιμες συγκεντρώσεις των Zn, Cu, Ni, Cr, Co, Mn, Fe, Ba, Pb και Cd σε δείγματα εδαφών καθώς και οι αντίστοιχες ολικές συγκεντρώσεις των ίδιων στοιχείων σε φυτικούς ιστούς λαχανικών που καλλιεργούνται στην περιοχή Δεν ανιχνεύθηκαν συγκεντρώσεις των μη απαραίτητων στοιχείων Pb και Asενώ αυτές των υπόλοιπων στοιχείων που μελετήθηκαν βρίσκονται εντός των φυσιολογικών ορίων. Οι συγκεντρώσεις στο έδαφος φαίνεται να επηρεάζονται από την προηγούμενη χρήση γης και αυτές στα φυτά φαίνεται να ρυθμίζονται μέσω της λειτουργίας σύνθετων μεταβολικών μηχανισμών.Preliminary data on heavy metals concentrations in soil and edible plants of DamourLebanon are presented for the first time. Concentration ranges of Zn, Cu, Ni, Cr, Co, Mn, Fe, Ba, Pb and Cd in soils and vegetables collected from urban allotments in Damour were determined and assessed taking into account the pseudototal (extracted by aqua regia) and mobilizable (0.43 M acetic acid extractable) concentrations of the elements in the rhizosphere soil of the plants as well as the total concentrations in edible plant tissue. Average elemental concentrations in urban allotments are low in general. No detectable concentrations of the non-essential heavy metals Pb and As were measured in the studied plants while concentrations of micronutrient elements in plants were within normal ranges. The collected data indicate that previous land use is an important factor controlling heavy metal content in soil and that there is a complex mechanism controlling micronutrient uptake by plants

Geochemical mapping of urban soils in Athens, Greece - Preliminary results

Η αστική γεωχημεία είναι ένας αναπτυσσόμενος επιστημονικός τομέας κυρίως λόγω των περιβαλλοντικών επιπτώσεων από την εξάπλωση των πόλεων και την αύξηση του αστικού πληθυσμού. Η παρούσα εργασία έχει ως στόχο τη γεωχημική χαρτογράφηση των επιφανειακών (0-10 cm) εδαφών της Αθήνας με έμφαση στη χωρική κατανομή δυνητικά βλαβερών χημικών στοιχείων. Η δειγματοληψία υπαίθρου πραγματοποιήθηκε βάσει τετραγωνικού κανάβου ισοδιάστασης 1 km και κάλυψε συνολική έκταση περίπου 200 km2, με προτεραιότητα σε παιδικές χαρές, σχολεία και πάρκα. Αναλύθηκαν320 εδαφικά δείγματα κοκκομετρίας < 100 μm με την τεχνική της φασματοσκοπίας ατομικής απορρόφησης μετά από διαλυτοποίηση με βασιλικό ύδωρ και προσδιορί- στηκαν τα στοιχεία Pb, Zn, Cu, Cd, Cr, Ni, Co και Mn. Οι μέσες συγκεντρώσεις των στοιχείων Pb (62 mg/kg), Cu (36 mg/kg), Zn (91 mg/kg) και Mn (465 mg/kg) είναι χαμηλότερες των αντίστοιχων συγκεντρώσεων άλλων Ευρωπαϊκών πόλεων ενώ οι συγκεντρώσεις των Cr (74 mg/kg), Ni (89 mg/kg) και Co (16 mg/kg) υψηλότερες. Το γεωχημικό ανάγλυφο αποτυπώθηκε σε περιβάλλον ΓΣΠ δίνοντας τη δυνατότητα προσδιορισμού διαφορετικών πηγών των στοιχείων. Τα αποτελέσματα της έρευνας συμβάλουν στην εκτίμηση της ποιότητας των εδαφών της Αθήνας και αποτελούν πολύτιμο εργαλείο στην αναγνώριση περιοχών περιβαλλοντικής επικινδυνότητας.Urban geochemistry is a fast growing scientific discipline mainly because of the profound impact of large cities on the environment as well as the increase in the world’s urban population. The present study aims to produce the urban geochemical map of Athens, based on multi-element analysis of surface soils (0-10 cm) with emphasis in the spatial distribution of potentially harmful elements (PHEs). Soil sampling was based on a regular 1km x 1km grid, laid over the survey area covering more than 200 km2. Sampling locations within the grid cells were selected giving priority to playgrounds, schools and urban parks. The < 100 μm fraction of a total of 320 soil samples were analysed by Flame Atomic Absorption Spectroscopy for Pb, Zn, Cu, Cd, Cr, Ni, Co and Mn after aqua regia dissolution. Average content of Pb (62 mg/kg), Cu (36 mg/kg), Zn (91 mg/kg) and Mn (465 mg/kg) in soil was lower than reported concentrations from other European cities while Cr (74 mg/kg), Ni (89 mg/kg) and Co (16 mg/kg) were relatively enriched. Geochemical maps were plotted within GIS enabling recognition of spatial trends in elemental concentrations and potential sources of the elements. The research outcome will contribute to the evaluation of quality characteristics of urban soils in Athens and drive attention to areas of any environmental or health risks

HEAVY METALS IN URBAN PARK SOILS FROM ATHENS, GREECE

Η αστική γεωχημεία είναιένας επιστημονικός κλάδος ο οποίος αναπτύσσεταιτα τελευταία χρόνια κυρίως λόγω των περιβαλλοντικών επιπτώσεων που προκύπτουν από την αστικοποίηση. Η παρούσα εργασία έχει ως στόχο τον προσδιορισμό των συγκεντρώσεων δυνητικά επιβλαβών στοιχείων (PHEs) των επιφανειακών (0-10 cm) εδαφών προερχόμενων από αλσύλια της Αθήνας. Η δειγματοληψία υπαίθρου πραγματοποιήθηκε σε 20 αλσύλια της Αττικής και κάλυψε συνολική έκταση περίπου 200km2 . Αναλύθηκαν 20 εδαφικά δείγματα κοκκομετρίας Mn >Ni≈ Cu≈ Zn> Cr. Τα δεδομένα της έρευνας υποδεικνύουν ότι το έδαφος των αλσυλίων μπορεί να είναι ένας σημαντικός ταμιευτήρας των ανθρωπογενών στοιχείων στο αστικό έδαφοςUrban geochemistry is a scientific discipline which is growing in the recent years mainly because of the environmental impact caused by urbanization. The present study aims to determine the concentrations of potentially harmful elements (PHEs) on surface soils (0-10cm) in Athens parks. Soil sampling was carried out in public park areas within the Athens urban area. Twenty surface soil (0-10cm) samples were collected and the Mn >Ni≈ Cu≈ Zn> Cr. The data indicate that park areas seem to be important sinks of anthropogenic elements in urban soils

Chemical and Microbiological Contamination in Limpet (Patella spp.) of the Portuguese Coast

Coastal production areas can be impacted by anthropogenic contamination from urban, agro-industrial and leisure activities. Some contaminants, such as chemical substances might also have a telluric origin. Non filter feeding univalve mollusks, such as limpets, which are collected in rocky shores either for sale or for auto-consumption, are very appreciated in Portugal, but have been excluded from provisions on the classification of production areas, although can present relevant contamination. Thus, the aim of this study was to assess the microbiological and toxic metal contaminations in limpets (Patella spp) of the Portuguese coast, taking into account the production area and seasonal variation, and comparing their contamination levels with those occurring in bivalve mollusk indicator species, mussel (Mytilus edulis). The risks associated to the consumption of limpet meals were also assessed. For that, microbial total and fecal levels and cadmium, lead and mercury contents in limpets and mussels samples from three coastal areas over several months were analyzed based on standard methodologies. Contents of mercury and lead in limpets from the three areas studied, were always below the limits of 0.50 mg kg-1 and 1.5 mg kg-1 allowed by the EU, respectively. Regarding cadmium, levels in limpet were always above the limit of 1.0 mg kg-1, reaching about 3.0 mg kg-1 in some samples. These values probably indicate contamination from telluric origin (soil or rocks) in the coastal studied areas. Results indicated that microbiological contamination of fecal origin was low and in general below the detection level. Contamination levels did not show a clear seasonal pattern. The two mollusk species, limpets and mussels, differed statistically in all contaminants analyzed, being cadmium the most of concern, and always higher in limpets than in mussel samples. Thus, the potential risk associated with limpet consumption, taking into account the cadmium tolerable weekly intake (TWI), was investigated, being possible to reach a reliable recommendation of less than a monthly meal of 160 g. As recreational picking of limpets is common in Portugal, official 4recommendations of maximum periodic human consumption should be published and enforcement increased in forbidden areasinfo:eu-repo/semantics/acceptedVersio

Effects of treated wastewater irrigation on the establishment of young grapevines

Irrigation with treated wastewater could produce excessive accumulations within the plant and soil, negatively affecting the yield and production quality. In addition, the presence of biological and chemical contaminants could harm the agricultural environment, as well as the health of farmers and consumers. During this work, the suitability of secondary and tertiary treated wastewater for use in young grapevines was evaluated by studying the effect of the wastewater irrigation on the soil-plant system, crop yield, fruit quality and the presence of inorganic chemical contamination (salts, elements and heavy metals), organic chemical contamination (polycyclic aromatic hydrocarbons) and microbial contamination (E. coli, total coliforms). The results show that tertiary treated wastewater had positive impact on plant growth and yield while secondary treated wastewater had negative impact on fruit safety in comparison with tap water. Sodium levels in soils irrigated with treated wastewater increased at the end of the irrigation period while decreased during the wet season. The total polycyclic aromatic hydrocarbon concentrations in the soils ranged from 363 μg/kg to 374 μg/kg at the end of the experiment for all irrigation treatments applied. The use of tertiary treated wastewater was recommended for the irrigation of young grapevines as an alternative water source secured protection of environment, plant health and fruit quality

Investigating the sources and potential health risks of environmental contaminants in the soils and drinking waters from the rural clusters in Thiva area (Greece)

The present study investigates the possible influence of human activities on metal loadings of topsoil in a typical small rural city in central Greece and the chemical quality of tap water in surrounding villages. Furthermore, the study aimed to examine potential health risks of naturally enriched heavy metals to exposed population taking into account the soil and drinking water as exposure pathways. The mean concentrations of Ni, Cr, Co, Mn, Pb, Cu, Zn and Cd in the soil were 1777, 285, 99, 946, 30, 26, 78 and 0.67. mg/kg respectively. Combination of pollution indexes based on local reference background soils and statistical analyses (correlation analysis, cluster analysis and principal component analysis) revealed that anthropogenic activities have not modified the natural soil chemistry at least in a large scale. High Hazard Quotient (HQ) values for children were estimated for Ni, Cr and Co based on total metal concentrations for the soil ingestion route (9.26E-01, 9.75E-01 and 3.45E+00 respectively). However, evaluation of HQs based on published bioaccessible concentrations suggested that the population groups would not likely experience potential health risks as a result of exposure to contaminated soils. Concentrations of Cr(VI) in tap waters were within the allowable limits. However, the risk assessment model revealed that local residents (adults) of Eleonas and Neochori villages are at some carcinogenic risks considering lifetime ingestion of water (potential cancer risks 2.05E-04 and 1.29E-04 respectively). Despite the uncertainties accompanying these procedures and the great deal of debate regarding the human carcinogenicity of Cr(VI) by the oral route, results of this study drive attention to remediation measures that should include epidemiological studies for the local population. © 2013 Elsevier Inc

Mercury in the Urban Topsoil of Athens, Greece

The present study documents the Hg content in 45 urban topsoil samples from the highly urbanized city of Athens, Greece. The Hg concentrations were quantified by applying aqua regia digestion on the &lt;100 μm soil fraction followed by inductively coupled plasma-mass spectrometry (ICP-MS) with a detection limit of 5 μg·kg−1. The median concentration of Hg in Athens soil is 96 μg·kg−1; ten out of 45 soil samples were found to contain Hg concentrations higher than 200 μg·kg−1, which is the maximum concentration value expected to be present in normal uncontaminated soils. Results obtained by multivariate principal component and hierarchical cluster analysis incorporating a large suite of chemical elements were notably effective for elucidating the anthropogenic origin of Hg in the studied soil. The elevated concentrations are most likely related to site-specific point source contamination rather than to the widely documented influences from the vehicular traffic emissions in urban settings. Given the proximity of urban population to the contaminated urban soils, we suggest the implementation of different soil extraction tests with the aim to evaluate the fraction of soil Hg available for absorption by the human body

Accumulation of heavy metals in agricultural soils of Mediterranean: Insights from Argolida basin, Peloponnese, Greece

Excessive application of chemical products for promoting crop growth is a significant contributor for elevated concentrations of heavy metals in agricultural soils potentially threatening human health through the food chain. In this study, a series of heavy metals were quantified in 132 agricultural soils of Argolida basin, Peloponnese, Greece, with the aim to characterize their accumulation patterns. Median concentrations of Cu, Pb, Zn, Ni, Co, Mn, As, Cd, Cr and Fe were 65.23, 20.1, 72.75, 120.3, 20.6, 956.5, 7.1, 0.45, 72.3 and 27,100. mg/kg respectively. Statistically significant differences for Cu, Zn, Pb and Cd content were found between agricultural and background soils in the same region. Implementation of principal component analysis and cluster analysis successfully grouped the investigated chemical elements according to their anthropogenic or natural origin. The prolonged application of large amounts of fertilizers and pesticides-fungicides has resulted to Cu, Zn, Cd, Pb and As accumulation in the agricultural fields whereas Ni, Cr, Co and Fe amounts are controlled by parent material influences. Contrary to results commonly reported in the literature that characterize Mn as a geogenic element, this metal was found to exhibit a mixed source in the study agricultural system. Geographical information system techniques were used to illustrate the spatial distribution trends of the investigated elements confirming the clear contribution of agrochemicals to soil chemistry and highlighting the citrus soils around Argos town to have received large anthropogenic inputs. The agricultural area represented by olive groves does not demonstrate significant anthropogenic soil metal enrichment indicating that accumulation phenomena are restricted to the soils cultivated for oranges and mandarins. This study is the first detailed report on metal accumulation in citrus soils from Argolida basin, and results promote the care for the environment by reducing application rates of fertilizers and pesticides-fungicides and monitoring heavy metals levels in receiving soils. Future studies should pay attention to characterize the fractionation and reactivity of metals in citrus soils by utilizing selective chemical extractions with the aim to assess the actual risks for the environment. © 2014 Elsevier B.V