The Study of the Strength Properties of Galvanized Iron (GI) Fiber Reinforced Concrete

 The use of concrete with randomly distributed metallic or non-metallic fiber is now prominent in concrete engineering and metallic fiber has been reported to have a better contribution to concrete mechanical properties. The utilization of locally available galvanized iron or metallic fiber as a bridging material which is a new technique in Bangladesh has the ability to surprisingly improve concrete physical properties. This research was, therefore, conducted to compare the concrete performance of GI fiber and steel fiber using previous literature as well as the suitability of GI fiber as a supplant to steel fiber in the concrete industry. This was achieved through the evaluation of the compression, tension, and brittleness of concrete with ‘Galvanized Iron’ fiber using several cutting lengths of 20 mm and 40 mm with multiple mix proportions including 1.0%, 1.5%, 2.0%, and 2.5% by volume of the concrete. The results showed the fiber with a large cut length of 40 mm and proportion lesser than 2.5% performed well than 20 mm with proportion 2% in reference to the plain concrete. Moreover, the incorporation of a 2.0% proportion of galvanized iron fiber with 40 mm length was observed to have exhibited crowning increment for both concrete compression and tension by 16.1% and 89.2% correspondingly contrasted to the control specimen. A further increase in the percent of fiber content 2% led to a reduction in the compression and tension for both 20 mm and 40 mm lengths while a significant reduction in brittleness for galvanized iron fiber reinforced concrete was observed in contrast to the control specimen. Furthermore, the inclusion of 1.0%–2.5% GI fiber with a 40 mm length reduced concrete brittleness by 56.9% - 65.5 % in comparison with the control specimen. Therefore, the inclusion of galvanized iron (metallic) to enhance the physical properties of concrete was deduced to be one of the startling stratagem

Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ2 N,O}copper(II)

In the title complex, [Cu(C12H7BrClN2O)2], the CuII center is tetra­coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the CuII atom has a distorted square-planar coordination environment. The inter­planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance

Bis{(E)-2-[1-(eth­oxy­imino)­eth­yl]-1-naphtho­lato-κ2 N,O 1}copper(II)

In the title complex, [Cu(C14H14NO2)2], the discrete complex mol­ecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the CuII atom comprises two phenolate O atoms and two oxime N atoms from two bidentate–chelate 2-[1-(eth­oxy­imino)­eth­yl]-1-naphtho­late O-ethyl oxime (L −) ligands [Cu—O = 1.8919 (17) Å and Cu—N = 1.988 (2) Å]. The two naphthalene ring systems in the mol­ecule are parallel, with a perpendicular inter­planar spacing of 1.473 (2) Å, while each complex unit forms links to four other mol­ecules via inter­molecular methyl C—H⋯π inter­actions, giving an infinite cross-linked layered supra­molecular structur

Quantum and dielectric confinements of sub-10 nm gold in dichroic phosphate glass nanocomposites

Blue shifts of the surface plasmon resonance band of sub-10 nm gold in dichroic phosphate glass nanocomposites are observed with increase in both size of gold nanoparticles and refractive index of the medium, which are contrary to the common trends. These phenomena have been enlightened with the electrodynamics theories (Mie and Drude models) and happened due to quantum and dielectric confinements. Nanocomposites have been synthesized by in-situ thermochemical reduction technique in reducing phosphate glass matrices. The plasmon bands are characterized by the UV-vis spectrophotometer, and shape and size of the nanogold by the transmission electron microscopy. All the nanocomposites are dichroic in nature. (C) 2014 Elsevier B.V. All rights reserved

The Study of the Strength Properties of Galvanized Iron (GI) Fiber Reinforced Concrete

The use of concrete with randomly distributed metallic or non-metallic fiber is now prominent in concrete engineering and metallic fiber has been reported to have a better contribution to concrete mechanical properties. The utilization of locally available galvanized iron or metallic fiber as a bridging material which is a new technique in Bangladesh has the ability to surprisingly improve concrete physical properties. This research was, therefore, conducted to compare the concrete performance of GI fiber and steel fiber using previous literature as well as the suitability of GI fiber as a supplant to steel fiber in the concrete industry. This was achieved through the evaluation of the compression, tension, and brittleness of concrete with ‘Galvanized Iron' fiber using several cutting lengths of 20 mm and 40 mm with multiple mix proportions including 1.0%, 1.5%, 2.0%, and 2.5% by volume of the concrete. The results showed the fiber with a large cut length of 40 mm and proportion lesser than 2.5% performed well than 20 mm with proportion 2% in reference to the plain concrete. Moreover, the incorporation of a 2.0% proportion of galvanized iron fiber with 40 mm length was observed to have exhibited crowning increment for both concrete compression and tension by 16.1% and 89.2% correspondingly contrasted to the control specimen. A further increase in the percent of fiber content 2% led to a reduction in the compression and tension for both 20 mm and 40 mm lengths while a significant reduction in brittleness for galvanized iron fiber reinforced concrete was observed in contrast to the control specimen. Furthermore, the inclusion of 1.0%–2.5% GI fiber with a 40 mm length reduced concrete brittleness by 56.9% - 65.5 % in comparison with the control specimen. Therefore, the inclusion of galvanized iron (metallic) to enhance the physical properties of concrete was deduced to be one of the startling stratagem