2018-2019 Philharmonia No. 5

Concert Date & Time: February 23, 2019 at 7:30 PM and February 24, 2019 at 4:00 PM Program Concerto for Clarinet, Strings and Harp / Aaron Copland Te Deum, op. 22 / Hector Berliozhttps://spiral.lynn.edu/conservatory_philharmonia/1140/thumbnail.jp

2022-2023 Philharmonia with the Master Chorale of South Florida

Concert Dates & Time March 30, 2023, 8:00 P.M. at the Parker, Fort Lauderdale April 1, 2023. 8:00 P.M. at the Wold Performing Arts Center April 2, 2023. 8:00 P.M. at the Wold Performing Arts Center Program Messa da Requiem / Giuseppe Verdihttps://spiral.lynn.edu/conservatory_philharmonia/1167/thumbnail.jp

2019-2020 Philharmonia No. 4

Concert Date & Time: February 22, 2020 at 7:30 pm and February 23, 2020 at 4:00 pm Program Short Ride in a Fast Machine / John Adams Lincoln Portrait / Aaron Copland Jon Robertson, narrator Symphony No. 9 in D minor, Op. 125 / Ludwig van Beethoven Sherezade Panthaki, soprano Rebecca Robinson, mezzo-soprano Robert Stahley, tenor Adrian Smith, baritone The Master Chorale of South Florida Brett Karlin, artistic directorhttps://spiral.lynn.edu/conservatory_philharmonia/1150/thumbnail.jp

2013-2014 Lynn Philharmonia Season Program

Wind Ensemble September 15, 2013 at 4:00 PM The Wind Symphony, Movement 2 Kenneth Amis, director and conductor Symphonie Militaire / François Joseph Gossec -- Sinfonietta, op. 188 (1873) / Joseph Joachim Raff -- La Vita Symphony in Three Scenes (1998) / Yasuhide Ito -- Symphony for Winds and Percussion / Donald Grantham Philharmonia No. 1 October 5, 2013 at 7:30 PM and October 6, 2013 at 4:00 PM Jon Robertson, guest conductor Crown Imperial March / William Walton -- Symphony No. 38 in D major, K. 504 ( Prague ) / Wolfgang Amadeus Mozart -- Symphony No. 4 in E-flat Major (1888 version) / Anton Bruckner Philharmonia No. 2 October 26, 2013 at 7:30 PM and October 27, 2013 at 4:00 PM Jon Robertson, guest conductor Orchestral Suite No. 3 in D major, BWV 1068 / Johann Sebastian Bach -- Symphony No. 1 in D major, op. 25 ( Classical ) / Sergei Prokofiev -- Symphony No. 9 in E Minor, op. 95 ( From the New World ) / Antonín Dvořák Philharmonia No. 3 November 16, 2013 at 7:30 PM and November 17, 2013 at 4:00 PM 2013 Concerto Competition Winners Guillermo Figueroa, conductor ; Doniyor Zuparov, cello ; Anna Brumbaugh, clarinet ; Vladislav Kosminov, piano ; Timothy Nemzin, trumpet ; Brenton Caldwell, viola Overture to Benvenuto Cellini, op. 23 / Hector Berlioz -- Concerto in E Minor for Violoncello, op. 61 / Edward Elgar -- Concerto Fantasia on Motives from Verdi\u27s Opera Rigoletto / Luigi Bassi, orchestrated by Kenneth Lee Richmond -- Capriccio Espagnol, op. 34 / Nicolai Rimsky-Korsakov -- Concerto No. 1 in C Minor for Piano, op. 35 / Dmitri Shostakovich -- Concerto for Viola (1962 version) / William Walton Philharmonia No. 4 January 18, 2014 at 7:30 PM and January 19, 2014 at 4:00 PM Guillermo Figueroa, conductor ; Carol Cole, violin ; David Cole, cello Overture to Le Nozze di Figaro (The Marriage of Figaro), K. 492 / Wolfgang Amadeus Mozart -- Concerto for Violin, Cello and Orchestra in A Minor, op. 102 / Johannes Brahms -- Fandangos / Roberto Sierra -- Suite from Der Rosenkavalier (The Knight of the Rose), op. 59 / Richard Strauss Philharmonia No. 5 February 8, 2014 at 7:30 PM and February 9, 2014 at 4:00 PM Guillermo Figueroa, conductor Overture to Guillaume Tell (William Tell) / Gioachino Rossini -- Don Juan, op. 20 / Richard Strauss -- Symphony No. 4 in F Minor, op. 36 / Pyotr Ilyich Tchaikovsky Philharmonia No. 6 March 22, 2014 at 7:30 PM and March 23, 2014 at 4:00 PM Guillermo Figueroa, conductor ; Abigail Santos Villalobos, soprano ; Gabriela García, mezzo-soprano ; Master Chorale of South Florida ; Brett Karlin, artistic director Symphony No. 2 in C minor ( Resurrection ) / Gustav Mahlerhttps://spiral.lynn.edu/conservatory_philharmonia/1017/thumbnail.jp

2016-2017 Philharmonia No. 4

Concert Date & Time: February 25, 2017 at 7:30 PM | February 26, 2017 at 4:00 PM Program Roméo et Juliette: Symphonie Dramatique, op. 17 / Hector Berliozhttps://spiral.lynn.edu/conservatory_philharmonia/1003/thumbnail.jp

Visual identification and quantification of Milankovitch climate cycles in outcrop: an example from the Upper Ordovician Kope Formation, Northern Kentucky

Applying time-series analyses using Fourier transform and multi-taper methods to lowfield, mass-specific magnetic susceptibility (χ) measurements on marine samples from wellstudied shale and limestone outcrops of the Upper Ordovician (Edenian Stage; Upper Katian) Kope Formation, northern Kentucky, corroborates direct visual identification in outcrops of Milankovitch eccentricity (c. 405 and 100 ka), obliquity and precessional climate cycles. Because individual outcrops were too short and deposition too chaotic to yield significant time-series results, it was necessary to build a c. 50 m thick composite sequence from three well-correlated outcrops to quantify the cyclicity. Time-series analysis was then performed using x measured for 1004 closely spaced samples covering the section. Milankovitch bands are recorded in the time-series data from the composite. We tested this result by comparison of these bands to cyclic packages in outcrop, which correspond to thicknesses represented in the time-series datasets. This is particularly well defined for the eccentricity and obliquity cycles, with precessional bands being evident but as less well-defined packages of beds. © The Geological Society of London 2013

Models for Met-hemocyanin Derivatives: Structural and Spectroscopic Comparisons of Analogous Phenolate and X (X = OH-, OMe-, N3 -, Cl-, OAc-, OBz-) Doubly Bridged Dinuclear Copper(II) Complexes

The extensive use of spectroscopic and chemical studies of the binding of small molecules such as acetate, chloride, azide, etc. in chemically modified hemocyanin derivatives has prompted us to develop the chemistry of the dinucleating ligand L-OH, which can be utilized to form the compounds [Cu2(L-O-)X]2+, where two copper(II) ions are bridged by a phenolate oxygen atom from L-O- and the exogenous X- bridging atom. Here, we report structural, magnetic, and spectroscopic comparisons for a series of complexes, X = OH- (I2+), OMe- (IV2+), N3 - (II2+), Cl- (III2+), Br- (V2+), OBz- (VI2+), OAc- (VII2+), including complete X-ray structural characterization of complexes III, IV, and V. Compound III crystallizes in the triclinic space group P1 with Z = 2 and a = 10.986 (3) Å, b = 15.138 (3) Å, c = 23.292 Å, α = 91.11 (2)°, β = 99.77 (2)°, and γ = 91.18 (2)°. Complex IV crystallizes in the triclinic space group P1 with Z = 2 and a = 10.843 (2) Å, b = 15.045 (3) Å, c = 23.170 (4) Å, α = 90.14 (2)°, β = 100.29 (2)°, and γ = 96.27 (2)°. Compound V crystallizes in the monoclinic space group C2/c with Z = 4 and a = 15.740 (4) Å, b = 32.033 (4) Å, c = 13.033 (4) Å, and β = 134.03 (2)°. In these complexes, each copper atom is coordinated in a square-based pyramidal (SP) or distorted SP geometry to three nitrogen atoms provided by L-O-, the bridging phenolate oxygen atom, and X. Structural comparisons are made among compounds I-V; the presence of a larger X atom results in a distortion away from pure SP geometry with an opening of the Cul-Ol-Cu2 bridging angle resulting in a greater Cu⋯Cu separation. UV-vis spectroscopic comparisons indicate that the OPh- → Cu(II) LMCT transition (λmax = 378-475 nm) and the d-d envelope (λmax = 625-680 nm) vary systematically with structure; a shift to lower energy is observed for both types of electronic absorption as X becomes larger. On the basis of these and other observations, complexes VI and VII are assigned a monoatomic μ-carboxylato-O(O′) structure in solution, but a μ-carboxylato-O,O′ coordination in the solid state. Temperature-dependent magnetic measurements on the structurally characterized complexes I-III and V reveal that the halide-bridged complexes are the least strongly coupled with singlet-triplet separations, -2J, of 335 cm-1 for each. The OH- complex is the most strongly coupled of the series (-2J = 600 cm-1), while the azide complex falls in between (-2J = 440 cm-1). On the basis of only the Cu-Ophenolate-Cu angles, the coupling should increase in the direction OH- \u3c μ-1,1-N3 - \u3c Br-, but the opposite trend is actually observed and is attributed to the modulating effect of the exogenous bridge. © 1987 American Chemical Society