Local motifs in GeS2_2-Ga2_2S3_3 glasses

The structure of (GeS$_2$)$_{0.75}$(Ga$_2$S$_3$)$_{0.25}$ and (GeS$_2$)$_{0.83}$(Ga$_2$S$_3$)$_{0.17}$ glasses was investigated by Raman scattering, high energy X-ray diffraction and extended X-ray absorption fine structure (EXAFS) measurements at the Ga and Ge K-edges. The reverse Monte Carlo simulation technique (RMC) was used to obtain structural models compatible with diffraction and EXAFS datasets. It was found that the coordination number of Ga is close to four. While Ge atoms have only S neighbors, Ga binds to S as well as to Ga atoms showing a violation of chemical ordering in GeS$_2$-Ga$_2$S$_3$ glasses. Analysis of the corner- and edge-sharing between [GeS$_{4/2}$] units revealed that about 30% of germanium atoms participate in the edge-shared tetrahedra.Comment: 23 pages, 7 figures, accepted for publication in Journal of Alloys and Compound

ANALISIS PENERAPAN PENGENDALIAN MUTU DALAM MENINGKATKAN KUALITAS PRODUK PADA PT. JAKARANA TAMA MEDAN

Adapun tujuan dari penelitian ini adalah untukmengetahui penerapan pengendalian mutu dalam meningkatkan kualitas produk yang ada pada PT.Jakarana Tama Medan, untuk mengetahui yang menjadikendala penerapan pengendalian mutu dalammeningkatkan kualitas produk yang ada pada PT.Jakarana Tama Medan dan untuk mengetahui solusikendala penerapan pengendalian mutu dalammeningkatkan kualitas produk yang ada pada PT.Jakarana Tama Medan. Adapun teknik pengumpulan datayang dilakukan pada penelitian ini yaitu denganwawancara, observasi dan studi dokumentasi, sedangkanteknik analisis yang digunakan yaitu analisis deskriptif.Berdasarkan hasil penelitian diketahui bahwa tahaptahapproses produksi mie instan pada PT. Jakarana TamaMedan antara lain; penuangan tepung ke mesin screwconveyor, mixing, roll sheeting dan slitting, steaming,frying, cooling dan packing. Selain itu bahanbahan yangdigunakan PT. Jakarana Tama Medan untukmemproduksi mie instan yaitu: tepung terigu, tepungtapioka, dan air alkali (air, garam dapur, ingredientlainnya dan pewarna) serta untuk mendapatkan kualitasmie yang bagus, PT. Jakarana Tama Medan melakukanpengendalian mutu bahan baku tepung dan bahanbahantambahan. Selanjutnya konsistensi mutu produk mieinstan PT. Jakarana Tama Medan terjaga denganpenerapan sistem manajemen mutu ISO 9001 : 2000,Sistem Jaminan Halal dan SNI

EUROMAT 2019 Symposia on Processing

This issue of JMEP contains invited, peer-reviewed papers presented at the European Congress and Exhibition on Advanced Materials and Processes (EUROMAT 2019), held on September 1–5, 2019, in Stockholm, Sweden, in two symposia from the Area C “Processing”: C6 “Joining,” organized by Anna Zervaki (University of Thessaly, Greece), Ivan Kaban (IFW Dresden, Germany), and C. Sommitsch (Technische Universität Graz, Austria) C8 “Interface Design and Modelling, Wetting, and High-Temperature Capillarity,” organized by Pavel Protsenko (M.V. Lomonosov Moscow State University, Russian Federation), Fabrizio Valenza (CNR—ICMATE, Genoa, Italy), and Simeon Agathopoulos (University of Ioannina, Greece) The research works in the field of joining technologies, presented at the C6 symposium, concerned soldering, brazing, diffusion bonding, resistance spot welding, friction stir welding, and riveting techniques. The symposium C8 covered research topics on grain boundary wetting, surface energy of liquid metals and interfacial phenomena, considering fundamental as well as applied issues related to materials joining, and interface design. We wish to thank the authors for the written contributions and acknowledge the reviewers for their careful reading and evaluation of the manuscripts and valuable suggestions to improve the quality of the papers. We are grateful to the editor-in-chief of JMEP, Dr. Rajiv Asthana, and the ASM journal staff, including Mary Anne Fleming, senior content developer; Kate Doman, content developer (journals); and Vincent Katona, production coordinator; for the opportunity to publish the symposia contributions in this issue and for their professional and friendly support during the entire reviewing and publication process. We hope this collection will stimulate fresh thinking and promote further research on joining and interfacial phenomena

Structural, electronic and kinetic properties of the phase-change material Ge2Sb2Te5 in the liquid state

Phase-change materials exhibit fast and reversible transitions between an amorphous and a crystalline state at high temperature. The two states display resistivity contrast, which is exploited in phase-change memory devices. The technologically most important family of phase-change materials consists of Ge-Sb-Te alloys. In this work, we investigate the structural, electronic and kinetic properties of liquid Ge2Sb2Te5 as a function of temperature by a combined experimental and computational approach. Understanding the properties of this phase is important to clarify the amorphization and crystallization processes. We show that the structural properties of the models obtained from ab initio and reverse Monte Carlo simulations are in good agreement with neutron and X-ray diffraction experiments. We extract the kinetic coefficients from the molecular dynamics trajectories and determine the activation energy for viscosity. The obtained value is shown to be fully compatible with our viscosity measurements

On the structure of Ge–As–Te–Cu glasses

International audienceShort range order in glassy 0.9(Ge0.1As0.15Te0.75)–0.1Cu (GATC1) and 0.9(Ge0.05As0.55Te0.4)–0.1Cu (GATC2) was studied by neutron- and X-ray diffraction as well as EXAFS (extended X-ray absorption fine structure) measurements at the K-edges of all components. The reverse Monte Carlo simulation technique was used to create models consistent with all experimental datasets. It was found that Cu binds predominantly to Te in GATC1 while Cu–As and Cu–Cu bonding is also significant in GATC2. Ge and As atoms have 4 and 3 Ge/As/Te neighbors in both compositions. In GATC1 the formation of ‘extra’ Te–Te bonds can be observed, similarly to GeTe4–AgI glasse

Local microstructure evolution at shear bands in metallic glasses with nanoscale phase separation

At room temperature, plastic flow of metallic glasses (MGs) is sharply localized in shear bands, which are a key feature of the plastic deformation in MGs. Despite their clear importance and decades of study, the conditions for formation of shear bands, their structural evolution and multiplication mechanism are still under debate. In this work, we investigate the local conditions at shear bands in new phase-separated bulk MGs containing glassy nanospheres and exhibiting exceptional plasticity under compression. It is found that the glassy nanospheres within the shear band dissolve through mechanical mixing driven by the sharp strain localization there, while those nearby in the matrix coarsen by Ostwald ripening due to the increased atomic mobility. The experimental evidence demonstrates that there exists an affected zone around the shear band. This zone may arise from low-strain plastic deformation in the matrix between the bands. These results suggest that measured property changes originate not only from the shear bands themselves, but also from the affected zones in the adjacent matrix. This work sheds light on direct visualization of deformation-related effects, in particular increased atomic mobility, in the region around shear bands

Structure evolution of soft magnetic (Fe36Co36B19.2Si4.8Nb4)100−xCux (x=0 and 0.5) bulk glassy alloys

AbstractFully amorphous rods with diameters up to 2mm diameter were obtained upon 0.5at.% Cu addition to the Fe36Co36B19.2Si4.8Nb4 bulk metallic glass. The Cu-added glass shows a very good thermal stability but, in comparison with the Cu-free base alloy, the entire crystallization behavior is drastically changed. Upon heating, the glassy (Fe36Co36B19.2Si4.8Nb4)99.5Cu0.5 samples show two glass transitions-like events, separated by an interval of more than 100K, in between which a bcc-(Fe,Co) solid solution is formed. The soft magnetic properties are preserved upon Cu-addition and the samples show a saturation magnetization of 1.1T combined with less than 2A/m coercivity. The relaxation behavior prior to crystallization, as well as the crystallization behavior, were studied by time-resolved X-ray diffraction using synchrotron radiation. It was found that both glassy alloys behave similar at temperatures below the glass transition. Irreversible structural transformations take place when approaching the glass transition and in the supercooled liquid region

The Effect of Boron Content on Wetting Kinetics in Si-B Alloy/h-BN System

In this work, the effect of boron content on the high-temperature wetting behavior in the Si-B alloy/h-BN systems was experimentally examined. For this reason, hypoeutectic, eutectic and hypereutectic Si-B alloys (Si-1B, Si-3.2B and Si-5.7B wt.%, respectively) were produced by electric arc melting method and then subjected to sessile drop/contact heating experiments with polycrystalline h-BN substrates, at temperatures up to 1750 °C. Similar to pure Si/h-BN system, wetting kinetics curves calculated on a basis of in situ recorded drop/substrate images point toward non-wetting behavior of all selected Si-B alloy/h-BN couples. The highest contact angle values of ~ 150° were obtained for hypoeutectic and eutectic Si-B alloys in the whole examined temperature range. © 2018, The Author(s)

Atomic level structure of Ge-Sb-S glasses: chemical short range order and long Sb-S bonds

The structure of Ge$_{20}$Sb$_{10}$S$_{70}$, Ge$_{23}$Sb$_{12}$S$_{65}$ and Ge$_{26}$Sb$_{13}$S$_{61}$ glasses was investigated by neutron diffraction (ND), X-ray diffraction (XRD), extended X-ray absorption fine structure (EXAFS) measurements at the Ge and Sb K-edges as well as Raman scattering. For each composition, large scale structural models were obtained by fitting simultaneously diffraction and EXAFS data sets in the framework of the reverse Monte Carlo (RMC) simulation technique. Ge and S atoms have 4 and 2 nearest neighbors, respectively. The structure of these glasses can be described by the chemically ordered network model: Ge-S and Sb-S bonds are always preferred. These two bond types adequately describe the structure of the stoichiometric glass while S-S bonds can also be found in the S-rich composition. Raman scattering data show the presence of Ge-Ge, Ge-Sb and Sb-Sb bonds in the S-deficient glass but only Ge-Sb bonds are needed to fit diffraction and EXAFS datasets. A significant part of the Sb-S pairs has 0.3-0.4 {\AA} longer bond distance than the usually accepted covalent bond length (~2.45 {\AA}). From this observation it was inferred that a part of Sb atoms have more than 3 S neighbors.Comment: 23 pages, 6 figures, submitted to Journal of Alloys and Compound