758 research outputs found
Subsequent layer growth of supported nanoparticles by deposition of Sb4 clusters onto MoS2(0001)
The surface morphology after deposition of Sb4 clusters
onto MoS2(0001) at 90 K has been studied in detail with
scanning tunnelling microscopy in ultrahigh vacuum. It has
been found that during the initial stage of growth
two-dimensional nanoparticles are formed. With increasing
coverage these nanoparticles grow layer by layer and each layer
has the height of one monolayer of undissociated Sb4
clusters. The interface width (surface roughness) has been
quantitatively determined as a function of total coverage.
Ideal three-dimensional layer-by-layer growth has been
identified for the single particles according to a Poisson
distribution of exposed areas of the layers of the particles.
Consequently, antimony grows on MoS2(0001) without
interlayer diffusion which is suppressed by an effective step
edge (Schwoebel-Ehrlich) barrier.Peer Reviewe
Adoption of unconventional approaches in construction: The case of cross-laminated timber
Achieving sustainable development requires the decoupling of economic growth from the use of non-renewable resources. This depends on industry adopting unconventional approaches to production. This research explores the root causes of barriers to the adoption of such approaches in the construction industry, and applies a behavioural model to assess whether companies are hindered by capability, opportunity or motivation.
The long history of lowest-cost tendering in construction has led to a path-dependent lock-in to conventional market-driven objectives of cost and risk reduction; it is suggested that locked-in companies lack the commercial opportunity and hence motivation, rather than the capability, to adopt approaches perceived to increase cost or risk. Such companies will therefore tend to resist unconventional approaches, restricting the physical opportunity for other project participants. This theory is explored in a case study of first adoptions of cross-laminated timber (CLT) in UK projects, using a survey and series of semi-structured interviews.
The case study found that project contexts created market niches. This provided designers, who were motivated to use CLT, the opportunity to promote its use in the project. CLT was seen as key to successful resolution of project constraints, thereby providing motivation to other project participants to adopt the material
Phase entrainment of induced ventricular fibrillation: A human feasibility and proof of concept study
Cardioversion and defibrillation by a single high energy shock applied by myocardial or body surface electrodes is painful, causes long term tissue damage, and is associated with worsening long term outcomes, but is almost always required for treatment of ventricular fibrillation .
As a initial step towards developing methods that can terminate ventricular arrhythmias painlessly, we aim to determine if pacing stimuli at a rate of 5/s applied via an implantable cardiac defibrillator (ICD) can modify human ventricular fibrillation. In 8 patients undergoing defibrillation testing of a new/exchanged intracardiac defibrillator, five seconds of pacing at five stimuli per second was applied during the 10-20 seconds of induced ventricular fibrillation before the defibrillation shock was automatically applied, and the cardiac electrograms recorded and analyzed.
The high frequency pacing did not entrain the ventricular fibrillation, but altered the dominant frequency in all 8 patients, and modulated the phase computed via the Hilbert Transform, in four of the patients.
In this pilot study we demonstrate that high frequency pacing applied via ICD electrodes during VF can alter the dominant frequency and modulate the probability density of the phase of the electrogram of the ventricular fibrillation
Size-dependent phase transition from amorphous to crystalline in antimony clusters on crystalline surfaces
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Peer Reviewe
Third FORATOM congress, London, 24-26 April 1967. Industrial aspects of a fast breeder reactor programme German contributions to sessions I, II, III, IV, VI
Comparison of Uncultured Marrow Mononuclear Cells and Culture-Expanded Mesenchymal Stem Cells in 3D Collagen-Chitosan Microbeads for Orthopedic Tissue Engineering
Stem cell-based therapies have shown promise in enhancing repair of bone and cartilage. Marrow-derived mesenchymal stem cells (MSC) are typically expanded in vitro to increase cell number, but this process is lengthy, costly, and there is a risk of contamination and altered cellular properties. Potential advantages of using fresh uncultured bone marrow mononuclear cells (BMMC) include heterotypic cell and paracrine interactions between MSC and other marrow-derived cells including hematopoietic, endothelial, and other progenitor cells. In the present study, we compared the osteogenic and chondrogenic potential of freshly isolated BMMC to that of cultured-expanded MSC, when encapsulated in three-dimensional (3D) collagen-chitosan microbeads. The effect of low and high oxygen tension on cell function and differentiation into orthopedic lineages was also examined. Freshly isolated rat BMMC (25?106 cells/mL, containing an estimated 5?104 MSC/mL) or purified and culture-expanded rat bone marrow-derived MSC (2?105 cells/mL) were added to a 65?35?wt% collagen-chitosan hydrogel mixture and fabricated into 3D microbeads by emulsification and thermal gelation. Microbeads were cultured in control MSC growth media in either 20% O2 (normoxia) or 5% O2 (hypoxia) for an initial 3 days, and then in control, osteogenic, or chondrogenic media for an additional 21 days. Microbead preparations were evaluated for viability, total DNA content, calcium deposition, and osteocalcin and sulfated glycosaminoglycan expression, and they were examined histologically. Hypoxia enhanced initial progenitor cell survival in fresh BMMC-microbeads, but it did not enhance osteogenic potential. Fresh uncultured BMMC-microbeads showed a similar degree of osteogenesis as culture-expanded MSC-microbeads, even though they initially contained only 1/10th the number of MSC. Chondrogenic differentiation was not strongly supported in any of the microbead formulations. This study demonstrates the microbead-based approach to culturing and delivering cells for tissue regeneration, and suggests that fresh BMMC may be an alternative to using culture-expanded MSC for bone tissue engineering.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/140225/1/ten.tea.2013.0151.pd
Evolution of E2 transition strength in deformed hafnium isotopes from new measurements on Hf, Hf, and Hf
The available data for E2 transition strengths in the region between
neutron-deficient Hf and Pt isotopes are far from complete. More and precise
data are needed to enhance the picture of structure evolution in this region
and to test state-of-the-art nuclear models. In a simple model, the maximum
collectivity is expected at the middle of the major shell. However, for actual
nuclei, this picture may no longer be the case, and one should use a more
realistic nuclear-structure model. We address this point by studying the
spectroscopy of Hf. We remeasure the 2^+_1 half-lives of 172,174,176Hf, for
which there is some disagreement in the literature. The main goal is to
measure, for the first time, the half-lives of higher-lying states of the
rotational band. The new results are compared to a theoretical calculation for
absolute transition strengths. The half-lives were measured using \gamma-\gamma
and conversion-electron-\gamma delayed coincidences with the fast timing
method. For the determination of half-lives in the picosecond region, the
generalized centroid difference method was applied. For the theoretical
calculation of the spectroscopic properties, the interacting boson model is
employed, whose Hamiltonian is determined based on microscopic energy-density
functional calculations. The measured 2^+_1 half-lives disagree with results
from earlier \gamma-\gamma fast timing measurements, but are in agreement with
data from Coulomb excitation experiments and other methods. Half-lives of the
4^+_1 and 6^+_1 states were measured, as well as a lower limit for the 8^+_1
states. We show the importance of the mass-dependence of effective boson charge
in the description of E2 transition rates in chains of nuclei. It encourages
further studies of the microscopic origin of this mass dependence. New data on
transition rates in nuclei from neighboring isotopic chains could support these
studies.Comment: 16 pages, 16 figures, 7 tables; Abstract shortened due to character
limi
Nonuniform friction-area dependency for antimony oxide surfaces sliding on graphite
Cataloged from PDF version of article.We present frictional measurements involving controlled lateral manipulation of antimony nanoparticles on graphite featuring atomically smooth particle-substrate interfaces via tapping- and contact-mode atomic force microscopy. As expected from earlier studies, the power required for lateral manipulation as well as the frictional forces recorded during the manipulation events exhibit a linear dependence on the contact area over a wide size range from 2000 nm2 to 120 000 nm2. However, we observe a significant and abrupt increase in frictional force and dissipated power per contact area at a value of about 20 000 nm2, coinciding with a phase transition from amorphous to crystalline within the antimony particles. Our results suggest that variations in the structural arrangement and stoichiometry of antimony oxide at the interface between the particles and the substrate may be responsible for the observed effect. © 2013 American Physical Society
Untersuchungen an den Ladungen 3 und 4 des Schnell-Thermischen Argonaut-Reaktors STARK. EUR 3701. = Studies on the charges 3 and 4 of the quick-thermal Argonaut reactor STARK. EUR 3701.
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