6,596 research outputs found
Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters
The dust mass in z > 6 normal star forming galaxies
We interpret recent ALMA observations of z > 6 normal star forming galaxies
by means of a semi-numerical method, which couples the output of a cosmological
hydrodynamical simulation with a chemical evolution model which accounts for
the contribution to dust enrichment from supernovae, asymptotic giant branch
stars and grain growth in the interstellar medium. We find that while stellar
sources dominate the dust mass of small galaxies, the higher level of metal
enrichment experienced by galaxies with Mstar > 10^9 Msun allows efficient
grain growth, which provides the dominant contribution to the dust mass. Even
assuming maximally efficient supernova dust production, the observed dust mass
of the z = 7.5 galaxy A1689-zD1 requires very efficient grain growth. This, in
turn, implies that in this galaxy the average density of the cold and dense
gas, where grain growth occurs, is comparable to that inferred from
observations of QSO host galaxies at similar redshifts. Although plausible, the
upper limits on the dust continuum emission of galaxies at 6.5 < z < 7.5 show
that these conditions must not apply to the bulk of the high redshift galaxy
populationComment: 5 pages, 2 figures, accepted for publication as a Letter to MNRA
Atomistic Insight into the Role of Threonine 127 in the Functional Mechanism of Channelrhodopsin-2
Channelrhodopsins (ChRs) belong to the unique class of light-gated ion channels. The structure of channelrhodopsin-2 from Chlamydomonas reinhardtii (CrChR2) has been resolved, but the mechanistic link between light-induced isomerization of the chromophore retinal and channel gating remains elusive. Replacements of residues C128 and D156 (DC gate) resulted in drastic effects in channel closure. T127 is localized close to the retinal Schiff base and links the DC gate to the Schiff base. The homologous residue in bacteriorhodopsin (T89) has been shown to be crucial for the visible absorption maximum and dark–light adaptation, suggesting an interaction with the retinylidene chromophore, but the replacement had little effect on photocycle kinetics and proton pumping activity. Here, we show that the T127A and T127S variants of CrChR2 leave the visible absorption maximum unaffected. We inferred from hybrid quantum mechanics/molecular mechanics (QM/MM) calculations and resonance Raman spectroscopy that the hydroxylic side chain of T127 is hydrogen-bonded to E123 and the latter is hydrogen-bonded to the retinal Schiff base. The C=N–H vibration of the Schiff base in the T127A variant was 1674 cm−1, the highest among all rhodopsins reported to date. We also found heterogeneity in the Schiff base ground state vibrational properties due to different rotamer conformations of E123. The photoreaction of T127A is characterized by a long-lived P2380 state during which the Schiff base is deprotonated. The conservative replacement of T127S hardly affected the photocycle kinetics. Thus, we inferred that the hydroxyl group at position 127 is part of the proton transfer pathway from D156 to the Schiff base during rise of the P3530 intermediate. This finding provides molecular reasons for the evolutionary conservation of the chemically homologous residues threonine, serine, and cysteine at this position in all channelrhodopsins known so far
Coupling radio propagation and weather forecast models to maximize Ka-band channel transmission rate for interplanetary missions
Deep space (DS) missions for interplanetary explorations are aimed at acquiring information about the solar system and its composition. To achieve this result a radio link is established between the space satellite and receiving stations on the Earth. Significant channel capacity must be guaranteed to such spacecraft-to-Earth link considering their large separation distance as well. Terrestrial atmospheric impairments on the space-to-Earth propagating signals are the major responsible for the signal degradation thus reducing the link’s channel temporal availability. Considering the saturation and the limited bandwidth of the conventional systems used working at X-band (around 8.4 GHz), frequencies above Ku-band (12-18 GHz) are being used and currently explored for next future DS missions. For example, the ESA mission EUCLID, planned to be launched in 2020 to reach Sun-Earth Lagrange point L2, will use the K-band (at 25.5-27 GHz). The BepiColombo (BC) ESA mission to Mercury, planned to be launched in 2016, will use Ka-band (at 32-34 GHz) with some modules operating at X-band too. The W-band is also being investigated for space communications (Lucente et al., IEEE Systems J., 2008) as well as near-infrared band for DS links (Luini at al., 3rd IWOW, 2014; Cesarone et al., ICSOS, 2011).
If compared with X-band channels, K-band and Ka-band can provide an appealing data rate and signal-to-noise ratio in free space due to the squared-frequency law increase of antenna directivity within the downlink budget (for the same physical antenna size). However, atmospheric path attenuation can be significant for higher frequencies since the major source of transmission outage is not only caused by convective rainfall, as it happens for lower frequencies too, but even non-precipitating clouds and moderate precipitation produced by stratiform rain events are detrimental. This means that accurate channel models are necessary for DS mission data link design at K and Ka band. A physical approach can offer advanced radiopropagation models to take into account the effects due to atmospheric gases, clouds and precipitation.
The objective of this work is to couple a weather forecast numerical model with a microphysically- oriented radiopropagation model, providing a description of the atmospheric state and of its effects on a DS downlink. This work is developed in the framework of the RadioMeteorological Operations Planner (RMOP) program, aimed at performing a feasibility study for the BC mission (Biscarini et al., EuCAP 2014). The RMOP chain for the link budget computation is composed by three modules: weather forecast (WFM), radio propagation (RPM) and downlink budget (DBM). WFM is aimed at providing an atmospheric state vector. Among the available weather forecast models, for RMOP purposes we have used the Mesoscale Model 5. The output of the WFM is the input of the RPM for the computation of the atmospheric attenuation and sky-noise temperature at the receiving ground station antenna. RPM makes use of radiative transfer solver based on the Eddington approximations well as accurate scattering models. Time series of attenuation and sky-noise temperature coming from the RPM are converted into probability density functions and then ingested by the DBM to compute the received data volume (DV).
Using the BC mission as a reference test case for the Ka-band ground station at Cebreros (Spain), this work will show the advantages of using a coupled WFM-RPM approach with respect to climatological statistics in a link budget optimization procedure. The signal degradation due to atmospheric effects in DS links in terms of received DV will be also investigated not only at Ka band, but also at X, K and W for intercomparison. The quality of the DS downlink will be given in terms of received DV and the results at different frequencies compared showing the respective advantages and drawbacks
Rapid diffusion of electrons in GaMnAs
We report ultrafast transient-grating measurements, above and below the Curie
temperature, of the dilute ferromagnetic semiconductor (Ga,Mn)As containing 6%
Mn. At 80 K (15 K), we observe that photoexcited electrons in the conduction
band have a lifetime of 8 ps (5 ps) and diffuse at about 70 cm2/s (60 cm2/s).
Such rapid diffusion requires either an electronic mobility exceeding 7,700
cm2/Vs or a conduction-band effective mass less than half the GaAs value. Our
data suggest that neither the scattering rate nor the effective mass of the
(Ga,Mn)As conduction band differs significantly from that of GaAs.Comment: 5 pages, 3 figures. Differs from the previous version in
incorporating additional data and changes made during the review process.
Differs from the published version in including section headings and in
omitting AIP copy-edits. No substantial differences in scientific conclusions
from either versio
Cladding defects in hollow core fibers for surface mode suppression and improved birefringence
Matrix biorthogonal polynomials on the unit circle and non-Abelian Ablowitz-Ladik hierarchy
Adler and van Moerbeke \cite{AVM} described a reduction of 2D-Toda hierarchy
called Toeplitz lattice. This hierarchy turns out to be equivalent to the one
originally described by Ablowitz and Ladik \cite{AL} using semidiscrete
zero-curvature equations. In this paper we obtain the original semidiscrete
zero-curvature equations starting directly from the Toeplitz lattice and we
generalize these computations to the matrix case. This generalization lead us
to the semidiscrete zero-curvature equations for the non-abelian (or
multicomponent) version of Ablowitz-Ladik equations \cite{GI}. In this way we
extend the link between biorthogonal polynomials on the unit circle and
Ablowitz-Ladik hierarchy to the matrix case.Comment: 23 pages, accepted on publication on J. Phys. A., electronic link:
http://stacks.iop.org/1751-8121/42/36521
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