1,872 research outputs found
Magnetically induced Ferroelectricity in BiCuO
The tetragonal copper oxide BiCuO has an unusual crystal structure
with a three-dimensional network of well separated CuO plaquettes. This
material was recently predicted to host electronic excitations with an
unconventional spectrum and the spin structure of its magnetically ordered
state appearing at T 43 K remains controversial. Here we present the
results of detailed studies of specific heat, magnetic and dielectric
properties of BiCuO single crystals grown by the floating zone
technique, combined with the polarized neutron scattering and high-resolution
X-ray measurements. Our polarized neutron scattering data show Cu spins are
parallel to the plane. Below the onset of the long range antiferromagnetic
ordering we observe an electric polarization induced by an applied magnetic
field, which indicates inversion symmetry breaking by the ordered state of Cu
spins. For the magnetic field applied perpendicular to the tetragonal axis, the
spin-induced ferroelectricity is explained in terms of the linear
magnetoelectric effect that occurs in a metastable magnetic state. A relatively
small electric polarization induced by the field parallel to the tetragonal
axis may indicate a more complex magnetic ordering in BiCuO
Does Starting School Before Labor Day Affect High School Retention and Graduation: Evidence From Virginia\u27s Kings Dominion Law
Several states have required K-12 public schools to start after Labor Day in an effort to aid the tourism and hospitality industry. However, little is known about how these policies impact educational outcomes. We examine the impact of Virginia\u27s post-Labor Day school start law on high school retention and graduation rates. We use a difference-in-differences model to exploit exogenous variation in school division start dates. Our results show small differences of up to three weeks have little effect on high school dropout and graduation rates. Our findings inform the debate on post-Labor Day school start laws and compulsory attendance age cutoff laws
Intricacies of the Co spin state in SrCoIrO: an x-ray absorption and magnetic circular dichroism study
We report on a combined soft x-ray absorption and magnetic circular dichroism
(XMCD) study at the Co- on the hybrid 3/5 solid state oxide
SrCoIrO with the KNiF structure. Our data
indicate unambiguously a pure high spin state for the Co
(3) ions with a significant unquenched orbital moment
despite the sizeable elongation of the CoO octahedra. Using quantitative
model calculations based on parameters consistent with our spectra, we have
investigated the stability of this high spin state with respect to the
competing low spin and intermediate spin states.Comment: 7 pages, 4 figure
Electronic signature of the vacancy ordering in NbO (Nb3O3)
We investigated the electronic structure of the vacancy-ordered 4d-transition
metal monoxide NbO (Nb3O3) using angle-integrated soft- and hard-x-ray
photoelectron spectroscopy as well as ultra-violet angle-resolved photoelectron
spectroscopy. We found that density-functional-based band structure
calculations can describe the spectral features accurately provided that
self-interaction effects are taken into account. In the angle-resolved spectra
we were able to identify the so-called vacancy band that characterizes the
ordering of the vacancies. This together with the band structure results
indicates the important role of the very large inter-Nb-4d hybridization for
the formation of the ordered vacancies and the high thermal stability of the
ordered structure of niobium monoxide
Incommensurate spin correlations in highly oxidized cobaltates LaSrCoO
We observe quasi-static incommensurate magnetic peaks in neutron scattering
experiments on layered cobalt oxides La2-xSrxCoO4 with high Co oxidation states
that have been reported to be paramagnetic. This enables us to measure the
magnetic excitations in this highly hole-doped incommensurate regime and
compare our results with those found in the low-doped incommensurate regime
that exhibit hourglass magnetic spectra. The hourglass shape of magnetic
excitations completely disappears given a high Sr doping. Moreover, broad
low-energy excitations are found, which are not centered at the incommensurate
magnetic peak positions but around the quarter-integer values that are
typically exhibited by excitations in the checkerboard charge ordered phase.
Our findings suggest that the strong inter-site exchange interactions in the
undoped islands are critical for the emergence of hourglass spectra in the
incommensurate magnetic phases of La2-xSrxCoO4.Comment: http://www.nature.com/articles/srep25117
Recommended from our members
Charge-transfer energy in iridates: A hard x-ray photoelectron spectroscopy study
We have investigated the electronic structure of iridates in the double perovskite crystal structure containing either Ir4+ or Ir5+ using hard x-ray photoelectron spectroscopy. The experimental valence band spectra can be well reproduced using tight-binding calculations including only the Ir 5d, O 2p, and O 2s orbitals with parameters based on the downfolding of the density-functional band structure results. We found that, regardless of the A and B cations, the A2BIrO6 iridates have essentially zero O 2p to Ir 5d charge-transfer energies. Hence double perovskite iridates turn out to be extremely covalent systems with the consequence being that the magnetic exchange interactions become very long ranged, thereby hampering the materialization of the long-sought Kitaev physics. Nevertheless, it still would be possible to realize a spin-liquid system using the iridates with a proper tuning of the various competing exchange interactions
k=0Magnetic Structure and Absence of Ferroelectricity in SmFeO3
SmFeO3 has attracted considerable attention very recently due to the reported
multiferroic properties above room-temperature. We have performed powder and
single crystal neutron diffraction as well as complementary polarization
dependent soft X-ray absorption spectroscopy measurements on floating-zone
grown SmFeO3 single crystals in order to determine its magnetic structure. We
found a k=0 G-type collinear antiferromagnetic structure that is not compatible
with inverse Dzyaloshinskii-Moriya interaction driven ferroelectricity. While
the structural data reveals a clear sign for magneto-elastic coupling at the
N\'eel-temperature of ~675 K, the dielectric measurements remain silent as far
as ferroelectricity is concerned
Predicting hemoglobin levels in whole blood donors using transition models and mixed effects models
Background: To optimize the planning of blood donations but also to continue motivating the volunteers it is important to streamline the practical organization of the timing of donations. While donors are asked to return for donation after a suitable period, still a relevant proportion of blood donors is deferred from donation each year due to a too low hemoglobin level. Rejection of donation may demotivate the candidate donor and implies an inefficient planning of the donation process. Hence, it is important to predict the future hemoglobin level to improve the planning of donors' visits to the blood bank. Methods. The development of the hemoglobin prediction rule is based on longitudinal (panel) data from blood donations collected by Sanquin (the only blood product collecting and supplying organization in the Netherlands). We explored and contrasted two popular statistical models, i.e. the transition (autoregressive) model and the mixed effects model as plausible models to account for the dependence among subsequent hemoglobin levels within a donor. Results: The predictors of the future hemoglobin level are age, season, hemoglobin levels at the previous visits, and a binary variable indicating whether a donation was made at the previous visit. Based on cross-validation, the areas under the receiver operating characteristic curve (AUCs) for male donors are 0.83 and 0.81 for the transition model and the mixed effects model, respectively; for female donors we obtained AUC values of 0.73 and 0.72 for the transition model and the mixed effects model, respectively. Conclusion: We showed that the transition models and the mixed effects models provide a much better prediction compared to a multiple linear regression model. In general, the transition model provides a somewhat better prediction than the mixed effects model, especially at high visit numbers. In addition, the transition model offers a better trade-off between sensitivity and specificity when varying the cut-off values for eligibility in predicted values. Hence transition models make the prediction of hemoglobin level more precise and may lead to less deferral from donation in the future
- …