394 research outputs found
Abundance Anomalies in the X-ray Spectra of the Planetary Nebulae NGC 7027 and BD +30 363
We revisit Chandra observations of the planetary nebulae NGC 7027 and BD +30 3639 in order to address the question of abundance anomalies in the X-ray emitting gas. Enhanced abundances relative to solar of magnesium (Mg) for NGC 7027 and neon (Ne) for BD +30 3639 are required to fit their X-ray spectra, whereas observations at optical and infrared wavelengths show depleted Mg and Ne in these systems. We attribute the enhancement of Mg in NGC 7027 in the X-ray, relative to the optical, to the depletion of Mg onto dust grains within the optical nebula. For BD +30 3639, we speculate that the highly enhanced Ne comes from a WD companion, which accreted a fraction of the wind blown by the asymptotic giant branch progenitor, and went through a nova-like outburst which enriched the X-ray emitting gas with Ne
Cross‐scale seismic anisotropy analysis in metamorphic rocks from the COSC‐1 borehole in the Scandinavian Caledonides
Metamorphic and deformed rocks in thrust zones show particularly high seismic anisotropy causing challenges for seismic imaging and interpretation. A good example is the Seve Nappe Complex in central Sweden, an old exhumed orogenic thrust zone that is characterized by a strong but incoherent seismic reflectivity and considerable seismic anisotropy. However, only little is known about their origin in relation to composition and structural influences on measurements at different seismic scales. Here, we present a new integrative study of cross‐scale seismic anisotropy analyses combining mineralogical composition, microstructural analyses and seismic laboratory experiments from the COSC‐1 borehole, which sampled a 2.5 km‐deep section of metamorphic rocks deformed in an orogenic root now preserved in the Lower Seve Nappe. While there is strong crystallographic preferred orientation in most samples in general, variations in anisotropy depend mostly on bulk mineral composition and dominant core lithology as shown by a strong correlation between these. This relationship enables to identify three distinct seismic anisotropy facies providing a continuous anisotropy profile along the borehole. Moreover, comparison of laboratory seismic measurements and electron‐backscatter diffraction data reveals a strong scale‐dependence, which is more pronounced in the highly deformed, heterogeneous samples. This highlights the need for comprehensive cross‐validation of microscale anisotropy analyses with additional lithological data when integrating seismic anisotropy over seismic scales
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Field-induced interactions in magneto-active elastomers - a comparison of experiments and simulations
In this contribution, field-induced interactions of magnetizable particles embedded into a soft elastomer matrix are analyzed with regard to the resulting mechanical deformations. By comparing experiments for two-, three- and four-particle systems with the results of finite element simulations, a fully coupled continuum model for magneto-active elastomers is validated with the help of real data for the first time. The model under consideration permits the investigation of magneto-active elastomers with arbitrary particle distances, shapes and volume fractions as well as magnetic and mechanical properties of the individual constituents. It thus represents a basis for future studies on more complex, realistic systems. Our results show a very good agreement between experiments and numerical simulations—the deformation behavior of all systems is captured by the model qualitatively as well as quantitatively. Within a sensitivity analysis, the influence of the initial particle positions on the systems' response is examined. Furthermore, a comparison of the full three-dimensional model with the often used, simplified two-dimensional approach shows the typical overestimation of resulting interactions in magneto-active elastomers
Variability-aware Datalog
Variability-aware computing is the efficient application of programs to
different sets of inputs that exhibit some variability. One example is program
analyses applied to Software Product Lines (SPLs). In this paper we present the
design and development of a variability-aware version of the Souffl\'{e}
Datalog engine. The engine can take facts annotated with Presence Conditions
(PCs) as input, and compute the PCs of its inferred facts, eliminating facts
that do not exist in any valid configuration. We evaluate our variability-aware
Souffl\'{e} implementation on several fact sets annotated with PCs to measure
the associated overhead in terms of processing time and database size.Comment: PADL'20 pape
3D sub-nanometer analysis of glucose in an aqueous solution by cryo-atom probe tomography
Atom Probe Tomography (APT) is currently a well-established technique to analyse the composition of solid materials including metals, semiconductors and ceramics with up to near-atomic resolution. Using an aqueous glucose solution, we now extended the technique to frozen solutions. While the mass signals of the common glucose fragments C(x)H(y) and C(x)O(y)H(z) overlap with (H(2)O)(n)H from water, we achieved stoichiometrically correct values via signal deconvolution. Density functional theory (DFT) calculations were performed to investigate the stability of the detected pyranose fragments. This paper demonstrates APT’s capabilities to achieve sub-nanometre resolution in tracing whole glucose molecules in a frozen solution by using cryogenic workflows. We use a solution of defined concentration to investigate the chemical resolution capabilities as a step toward the measurement of biological molecules. Due to the evaporation of nearly intact glucose molecules, their position within the measured 3D volume of the solution can be determined with sub-nanometre resolution. Our analyses take analytical techniques to a new level, since chemical characterization methods for cryogenically-frozen solutions or biological materials are limited
Magic Islands and Barriers to Attachment: A Si/Si(111)7x7 Growth Model
Surface reconstructions can drastically modify growth kinetics during initial
stages of epitaxial growth as well as during the process of surface
equilibration after termination of growth. We investigate the effect of
activation barriers hindering attachment of material to existing islands on the
density and size distribution of islands in a model of homoepitaxial growth on
Si(111)7x7 reconstructed surface. An unusual distribution of island sizes
peaked around "magic" sizes and a steep dependence of the island density on the
growth rate are observed. "Magic" islands (of a different shape as compared to
those obtained during growth) are observed also during surface equilibration.Comment: 4 pages including 5 figures, REVTeX, submitted to Physical Review
Carbon Atom Reactivity with Amorphous Solid Water: H2O-Catalyzed Formation of H2CO
We report new computational and experimental evidence of an efficient and astrochemically relevant formation route to formaldehyde (H2CO). This simplest carbonylic compound is central to the formation of complex organics in cold interstellar clouds and is generally regarded to be formed by the hydrogenation of solid-state carbon monoxide. We demonstrate H2CO formation via the reaction of carbon atoms with amorphous solid water. Crucial to our proposed mechanism is a concerted proton transfer catalyzed by the water hydrogen bonding network. Consequently, the reactions 3C + H2O → 3HCOH and 1HCOH → 1H2CO can take place with low or without barriers, contrary to the high-barrier traditional internal hydrogen migration. These low barriers (or the absence thereof) explain the very small kinetic isotope effect in our experiments when comparing the formation of H2CO to D2CO. Our results reconcile the disagreement found in the literature on the reaction route C + H2O → H2CO. © 2021 The Authors. Published by American Chemical Society.Ko-Ju Chuang and Melissa McClure are greatly thanked for stimulating discussions. We also thank the anonymous reviewers for their suggestions. Computer time was granted by the state of Baden-Württemberg through bwHPC and the German Research Foundation (DFG) through grant no. INST 40/467-1FUGG is greatly acknowledged. G.M thanks the Alexander von Humboldt Foundation for a postdoctoral research grant. We thank the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) for supporting this work by funding EXC 2075-390740016 under Germany’s Excellence Strategy. T.L. is grateful for support from the Dutch Research Council (NWO) via a VENI fellowship (Grant No. 722.017.008). Astrochemistry in Leiden is supported by the Dutch Astrochemistry Network (DAN) II (Project No. 648.000.029). G.F. acknowledges financial support from the Russian Ministry of Science and Higher Education via the State Assignment Contract. FEUZ-2020-0038. This work has been supported in part by the Danish National Research Foundation through the Center of Excellence “InterCat” (Grant Agreement No.: DNRF150)
Carbon atom reactivity with amorphous solid water: H2O-catalyzed formation of H2CO
NWOTheoretical Chemistr
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