3-O-Benzyl-6-O-benzoyl-1,2-O-isopropil­idene-5-C-nitro­methyl-a-d-glucofuran­ose

The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropyl­idene-a-d-glucofuran-5-one with nitro­methane. The conformation of the five membered rings is as expected from the precursor compound and the mol­ecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O—H⋯O hydrogen bond and some intra­molecular and inter­molecular C—H⋯O inter­actions are observed in the structure

Ethyl 1-O-tert-butyl­dimethyl­silyl-2,3-O-isopropyl­idene-5-[(2′S)-tetra­hydro­pyran-2-yl­oxy]-d-glycero-α-d-manno-hepto­furonate

The title compound {systematic name: (2S,3R)-ethyl 3-[(3aS,4R,6S,6aS)-6-tert-butyl­dimethyl­silyl­oxy-2,2-dimethyl­per­hydro­furo[3,4-d][1,3]dioxol-4-yl]-2-nitro-3-[(S)-tetra­hydro-2H-pyran-2-yl­oxy]propanoate}, C23H41NO10Si, is the product of the Henry reaction of 1-O-tert-butyl­dimethyl­silyl-2,3-O-isopropyl­idene-α-d-lyxo-penta­dialdo-1,4-furan­ose with ethyl nitro­acetate and the subsequent protection of its C-5 hydr­oxy group as tetra­hydro­pyranyl, in order to avoid the retro-Henry reaction. The tetra­hydro­pyranyl group adopts a chair conformation. The absolute configuration, assumed from the synthesis, was confirmed from the diffraction data

Growth of octopus (Octopus vulgaris) males and females under culture conditions

Publicado

Ajuste psicosocial en cibervíctimas y ciberagresores en educación secundaria

The rise of cyberbullying among high school students and the importance of certain variables of psychological adjustment for the comprehension of this type of violent behavior both in bullies and in victims. This work aims to analyze the psychological profile of individuals involved in situations of cyberbullying, both victims and bullies. The adjustment variables analyzed were self-concept, perceived stress, loneliness, depressive symptomatology, social anxiety, life satisfaction, and emotional intelligence. Using a sample of 1318 adolescents (47% boys), aged between 11 and 18 years (M = 13.8, SD = 1.32), three contrast groups were established for cybervictims (severe cybervictims, moderate cybervictims, and non-cybervictims) and three groups for cyberbullies (severe cyberbullies, moderate cyberbullies, and non-cyberbullies). The results obtained through analysis of variance showed that both cybervictims and cyberbullies show deterioration in most of the studied dimensions, albeit with a different profile. Severe cybervictims showed higher scores in perceived stress, loneliness, depression, and social anxiety, and lower scores in self-concept, life satisfaction, and emotional intelligence, in comparison with non-cybervictims. Severe cyberbullies obtained higher scores in perceived stress, loneliness, and depression, and lower scores in self-concept and life satisfaction, compared to non-cyberbullies. These results allow deepening our comprehension of cyberbullying among students to improve preventive and intervention programs in schools.El auge de las agresiones cibernéticas entre estudiantes de secundaria y la importancia de ciertas variables de ajuste psicosocial para la comprensión de este tipo de conducta violenta, tanto en agresores como en víctimas, plantean como objetivo en el presente trabajo analizar el perfil psicosocial de ambos implicados en situaciones de ciberagresión. Las variables de ajuste analizadas fueron autoconcepto, estrés percibido, soledad, sintomatología depresiva, ansiedad social, satisfacción con la vida e inteligencia emocional. A partir de una muestra de 1318 adolescentes (47% chicos), de entre 11 y 18 años, se establecieron tres grupos de contraste para cibervíctimas (víctimas severas, moderadas y no cibervíctimas) y tres grupos para ciberagresores (ciberagresores severos, moderados y no ciberagresores). El análisis de varianza mostró que los implicados presentan perfiles psicosociales diferentes y deteriorados. Las cibervíctimas severas mostraron mayor estrés percibido, soledad, depresión y ansiedad social, y menor autoconcepto, satisfacción con la vida e IE, en comparación con las no cibervíctimas. Los ciberagresores severos mostraron mayor estrés percibido, soledad y depresión, y menor autoconcepto y satisfacción con la vida, comparativamente con los no ciberagresores. Estos resultados permiten profundizar en la comprensión del ciberacoso entre estudiantes y mejorar los programas preventivos y de intervención en escuelas

Aplicación de diferentes métodos de marcado externo a Octopus vulgaris Cuvier, 1797 con referencia especial a las marcas de tipo T y a los discos de Petersen

En este trabajo se presentan datos de persistencia y efectos provocados por una gran variedad de estilos de marcas (loops, marcas de conejos, cinchas, cintas plásticas flexibles, lancetas, discos de Petersen, marcas de tipo T, marcas plásticas circulares, banderillas plásticas rectangulares, soportes de bisutería, pines comerciales y quemaduras con nitrógeno líquido) aplicadas al cefalópodo Octopus vulgaris Cuvier, 1797 sometido a condiciones de cultivo. Tras una primera revisión de los resultados obtenidos con los diferentes sistemas de marcado se concluye que los discos de Petersen y las marcas de tipo T son los más aconsejables. Ambos muestran una retención adecuada después de un mes (90 y 80 % respectivamente), una persistencia máxima de tres meses, un coste similar y ambos son detectados externamente con facilidad. Sin embargo, los discos de Petersen producen heridas considerables y requieren un proceso de inserción más laborioso, por lo que, finalmente, el sistema considerado más adecuado fue la inserción de marcas de tipo T en el brazo III izquierdoThis paper presents a study on the persistence and effects caused by a wide variety of types of tag (loops, rabbit tags, girths, flexible plastic bands, small darts, Petersen disks, T-bar anchor tags, circular plastic tags, rectangular plastic flags, jewellery pins, commercial badges, and burning with liquid nitrogen) applied to the cephalopod Octopus vulgaris Cuvier, 1797, under culture conditions. Preliminary analysis of the results obtained with the different tagging systems indicates that Petersen disks and T-bar anchor tags are the most suitable types. Both provide adequate retention after 1 month (90 % and 80 %, respectively), a maximum persistence of three months, a similar cost, and they are easily recognised externally. However, Petersen disks can produce serious injuries, and require a more laborious insertion process. Therefore, in the final analysis, the insertion of T-bar anchor tags in left arm III can be considered the most appropriate systemThis work has been carried out with a grant from the Inter-ministerial Commission for Science and Technology and the Instituto Español de Oceanografía, as part of the CYTMAR 97-0323 projec

Desarrollo de un sistema de toma de decisiones autónomo y ejemplo de aplicación a servicios de seguridad bajo demanda

Existen multitud de sistemas de adquisición de datos autónomos basados en diferentes metodologías, muchos de ellos se imparten en la educación universitaria y otros por el contrario surgen de un exhaustivo trabajo de investigación científica. Estos sistemas se aplican hoy en día en un gran número de áreas, siendo todas ellas muy diversas aunque con importantes nexos comunes. En el presente artículo se propone, a partir de un proyecto fin de carrera, un sistema autónomo de adquisición de datos y reconocimiento del entorno, con un alto índice de escalabilidad e integración a nuevos espacios. Para probar su eficacia se propone también una aplicación robotizada que utiliza estas características en el área de la seguridad, un campo en el que resultan especialmente claras las propiedades diferenciadoras del método propuesto

Measurement of jet-substructure observables in top quark, W boson and light jet production in proton-proton collisions at √s = 13 TeV with the ATLAS detector

Artículo escrito por un elevado número de autores, solo se referencian el que aparece en primer lugar, el nombre del grupo de colaboración, si lo hubiere, y los autores pertenecientes a la UAMA measurement of jet substructure observables is presented using data collected in 2016 by the ATLAS experiment at the LHC with proton-proton collisions at √ s =13 TeV. Large-radius jets groomed with the trimming and soft-drop algorithms are studied.Dedicated event selections are used to study jets produced by light quarks or gluons, andhadronically decaying top quarks and W bosons. The observables measured are sensitive to substructure, and therefore are typically used for tagging large-radius jets from boosted massive particles. These include the energy correlation functions and the N-subjettiness variables. The number of subjets and the Les Houches angularity are also considered. The distributions of the substructure variables, corrected for detector effects, are compared tothe predictions of various Monte Carlo event generators. They are also compared between the large-radius jets originating from light quarks or gluons, and hadronically decaying top quarks and W bosonsWe thank CERN for the very successful operation of the LHC, as well as the support staff from our institutions without whom ATLAS could not be operated efficiently. We acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWFW and FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq and FAPESP, Brazil; NSERC, NRC and CFI, Canada; CERN; CONICYT, Chile; CAS, MOST and NSFC, China; COLCIENCIAS, Colombia; MSMT CR, MPO CR and VSC CR, Czech Republic; DNRF and DNSRC, Denmark; IN2P3-CNRS, CEA-DRF/IRFU, France; SRNSFG, Georgia; BMBF, HGF, and MPG, Germany; GSRT, Greece; RGC, Hong Kong SAR, China; ISF and Benoziyo Center, Israel; INFN, Italy; MEXT and JSPS, Japan; CNRST, Morocco; NWO, Netherlands; RCN, Norway; MNiSW and NCN, Poland; FCT, Portugal; MNE/IFA, Romania; MES of Russia and NRC KI, Russian Federation; JINR; MESTD, Serbia; MSSR, Slovakia; ARRS and MIZS, Slovenia; DST/NRF, South Africa; ˇ MINECO, Spain; SRC and Wallenberg Foundation, Sweden; SERI, SNSF and Cantons of Bern and Geneva, Switzerland; MOST, Taiwan; TAEK, Turkey; STFC, United Kingdom; DOE and NSF, United States of America. In addition, individual groups and members have received support from BCKDF, CANARIE, CRC and Compute Canada, Canada; COST, ERC, ERDF, Horizon 2020, and Marie Sk lodowska-Curie Actions, European Union; Investissements d’ Avenir Labex and Idex, ANR, France; DFG and AvH Foundation, Germany; Herakleitos, Thales and Aristeia programmes co-financed by EU-ESF and the Greek NSRF, Greece; BSF-NSF and GIF, Israel; CERCA Programme Generalitat de Catalunya, Spain; The Royal Society and Leverhulme Trust, United Kingdom. The crucial computing support from all WLCG partners is acknowledged gratefully, in particular from CERN, the ATLAS Tier-1 facilities at TRIUMF (Canada), NDGF (Denmark, Norway, Sweden), CC-IN2P3 (France), KIT/GridKA (Germany), INFN-CNAF (Italy), NL-T1 (Netherlands), PIC (Spain), ASGC (Taiwan), RAL (U.K.) and BNL (U.S.A.), the Tier-2 facilities worldwide and large non-WLCG resource providers. Major contributors of computing resources are listed in re

Fatty acid composition and age estimation of wild Octopus vulgaris paralarvae

En prensa2,041

Metas académicas y estrategias de aprendizaje en estudiantes españoles de Educación Secundaria Obligatoria con ansiedad social

The purpose of this study was to analyse the relationship between high social anxiety, academic goals and learning strategies in a sample of 2,022 (51.1% male) Spanish adolescents aged 12–16. The Social Phobia and Anxiety Inventory (SPAI), Achievement Goal Tendencies Questionnaire (AGTQ) and Learning and Studies Skills Strategies Inventory — High School Version (LASSI-HS) were used to assess the variables. The results showed no statistically significant differences in goal orientations between students with and without high social anxiety. However, students with high social anxiety used learning strategies significantly less. In addition, the logistic regression results indicated that high social anxiety acts as a significant predictor for setting social reinforcement goals and learning and study strategies.El objetivo de este estudio fue analizar la relación entre la alta ansiedad social, las metas académicas y las estrategias de aprendizaje en una muestra de 2,022 (51.1% varones) adolescentes españoles de 12 a 16 años. Las variables fueron evaluadas mediante los cuestionarios Social Phobia and Anxiety Inventory (SPAI), Achievement Goal Tendencies Questionnaire (AGTQ) y Learning And Studies Skills Inventory — High school (LASSI-HS). Los resultados no mostraron ninguna diferencia estadísticamente significativa en las orientaciones de meta entre estudiantes con y sin alta ansiedad social. No obstante, los estudiantes con alta ansiedad social utilizaron significativamente menos estrategias de aprendizaje. Asimismo, los resultados obtenidos de la regresión logística señalaron que la alta ansiedad social actúa como predictor significativo de las metas de reconocimiento social y de las estrategias de aprendizaje y estudio.This work has been funded by the SEJ 2004-07311/EDUC Project, under the Plan Nacional de Investigación Científica, Desarrollo de Innovación Tecnológica del MEC (MEC National Plan for Scientific Research and Technological Innovation Development). / Este artículo de investigación ha sido financiado a través del Proyecto SEJ 2004-07311/EDUC perteneciente al Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica del MEC

Fatty acids composition and age estimation of wild Octopus vulgaris paralarvae

Under culture conditions, lipid composition and specifically, the fatty acid profile of reared paralarvae is significantly different from hatchlings. Therefore, comparing wild paralarvae and reared paralarvae of similar age would allow us to elucidate if the changes in fatty acid profile are related with a non-optimal prey composition or are caused by the normal development. The aim of this study was analyze, for the very first time, the fatty acid profile of wild Octopus vulgaris paralarvae individually, determining for each paralarvae their age through deposition of daily increments on lateral hood surface of the beaks. The main goal is to clear up lipid requirements of paralarvae and optimise the diet of reared paralarvae