The local structure of SO2 and SO3 on Ni(1 1 1): a scanned-energy mode photoelectron diffraction study

O 1s and S 2p scanned-energy mode photoelectron diffraction (PhD) data, combined with multiple-scattering simulations, have been used to determine the local adsorption geometry of the SO2 and SO3 species on a Ni(1 1 1) surface. For SO2, the application of reasonable constraints on the molecular conformation used in the simulations leads to the conclusion that the molecule is centred over hollow sites on the surface, with the molecular plane essentially parallel to the surface, and with both S and O atoms offset from atop sites by almost the same distance of 0.65 Å. For SO3, the results are consistent with earlier work which concluded that surface bonding is through the O atoms, with the S atom higher above the surface and the molecular symmetry axis almost perpendicular to the surface. Based on the O 1s PhD data alone, three local adsorption geometries are comparably acceptable, but only one of these is consistent with the results of an earlier normal-incidence X-ray standing wave (NIXSW) study. This optimised structural model differs somewhat from that originally proposed in the NIXSW investigation

Theory of a magnetic microscope with nanometer resolution

We propose a theory for a type of apertureless scanning near field microscopy that is intended to allow the measurement of magnetism on a nanometer length scale. A scanning probe, for example a scanning tunneling microscope (STM) tip, is used to scan a magnetic substrate while a laser is focused on it. The electric field between the tip and substrate is enhanced in such a way that the circular polarization due to the Kerr effect, which is normally of order 0.1% is increased by up to two orders of magnitude for the case of a Ag or W tip and an Fe sample. Apart from this there is a large background of circular polarization which is non-magnetic in origin. This circular polarization is produced by light scattered from the STM tip and substrate. A detailed retarded calculation for this light-in-light-out experiment is presented.Comment: 17 pages, 8 figure

Detailed Calculation of Test-Mass Charging in the LISA Mission

The electrostatic charging of the LISA test masses due to exposure of the spacecraft to energetic particles in the space environment has implications in the design and operation of the gravitational inertial sensors and can affect the quality of the science data. Robust predictions of charging rates and associated stochastic fluctuations are therefore required for the exposure scenarios expected throughout the mission. We report on detailed charging simulations with the Geant4 toolkit, using comprehensive geometry and physics models, for Galactic cosmic-ray protons and helium nuclei. These predict positive charging rates of 50 +e/s (elementary charges per second) for solar minimum conditions, decreasing by half at solar maximum, and current fluctuations of up to 30 +e/s/Hz^{1/2}. Charging from sporadic solar events involving energetic protons was also investigated. Using an event-size distribution model, we conclude that their impact on the LISA science data is manageable. Several physical processes hitherto unexplored as potential charging mechanisms have also been assessed. Significantly, the kinetic emission of very low-energy secondary electrons due to bombardment of the inertial sensors by primary cosmic rays and their secondaries can produce charging currents comparable with the Monte Carlo rates.Comment: 31 pages, 18 figures, 4 tables. to be published in Astroparticle Physics. Changed due to error found in normalisation of the simulation result

Retrieval of soil moisture and vegetation water content using SSM/I data over a corn and soybean region

The potential for soil moisture and vegetation water content retrieval using Special Sensor Microwave Imager (SSM/I) brightness temperature over a corn and soybean field region was analyzed and assessed using datasets from the Soil Moisture Experiment 2002 (SMEX02). Soil moisture retrieval was performed using a dual-polarization 19.4-GHz data algorithm that requires the specification of two vegetation parameters¿single scattering albedo and vegetation water content. Single scattering albedo was estimated using published values. A method for estimating the vegetation water content from the microwave polarization index using SSM/I 37.0-GHz data was developed for the region using extensive datasets developed as part of SMEX02. Analyses indicated that the sensitivity of the brightness temperature to soil moisture decreased as vegetation water content increased. However, there was evidence that SSM/I brightness temperatures changed in response to soil moisture increases resulting from rainfall during the later stages of crop growth. This was partly attributed to the lower soil and vegetation thermal temperatures that typically followed a rainfall. Comparisons between experimentally measured volumetric soil moisture and SSM/I-retrieved soil moisture indicated that soil moisture retrieval was feasible using SSM/I data, but the accuracy highly depended upon the levels of vegetation and atmospheric precipitable water; the standard error of estimate over the 3-week study period was 5.49%. The potential for using this approach on a larger scale was demonstrated by mapping the state of Iowa. Results of this investigation provide new insights on how one might operationally correct for vegetation effects using high-frequency microwave observation

Flux-noise spectra around the Kosterlitz-Thouless transition for two-dimensional superconductors

The flux-noise spectra around the Kosterlitz-Thouless transition are obtained from simulations of the two-dimensional resistively shunted junction model. In particular the dependence on the distance $d$ between the pick-up coil and the sample is investigated. The typical experimental situation corresponds to the large-$d$ limit and a simple relation valid in this limit between the complex impedance and the noise spectra is clarified. Features, which distinguish between the large- and small-$d$ limit, are identified and the possibility of observing these features in experiments is discussed.Comment: 12 pages including 8 figures, submitted to Phys. Rev.

The Capaciousness of No: Affective Refusals as Literacy Practices

© 2020 The Authors. Reading Research Quarterly published by Wiley Periodicals, Inc. on behalf of International Literacy Association The authors considered the capacious feeling that emerges from saying no to literacy practices, and the affective potential of saying no as a literacy practice. The authors highlight the affective possibilities of saying no to normative understandings of literacy, thinking with a series of vignettes in which children, young people, and teachers refused literacy practices in different ways. The authors use the term capacious to signal possibilities that are as yet unthought: a sense of broadening and opening out through enacting no. The authors examined how attention to affect ruptures humanist logics that inform normative approaches to literacy. Through attention to nonconscious, noncognitive, and transindividual bodily forces and capacities, affect deprivileges the human as the sole agent in an interaction, thus disrupting measurements of who counts as a literate subject and what counts as a literacy event. No is an affective moment. It can signal a pushback, an absence, or a silence. As a theoretical and methodological way of thinking/feeling with literacy, affect proposes problems rather than solutions, countering solution-focused research in which the resistance is to be overcome, co-opted, or solved. Affect operates as a crack or a chink, a tiny ripple, a barely perceivable gesture, that can persist and, in doing so, hold open the possibility for alternative futures

Long‐term trends in the distribution, abundance and impact of native “injurious” weeds

Questions: How can we quantify changes in the distribution and abundance of injurious weed species (Senecio jacobaea, Cirsium vulgare, Cirsium arvense, Rumex obtusifolius, Rumex crispus and Urtica dioica), over long time periods at wide geographical scales? What impact do these species have on plant communities? To what extent are changes driven by anthropogenically induced drivers such as disturbance, eutrophication and management? Location: Great Britain. Methods: Data from national surveys were used to assess changes in the frequency and abundance of selected weed species between 1978 and 2007. This involved novel method development to create indices of change, and to relate changes in distribution and abundance of these species to plant community diversity and inferred changes in resource availability, disturbance and management. Results: Three of the six weed species became more widespread in GB over this period and all of them increased in abundance (in grasslands, arable habitats, roadsides and streamsides). Patterns were complex and varied by landscape context and habitat type. For most of the species, there were negative relationships between abundance, total plant species richness, grassland, wetland and woodland indicators. Each individual species responds to a different combination of anthropogenic drivers but disturbance, fertility and livestock management significantly influenced most species. Conclusions: The increase in frequency and abundance of weeds over decades has implications for landscape‐scale plant diversity, fodder yield and livestock health. This includes reductions in plant species richness, loss of valuable habitat specialists and homogenisation of vegetation communities. Increasing land‐use intensity, excessive nutrient input, overgrazing, sward damage, poaching and bare ground in fields and undermanagement or too frequent cutting on linear features may have led to increases in weeds. These weeds do have conservation value so we are not advocating eradication, rather co‐existence, without dominance. Land management policy needs to adapt to benefit biodiversity and agricultural productivity

‘The Brick’ is not a brick: a comprehensive study of the structure and dynamics of the central molecular zone cloud G0.253+0.016

This article has been accepted for publication in Monthly Notices of the Royal Astronomical Society © 2019 The Author(s). Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved.In this paper we provide a comprehensive description of the internal dynamics of G0.253+0.016 (a.k.a. ‘the Brick’); one of the most massive and dense molecular clouds in the Galaxy to lack signatures of widespread star formation. As a potential host to a future generation of high-mass stars, understanding largely quiescent molecular clouds like G0.253+0.016 is of critical importance. In this paper, we reanalyse Atacama Large Millimeter Array cycle 0 HNCO J = 4(0, 4) − 3(0, 3) data at 3 mm, using two new pieces of software that we make available to the community. First, SCOUSEPY, a Python implementation of the spectral line fitting algorithm SCOUSE. Secondly, ACORNS (Agglomerative Clustering for ORganising Nested Structures), a hierarchical n-dimensional clustering algorithm designed for use with discrete spectroscopic data. Together, these tools provide an unbiased measurement of the line-of-sight velocity dispersion in this cloud, σvlos,1D=4.4±2.1 km s−1, which is somewhat larger than predicted by velocity dispersion-size relations for the central molecular zone (CMZ). The dispersion of centroid velocities in the plane of the sky are comparable, yielding σvlos,1D/σvpos,1D∼1.2±0.3⁠. This isotropy may indicate that the line-of-sight extent of the cloud is approximately equivalent to that in the plane of the sky. Combining our kinematic decomposition with radiative transfer modelling, we conclude that G0.253+0.016 is not a single, coherent, and centrally condensed molecular cloud; ‘the Brick’ is not a brick. Instead, G0.253+0.016 is a dynamically complex and hierarchically structured molecular cloud whose morphology is consistent with the influence of the orbital dynamics and shear in the CMZ

Field Measurements of Terrestrial and Martian Dust Devils

Surface-based measurements of terrestrial and martian dust devils/convective vortices provided from mobile and stationary platforms are discussed. Imaging of terrestrial dust devils has quantified their rotational and vertical wind speeds, translation speeds, dimensions, dust load, and frequency of occurrence. Imaging of martian dust devils has provided translation speeds and constraints on dimensions, but only limited constraints on vertical motion within a vortex. The longer mission durations on Mars afforded by long operating robotic landers and rovers have provided statistical quantification of vortex occurrence (time-of-sol, and recently seasonal) that has until recently not been a primary outcome of more temporally limited terrestrial dust devil measurement campaigns. Terrestrial measurement campaigns have included a more extensive range of measured vortex parameters (pressure, wind, morphology, etc.) than have martian opportunities, with electric field and direct measure of dust abundance not yet obtained on Mars. No martian robotic mission has yet provided contemporaneous high frequency wind and pressure measurements. Comparison of measured terrestrial and martian dust devil characteristics suggests that martian dust devils are larger and possess faster maximum rotational wind speeds, that the absolute magnitude of the pressure deficit within a terrestrial dust devil is an order of magnitude greater than a martian dust devil, and that the time-of-day variation in vortex frequency is similar. Recent terrestrial investigations have demonstrated the presence of diagnostic dust devil signals within seismic and infrasound measurements; an upcoming Mars robotic mission will obtain similar measurement types