Effect of deflocculation on the efficiency of sludge reduction by Fenton process.

A novel approach to improve the efficiency of Fenton treatment for sludge reduction through the implication of a deflocculating agent citric acid, for the exclusion of extracellular polymeric substances (EPS) from waste-activated sludge (WAS), was investigated. Deflocculation was achieved with 0.06 g/g suspended solids (SS) of citric acid dosage. Fenton optimization studies using response surface methodology (RSM) revealed that 0.5 and 0.0055 g/g SS were the optimal dosages of H2O2 and Fe2+. The addition of a cation-binding agent set the pH value of sludge to 5 which did not affect the Fenton efficiency. The results presented in this study shows the advantage of deflocculating the sludge as SS and volatile suspended solids (VSS) reductions were found to be higher in the deflocculated (53 and 63 %, respectively) than in the flocculated (22 and 34 %, respectively) sludges. Kinetic investigation of the treatment showed that the rate of the reaction was four times higher in the deflocculated sludge than control. The methodology reported in this manuscript was successfully applied to a real case were the deflocculated mediated Fenton process reduced the sludge disposal cost from 297.8 to 61.9 US dollars/ton of sludge

Development of bioelectrochemical systems using various biogas fermenter effluents as inocula and municipal waste liquor as adapting substrate

The purpose of this research was to improve microbial fuel cell (MFC) performance – treating landfill-derived waste liquor – by applying effluents of various biogas fermenters as inocula. It turned out that the differences of initial microbial community profiles notably influenced the efficiency of MFCs. In fact, the adaptation time (during 3 weeks of operation) has varied significantly, depending on the source of inoculum and accordingly, the obtainable cumulative energy yields were also greatly affected (65% enhancement in case of municipal wastewater sludge inoculum compared to sugar factory waste sludge inoculum). Hence, it could be concluded that the capacity of MFCs to utilize the complex feedstock was heavily dependent on biological factors such as the origin/history of inoculum, the microbial composition as well as proper acclimation period. Therefore, these parameters should be of primary concerns for adequate process design to efficiently generate electricity with microbial fuel cells

Process optimisation for production and recovery of succinic acid using xylose-rich hydrolysates by Actinobacillus succinogenes

Succinic acid (SA) is a top platform chemical obtainable from biomass. The current study evaluated the potential of Actinobacillus succinogenes for SA production using xylose-rich hemicellulosic fractions of two important lignocellulosic feedstocks, olive pits (OP) and sugarcane bagasse (SCB) and the results were compared with pure xylose. Initial experiments were conducted in shake flask followed by batch and fed-batch cultivation in bioreactor. Further separation of SA from the fermented broth was carried out by adapting direct crystallisation method. During fed-batch culture, maximum SA titers of 36.7, 33.6, and 28.7 g/L was achieved on pure xylose, OP and SCB hydrolysates, respectively, with same conversion yield of 0.27 g/g. The recovery yield of SA accumulated on pure xylose, OP and SCB hydrolysates was 79.1, 76.5, and 75.2%, respectively. The results obtained are of substantial value and pave the way for development of sustainable SA biomanufacturing in an integrated biorefinery

Reducing the environmental impact of surgery on a global scale: systematic review and co-prioritization with healthcare workers in 132 countries

Abstract Background Healthcare cannot achieve net-zero carbon without addressing operating theatres. The aim of this study was to prioritize feasible interventions to reduce the environmental impact of operating theatres. Methods This study adopted a four-phase Delphi consensus co-prioritization methodology. In phase 1, a systematic review of published interventions and global consultation of perioperative healthcare professionals were used to longlist interventions. In phase 2, iterative thematic analysis consolidated comparable interventions into a shortlist. In phase 3, the shortlist was co-prioritized based on patient and clinician views on acceptability, feasibility, and safety. In phase 4, ranked lists of interventions were presented by their relevance to high-income countries and low–middle-income countries. Results In phase 1, 43 interventions were identified, which had low uptake in practice according to 3042 professionals globally. In phase 2, a shortlist of 15 intervention domains was generated. In phase 3, interventions were deemed acceptable for more than 90 per cent of patients except for reducing general anaesthesia (84 per cent) and re-sterilization of ‘single-use’ consumables (86 per cent). In phase 4, the top three shortlisted interventions for high-income countries were: introducing recycling; reducing use of anaesthetic gases; and appropriate clinical waste processing. In phase 4, the top three shortlisted interventions for low–middle-income countries were: introducing reusable surgical devices; reducing use of consumables; and reducing the use of general anaesthesia. Conclusion This is a step toward environmentally sustainable operating environments with actionable interventions applicable to both high– and low–middle–income countries

Anaerobic Digestion

Recent advances in technology to recover bioenergy from various feedstocks make them suitable alternatives to fossil fuel. This book contains several scientific discussions regarding microbes involved in biogas production, the anaerobic digestion process, their operation, and application for sustainable development. The book provides in-depth information about anaerobic digestion for researchers and graduate students. The editor sincerely thanks all the contributors, whose efforts have brought this book to fruition

High rate anaerobic treatment of Sago wastewater using HUASB with PUF as carrier

Sago industry is one of the major small-scale sectors in India and over 800 units are located in the southern State of Tamilnadu. Processing of sago generates enormous quantities of high strength wastewater requiring systematic treatment prior to disposal. The present study is an attempt to treat the sago wastewater using Hybrid Upflow Anaerobic Sludge Blanket (HUASB) reactor, which offers the advantages of both fixed film and up flow anaerobic sludge blanket treatment. HUASB reactor with a volume of 5.6 L was operated at Organic Loading Rates varying from 10.7 to 24.7 kg COD/m3.day. After 130 days of startup, the reactor produced appreciable decrease in COD of wastewater and removed solids efficiently. The COD removal varied from 91-87%. While the removal of Total Solids was in the range of 61-57%, that of volatile solids varied from 70-67%. The ideal OLR for the reactor was 23.5 kg COD/m3.day. The findings of the study open up newer possibilities of design low cost and compact onsite treatment systems with very short retention periods

Effect of sludge pretreatment on the performance of anaerobic/anoxic/oxic membrane bioreactor treating domestic wastewater

In the present study, two bench-scale anaerobic/ anoxic/ oxic submerged membrane bioreactors were used to study the effect of thermochemical sludge disintegration system on the excess sludge production. Among the two membrane bioreactors, one was named experimental membrane bioreactor and another one was named as control membrane bioreactor, where a part of the mixed liquor was treated with thermo chemical and was returned back to membrane bioreactor. Thermo chemical digestion of sludge was carried out at fixed pH (11) and temperature (75 °C) for 24 % chemical oxygen demand solubilization. The other one was named control membrane bioreactor and was used as control. The reactors were operated at three different mixed liquor suspended solids range starting from 7500 mg/L to 15000 mg/L. Both the membrane bioreactors were operated at a flux of 17 LMH over a period of 240 days. The designed flux was increased stepwise over a period of one week. During the 240 days of reactor operation, both the membrane bioreactors maintained relatively constant transmembrane pressure. The sludge digestion had no impact on chemical oxygen demand removal efficiency of the reactor. The results based on the study indicated that the proposed process configuration has potential to reduce the excess sludge production as well as it didn't detoriate the treated water quality

Treatment of poultry slaughterhouse wastewater in upflow anaerobic filter under low upflow velocity

The wastewater discharged by poultry slaughterhouse industries are characterized mainly by high biochemical oxygen demand, high suspended solids and complex mixture of fats, proteins and fibers requiring systematic treatment prior to disposal. In this study, the performance of an upflow anaerobic filter reactor for treating Indian poultry slaughterhouse wastewater under low upflow velocity of 1.38 m/day at mesophilic temperature (29-35 °C) was investigated. The reactor was inoculated with anaerobic non-granular sludge from an anaerobic reactor treating the poultry slaughterhouse wastewater. The reactor took 147 days for complete start-up with removal efficiencies of total chemical oxygen demand and soluble chemical oxygen demand of 70 and 79 % respectively. The maximum total chemical oxygen demand removal efficiency of 78 % was achieved at an organic loading rate of 10.05 kg/m3/day and at an hydraulic retention time of 12 h. The average methane content varied between 46 and 56 % and methane yield at maximum removal efficiency was 0.24 m3 CH4 /kg CODremoved.day. Sludge granules of 1-2 mm were observed in between the packing media. Scanning electron microscope analysis revealed that sludge granules are composed of clumps of Methanosarcina clustered with less intertwined Methanosaeta fibre of granules. The lower velocity used in this study has achieved better performance of the reactor by creating active microbial formation with stable pH upto an organic loading rate of 14.3 kg/m3/day. This has proved that the poultry slaughterhouse wastewater can be treated using anaerobic filter reactor under low upflow velocity

Effects of sludge pretreatment on sludge reduction in a lab-scale anaerobic/anoxic/oxic system treating domestic wastewater

Excess sludge disposal is one of the serious challenges in biological wastewater treatment. Reduction of sludge production would be an ideal way to solve sludge-associated problems rather than the post-treatment of the sludge produced. In this study, a new wastewater treatment process combining anaerobic/anoxic/oxic system with thermochemical sludge pretreatment was tested in a laboratory scale experiment. In this study, the effects of the sludge pretreatment on the excess sludge production in anaerobic/anoxic/oxic were investigated. The system was operated in two Runs (1 and 2). In Run 1, the system was operated as a reference and in Run 2, a part of the mixed liquid was pretreated thermochemically and was returned to the bioreactor. The average solubilization efficiency of pretreated sludge was found to be about 35 % during the study period of 220 days. Sludge production rate in Run 2 was less than that in Run 1 by about 52 %. Total phosphorous was removed by enhanced biological phosphorous removal with the removal efficiency of 83–87 % and 81–83 % for Run 1 and Run 2, respectively. Total nitrogen removal in Run 2 (79–82 %) was slightly higher than that in Run 1 (68–75 %). The mixed liquor suspended solids/mixed liquor volatile suspended solids ratio was identical after both runs in the range 78–83 %. The effluent water qualities were not significantly affected when operated with thermochemical pretreatment at pH 11 and 60 °C for 3 h during 7 months. From the present study it is concluded that thermochemical sludge pretreatment of anaerobic/anoxic/oxic process plays an important role in reduction of sludge production