311 research outputs found

    A new archive of large volcanic events over the past millennium derived from reconstructed summer temperatures

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    Information about past volcanic impact on climate is mostly derived from historic documentary data and sulfate depositions in polar ice sheets. Although these archives have provided important insights into the Earth's volcanic eruption history, the climate forcing and exact dating of many events is still vague. Here we apply a new method of break detection to the first millennium-length maximum latewood density reconstruction of Northern Hemisphere summer temperatures to develop an alternative record of large volcanic eruptions. The analysis returns fourteen outstanding cooling events, all of which agree well with recently developed volcanic forcing records from high-resolution bipolar ice cores. In some cases, however, the climatic impact detected with our new method peaks in neighboring years, likely due to either dating errors in the polar ice cores or uncertainty in the interpretation of atmospheric aerosol transport to polar ice core locations. The most apparent mismatches between forcing and cooling estimates occur in the 1450s and 1690s. Application of the algorithm to two additional and recently developed reconstructions that blend maximum latewood density and ring width data reproduces twelve of the detected events among which eight are retrieved in all three of the dendroclimatic reconstructions. Collectively, the new estimates of volcanic activity with precise age control provide independent evidence for forcing records during the last millennium. Evaluating the cooling magnitude in response to detected events yields an upper benchmark for the volcanic impact on climate. The average response to the ten major events in the density derived reconstruction is −0.60 °C ± 0.13 °C. Other last millennium temperature records from proxies and model simulations reveal higher cooling estimates, which is, to some degree, related to the very different high frequency variance in these timeseries

    The surface science of quasicrystals

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    The surfaces of quasicrystals have been extensively studied since about 1990. In this paper we review work on the structure and morphology of clean surfaces, and their electronic and phonon structure. We also describe progress in adsorption and epitaxy studies. The paper is illustrated throughout with examples from the literature. We offer some reflections on the wider impact of this body of work and anticipate areas for future development. (Some figures in this article are in colour only in the electronic version

    Pseudomorphic Growth of a Single Element Quasiperiodic Ultrathin Film on a Quasicrystal Substrate

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    An ultrathin film with a periodic interlayer spacing was grown by the deposition of Cu atoms on thefivefold surface of the icosahedral Al70 Pd21 Mn9 quasicrystal. For coverages from 5 to 25 monolayers, a distinctive quasiperiodic low-energy electron diffraction pattern is observed. Scanning tunneling microscopy images show that the in-plane structure comprises rows having separations of S = 4.5 �0.2 �A and L = 7.3 0.3 A, whose ratio equals � =1.618... within experimental error. The sequences of such row separations form segments of terms of the Fibonacci sequence, indicative of the formation of a pseudomorphic Cu film

    Climate field reconstruction uncertainty arising from multivariate and nonlinear properties of predictors

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    Climate field reconstructions (CFRs) of the global annual surface air temperature (SAT) field and associated global area-weighted mean annual temperature (GMAT) are derived in a collection of pseudoproxy experiments for the past millennium. Pseudoproxies are modeled from temperature (T), precipitation (P), T + P, and VS-Lite (VSL), a nonlinear and multivariate proxy system model for tree ring widths. Spatial patterns of reconstruction skill and spectral bias for the T + P and VSL-derived CFRs are similar to those previously shown using temperature-only pseudoproxies but demonstrate overall degraded skill and spectral bias for SAT reconstruction. Analysis of GMAT spectra nevertheless suggests that the true GMAT frequency spectrum is resolved by those pseudoproxies (T, T + P, and VSL) that contain some temperature information. The results suggest that mixed temperature and moisture-responding paleoclimate data may produce actual GMAT reconstructions with skill, error, and spectral characteristics like those expected from univariate and linear temperature responders, but spatially resolved CFR results should be analyzed cautiousl

    Surface Geometry of C60 on Ag(111)

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    The geometry of adsorbed C60 influences its collective properties. We report the first dynamical low-energy electron diffraction study to determine the geometry of a C60 monolayer, Ag(111)-(23×23)30°-C60, and related density functional theory calculations. The stable monolayer has C60 molecules in vacancies that result from the displacement of surface atoms. C60 bonds with hexagons down, with their mirror planes parallel to that of the substrate. The results indicate that vacancy structures are the rule rather than the exception for C60 monolayers on close-packed metal surfaces. © 2009 The American Physical Society
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