164 research outputs found
Femtosecond pulses and dynamics of molecular photoexcitation: RbCs example
We investigate the dynamics of molecular photoexcitation by unchirped
femtosecond laser pulses using RbCs as a model system. This study is motivated
by a goal of optimizing a two-color scheme of transferring
vibrationally-excited ultracold molecules to their absolute ground state. In
this scheme the molecules are initially produced by photoassociation or
magnetoassociation in bound vibrational levels close to the first dissociation
threshold. We analyze here the first step of the two-color path as a function
of pulse intensity from the low-field to the high-field regime. We use two
different approaches, a global one, the 'Wavepacket' method, and a restricted
one, the 'Level by Level' method where the number of vibrational levels is
limited to a small subset. The comparison between the results of the two
approaches allows one to gain qualitative insights into the complex dynamics of
the high-field regime. In particular, we emphasize the non-trivial and
important role of far-from-resonance levels which are adiabatically excited
through 'vertical' transitions with a large Franck-Condon factor. We also point
out spectacular excitation blockade due to the presence of a quasi-degenerate
level in the lower electronic state. We conclude that selective transfer with
femtosecond pulses is possible in the low-field regime only. Finally, we extend
our single-pulse analysis and examine population transfer induced by coherent
trains of low-intensity femtosecond pulses.Comment: 25 pages, 12 figure
Extreme events in gross primary production: a characterization across continents
Climate extremes can affect the functioning of terrestrial ecosystems, for
instance via a reduction of the photosynthetic capacity or alterations of
respiratory processes. Yet the dominant regional and seasonal effects of
hydrometeorological extremes are still not well documented and in the focus
of this paper. Specifically, we quantify and characterize the role of large
spatiotemporal extreme events in gross primary production (GPP) as triggers
of continental anomalies. We also investigate seasonal dynamics of extreme
impacts on continental GPP anomalies. We find that the 50 largest positive
extremes (i.e., statistically unusual increases in carbon uptake rates) and
negative extremes (i.e., statistically unusual decreases in carbon uptake
rates) on each continent can explain most of the continental variation in
GPP, which is in line with previous results obtained at the global scale. We
show that negative extremes are larger than positive ones and demonstrate
that this asymmetry is particularly strong in South America and Europe. Our
analysis indicates that the overall impacts and the spatial extents of GPP
extremes are power-law distributed with exponents that vary little across
continents. Moreover, we show that on all continents and for all data sets
the spatial extents play a more important role for the overall impact of GPP
extremes compared to the durations or maximal GPP. An analysis of possible
causes across continents indicates that most negative extremes in GPP can be
attributed clearly to water scarcity, whereas extreme temperatures play a
secondary role. However, for Europe, South America and Oceania we also
identify fire as an important driver. Our findings are consistent with remote
sensing products. An independent validation against a literature survey on
specific extreme events supports our results to a large extent
Deciphering the components of regional net ecosystem fluxes following a bottom-up approach for the Iberian Peninsula
Quantification of ecosystem carbon pools is a fundamental requirement for estimating carbon fluxes and for addressing the dynamics and responses of the terrestrial carbon cycle to environmental drivers. The initial estimates of carbon pools in terrestrial carbon cycle models often rely on the ecosystem steady state assumption, leading to initial equilibrium conditions. In this study, we investigate how trends and inter-annual variability of net ecosystem fluxes are affected by initial non-steady state conditions. Further, we examine how modeled ecosystem responses induced exclusively by the model drivers can be separated from the initial conditions. For this, the Carnegie-Ames-Stanford Approach (CASA) model is optimized at set of European eddy covariance sites, which support the parameterization of regional simulations of ecosystem fluxes for the Iberian Peninsula, between 1982 and 2006. <br><br> The presented analysis stands on a credible model performance for a set of sites, that represent generally well the plant functional types and selected descriptors of climate and phenology present in the Iberian region – except for a limited Northwestern area. The effects of initial conditions on inter-annual variability and on trends, results mostly from the recovery of pools to equilibrium conditions; which control most of the inter-annual variability (IAV) and both the magnitude and sign of most of the trends. However, by removing the time series of pure model recovery from the time series of the overall fluxes, we are able to retrieve estimates of inter-annual variability and trends in net ecosystem fluxes that are quasi-independent from the initial conditions. This approach reduced the sensitivity of the net fluxes to initial conditions from 47% and 174% to −3% and 7%, for strong initial sink and source conditions, respectively. <br><br> With the aim to identify and improve understanding of the component fluxes that drive the observed trends, the net ecosystem production (NEP) trends are decomposed into net primary production (NPP) and heterotrophic respiration (<i>R</i><sub>H</sub>) trends. The majority (~97%) of the positive trends in NEP is observed in regions where both NPP and <i>R</i><sub>H</sub> fluxes show significant increases, although the magnitude of NPP trends is higher. Analogously, ~83% of the negative trends in NEP are also associated with negative trends in NPP. The spatial patterns of NPP trends are mainly explained by the trends in <i>f</i>APAR (<i>r</i>=0.79) and are only marginally explained by trends in temperature and water stress scalars (<i>r</i>=0.10 and <i>r</i>=0.25, respectively). Further, we observe the significant role of substrate availability (<i>r</i>=0.25) and temperature (<i>r</i>=0.23) in explaining the spatial patterns of trends in <i>R</i><sub>H</sub>. These results highlight the role of primary production in driving ecosystem fluxes. <br><br> Overall, our study illustrates an approach for removing the confounding effects of initial conditions and emphasizes the need to decompose the ecosystem fluxes into its components and drivers for more mechanistic interpretations of modeling results. We expect that our results are not only specific for the CASA model since it incorporates concepts of ecosystem functioning and modeling assumptions common to biogeochemical models. A direct implication of these results is the ability of this approach to detect climate and phenology induced trends regardless of the initial conditions
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The influence of soil communities on the temperature sensitivity of soil respiration
Soil respiration represents a major carbon flux between terrestrial ecosystems and the atmosphere, and is expected to accelerate under climate warming. Despite its importance in climate change forecasts, however, our understanding of the effects of temperature on soil respiration (RS) is incomplete. Using a metabolic ecology approach we link soil biota metabolism, community composition and heterotrophic activity, to predict RS rates across five biomes. We find that accounting for the ecological mechanisms underpinning decomposition processes predicts climatological RS variations observed in an independent dataset (n = 312). The importance of community composition is evident because without it RS is substantially underestimated. With increasing temperature, we predict a latitudinal increase in RS temperature sensitivity, with Q10 values ranging between 2.33 ±0.01 in tropical forests to 2.72 ±0.03 in tundra. This global trend has been widely observed, but has not previously been linked to soil communities
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Reclassifying historical disasters: From single to multi-hazards
Data availability:
Data will be made available on request.Multi-hazard events, characterized by the simultaneous, cascading, or cumulative occurrence of multiple natural hazards, pose a significant threat to human lives and assets. This is primarily due to the cumulative and cascading effects arising from the interplay of various natural hazards across space and time. However, their identification is challenging, which is attributable to the complex nature of natural hazard interactions and the limited availability of multi-hazard observations. This study presents an approach for identifying multi-hazard events during the past 123 years (1900–2023) using the EM-DAT global disaster database. Leveraging the ‘associated hazard’ information in EM-DAT, multi-hazard events are detected and assessed in relation to their frequency, impact on human lives and assets, and reporting trends. The interactions between various combinations of natural hazard pairs are explored, reclassifying them into four categories: preconditioned/triggering, multivariate, temporally compounding, and spatially compounding multi-hazard events. The results show, globally, approximately 19 % of the 16,535 disasters recorded in EM-DAT can be classified as multi-hazard events. However, the multi-hazard events recorded in EM-DAT are disproportionately responsible for nearly 59 % of the estimated global economic losses. Conversely, single hazard events resulted in higher fatalities compared to multi-hazard events. The largest proportion of multi-hazard events are associated with floods, storms, and earthquakes. Landslides emerge as the predominant secondary hazards within multi-hazard pairs, primarily triggered by floods, storms, and earthquakes, with the majority of multi-hazard events exhibiting preconditioned/triggering and multivariate characteristics. There is a higher prevalence of multi-hazard events in Asia and North America, whilst temporal overlaps of multiple hazards predominate in Europe. These results can be used to increase the integration of multi-hazard thinking in risk assessments, emergency management response plans and mitigation policies at both national and international levels.The authors acknowledge the European COST Action DAMOCLES (CA17109). CJW, MSGA, JD, MJR and ET were supported by the European Union's Horizon Europe ‘Multi-hazard and risk informed system for Enhanced local and regional Disaster risk management (MEDiate)’ project under grant agreement no. 10049641. CJW also acknowledges support from the NERC Global Partnerships Seedcorn Fund ‘EMERGE’ project though grant no. NE/W003775/1. PJW received support from the MYRIAD-EU project, which received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 101003276. MDM and JZ received support from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 101003469 (XAIDA). AMR was supported by the Helmholtz ‘Changing Earth’ program and acknowledges the Portuguese Science Foundation (FCT) through the project AMOTHEC (DRI/India/0098/2020)
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Reclassifying historical disasters: from single to multi-hazards
EGU General Assembly 2024, Session NH10.1.Multi-hazard events, characterized by the simultaneous, cascading, or cumulative occurrence of multiple natural hazards, pose a significant threat to human lives and assets. This is primarily due to the cumulative and cascading effects arising from the interplay of various natural hazards across space and time. However, their identification is challenging, which is attributable to the complex nature of natural hazard interactions and the limited availability of multi-hazard observations. This presentation, focused on a recently published article in Science of the Total Environment (https://doi.org/10.1016/j.scitotenv.2023.169120), presents an approach for identifying multi-hazard events during the past 123 years (1900-2023) using the EM-DAT global disaster database. Leveraging the ‘associated hazard’ information in EM-DAT, multi-hazard events are detected and assessed in relation to their frequency, impact on human lives and assets, and reporting trends. The interactions between various combinations of natural hazard pairs are explored, reclassifying them into four categories: preconditioned/triggering, multivariate, temporally compounding, and spatially compounding multi-hazard events. The results show, globally, approximately 19% of the 16,535 disasters recorded in EM-DAT can be classified as multi-hazard events. However, the multi-hazard events recorded in EM-DAT are disproportionately responsible for nearly 59% of the estimated global economic losses. Conversely, single hazard events resulted in higher fatalities compared to multi-hazard events. The largest proportion of multi-hazard events are associated with floods, storms, and earthquakes. Landslides emerge as the predominant secondary hazards within multi-hazard pairs, primarily triggered by floods, storms, and earthquakes, with the majority of multi-hazard events exhibiting preconditioned/triggering and multivariate characteristics. There is a higher prevalence of multi-hazard events in Asia and North America, whilst temporal overlaps of multiple hazards predominate in Europe. These results can be used to increase the integration of multi-hazard thinking in risk assessments, emergency management response plans and mitigation policies at both national and international levels
Contamination level and spatial distribution of heavy metals in water and sediments of El Guájaro Reservoir, Colombia
Heavy metals have become a subject of special concern worldwide, mainly due to high persistence in the environment, toxicity, biogeochemical recycling and ecological risk. Therefore, the objective of this investigation was to analyze the spatial–temporal distribution of heavy metals in water and sediments to determine the environmental status of El Guájaro Reservoir, where such studies have not been developed. Two measurement campaigns (dry and wet period) were carried out and eight sampling stations were selected. A comparison of water and sediment quality parameters with existing national and international regulations was done. Also, heavy metal distribution maps were generated, and the geoaccumulation index was calculated to identify sources and sediments contamination level. Based on the obtained results, agriculture and mining activities are the main causes of the reservoir contamination. This metals levels could be a potential risk for the aquatic life and the populations that are supplied from this water body
Designing an outdoor learning environment for and with a primary school community:A case study in Bangladesh
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