267 research outputs found
Morphologies of three-dimensional shear bands in granular media
We present numerical results on spontaneous symmetry breaking strain
localization in axisymmetric triaxial shear tests of granular materials. We
simulated shear band formation using three-dimensional Distinct Element Method
with spherical particles. We demonstrate that the local shear intensity, the
angular velocity of the grains, the coordination number, and the local void
ratio are correlated and any of them can be used to identify shear bands,
however the latter two are less sensitive. The calculated shear band
morphologies are in good agreement with those found experimentally. We show
that boundary conditions play an important role. We discuss the formation
mechanism of shear bands in the light of our observations and compare the
results with experiments. At large strains, with enforced symmetry, we found
strain hardening.Comment: 6 pages 5 figures, low resolution figures
Effects of photon reabsorption phenomena in confocal micro-photoluminescence measurements in crystalline silicon
Confocal micro-photoluminescence (PL) spectroscopy has become a powerful characterization technique for studying novel photovoltaic (PV) materials and structures at the micrometer level. In this work, we present a comprehensive study about the effects and implications of photon reabsorption phenomena on confocal micro-PL measurements in crystalline silicon (c-Si), the workhorse material of the PV industry. First, supported by theoretical calculations, we show that the level of reabsorption is intrinsically linked to the selected experimental parameters, i.e., focusing lens, pinhole aperture, and excitation wavelength, as they define the spatial extension of the confocal detection volume, and therefore, the effective photon traveling distance before collection. Second, we also show that certain sample properties such as the reflectance and/or the surface recombination velocity can also have a relevant impact on reabsorption. Due to the direct relationship between the reabsorption level and the spectral line shape of the resulting PL emission signal, reabsorption phenomena play a paramount role in certain types of micro-PL measurements. This is demonstrated by means of two practical and current examples studied using confocal PL, namely, the estimation of doping densities in c-Si and the study of back-surface and/or back-contacted Si devices such as interdigitated back contact solar cells, where reabsorption processes should be taken into account for the proper interpretation and quantification of the obtained PL data.Peer ReviewedPostprint (published version
Critical packing in granular shear bands
In a realistic three-dimensional setup, we simulate the slow deformation of
idealized granular media composed of spheres undergoing an axisymmetric
triaxial shear test. We follow the self-organization of the spontaneous strain
localization process leading to a shear band and demonstrate the existence of a
critical packing density inside this failure zone. The asymptotic criticality
arising from the dynamic equilibrium of dilation and compaction is found to be
restricted to the shear band, while the density outside of it keeps the memory
of the initial packing. The critical density of the shear band depends on
friction (and grain geometry) and in the limit of infinite friction it defines
a specific packing state, namely the \emph{dynamic random loose packing}
Contact dynamics in a gently vibrated granular pile
We use multi-speckle diffusive wave spectroscopy (MSDWS) to probe the
micron-scale dynamics of a granular pile submitted to discrete gentle taps. The
typical time-scale between plastic events is found to increase dramatically
with the number of applied taps. Furthermore, this microscopic dynamics weakly
depends on the solid fraction of the sample. This process is strongly analogous
to the aging phenomenon observed in thermal glassy systems. We propose a
heuristic model where this slowing down mechanism is associated with a slow
evolution of the distribution of the contact forces between particles. This
model accounts for the main features of the observed dynamics.Comment: 4 pages, 4 figure
Anomalous acoustic reflection on a sliding interface or a shear band
We study the reflection of an acoustic plane wave from a steadily sliding
planar interface with velocity strengthening friction or a shear band in a
confined granular medium. The corresponding acoustic impedance is utterly
different from that of the static interface. In particular, the system being
open, the energy of an in-plane polarized wave is no longer conserved, the work
of the external pulling force being partitioned between frictional dissipation
and gain (of either sign) of coherent acoustic energy. Large values of the
friction coefficient favor energy gain, while velocity strengthening tends to
suppress it. An interface with infinite elastic contrast (one rigid medium) and
V-independent (Coulomb) friction exhibits spontaneous acoustic emission, as
already shown by M. Nosonovsky and G.G. Adams (Int. J. Ing. Sci., {\bf 39},
1257 (2001)). But this pathology is cured by any finite elastic contrast, or by
a moderately large V-strengthening of friction.
We show that (i) positive gain should be observable for rough-on-flat
multicontact interfaces (ii) a sliding shear band in a granular medium should
give rise to sizeable reflection, which opens a promising possibility for the
detection of shear localization.Comment: 13 pages, 10 figure
Plastic Flow in Two-Dimensional Solids
A time-dependent Ginzburg-Landau model of plastic deformation in
two-dimensional solids is presented. The fundamental dynamic variables are the
displacement field \bi u and the lattice velocity {\bi v}=\p {\bi u}/\p t.
Damping is assumed to arise from the shear viscosity in the momentum equation.
The elastic energy density is a periodic function of the shear and tetragonal
strains, which enables formation of slips at large strains. In this work we
neglect defects such as vacancies, interstitials, or grain boundaries. The
simplest slip consists of two edge dislocations with opposite Burgers vectors.
The formation energy of a slip is minimized if its orientation is parallel or
perpendicular to the flow in simple shear deformation and if it makes angles of
with respect to the stretched direction in uniaxial stretching.
High-density dislocations produced in plastic flow do not disappear even if
the flow is stopped. Thus large applied strains give rise to metastable,
structurally disordered states. We divide the elastic energy into an elastic
part due to affine deformation and a defect part. The latter represents degree
of disorder and is nearly constant in plastic flow under cyclic straining.Comment: 16pages, Figures can be obtained at
http://stat.scphys.kyoto-u.ac.jp/index-e.htm
Sheared Solid Materials
We present a time-dependent Ginzburg-Landau model of nonlinear elasticity in
solid materials. We assume that the elastic energy density is a periodic
function of the shear and tetragonal strains owing to the underlying lattice
structure. With this new ingredient, solving the equations yields formation of
dislocation dipoles or slips. In plastic flow high-density dislocations emerge
at large strains to accumulate and grow into shear bands where the strains are
localized. In addition to the elastic displacement, we also introduce the local
free volume {\it m}. For very small the defect structures are metastable
and long-lived where the dislocations are pinned by the Peierls potential
barrier. However, if the shear modulus decreases with increasing {\it m},
accumulation of {\it m} around dislocation cores eventually breaks the Peierls
potential leading to slow relaxations in the stress and the free energy
(aging). As another application of our scheme, we also study dislocation
formation in two-phase alloys (coherency loss) under shear strains, where
dislocations glide preferentially in the softer regions and are trapped at the
interfaces.Comment: 16pages, 11figure
Quantification of Optical Clarity of Transparent Soil Using the Modulation Transfer Function
Transparent synthetic soils have been developed as a soil surrogate to enable internal visualization of geotechnical processes in physical models. Transparency of the soil dictates the overarching success of the technique; however, despite this fundamental requirement, no quantitative framework has yet been established to appraise the visual quality of transparent soil. Previous approaches to assess and optimize transparency quality included an eye chart assessment method, although this approach is highly subjective and operator-dependent. In this paper, an independent method for quantitatively assessing the optical quality of transparent soil is proposed based on the optical calibration method, Modulation Transfer Function (MTF). The work explores this hypothesis and assesses the potential for MTF to quantify the optical quality of transparent soils for a number of aspects including (i) optimum oil blend ratio, (ii) depth of viewing plane, and (iii) temperature. The results confirmed that MTF offers a robust and reliable method to provide an independent quantitative measure of the optical quality of transparent soil. The impact of reduced soil transparency and the ability to track speckle patternsâthus accuracy and precision of displacement measurementâwas correlated with MTF to evaluate the permissible viewing depth of transparent soil
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Identification of structural features of condensed tannins that affect protein aggregation
A diverse panel of condensed tannins was used to resolve the confounding effects of size and subunit composition seen previously in tannin-protein interactions. Turbidimetry revealed that size in terms of mean degree of polymerisation (mDP) or average molecular weight (amw) was the most important tannin parameter. The smallest tannin with the relatively largest effect on protein aggregation had an mDP of ~7. The average size was significantly correlated with aggregation of bovine serum albumin, BSA (mDP: r=-0.916; amw: r=-0.925; p<0.01; df=27), and gelatin (mDP: r=-0.961; amw: r=-0.981; p<0.01; df=12). The procyanidin/prodelphinidin and cis-/trans-flavan-3-ol ratios gave no significant correlations. Tryptophan fluorescence quenching indicated that procyanidins and cis-flavan-3-ol units contributed most to the tannin interactions on the BSA surface and in the hydrophobic binding pocket (r=0.677; p<0.05; df=9 and r=0.887; p<0.01; df=9, respectively). Circular dichroism revealed that higher proportions of prodelphinidins decreased the apparent α-helix content (r=-0.941; p<0.01; df=5) and increased the apparent ÎČ-sheet content (r=0.916; p<0.05; df=5) of BSA
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Assessment of the anthelmintic activity of medicinal plant extracts and purified condensed tannins against free-living and parasitic stages of Oesophagostomum dentatum
Background: Plant-derived condensed tannins (CT) show promise as a complementary option to treat gastrointestinal helminth infections, thus reducing reliance on synthetic anthelmintic drugs. Most studies on the anthelmintic effects of CT have been conducted on parasites of ruminant livestock. Oesophagostomum dentatum is an economically important parasite of pigs, as well as serving as a useful laboratory model of helminth parasites due to the ability to culture it in vitro for long periods through several life-cycle stages. Here, we investigated the anthelmintic effects of CT on multiple life-cycles stages of O. dentatum.
Methods: Extracts and purified fractions were prepared from five plants containing CT and analysed by HPLC-MS. Anthelmintic activity was assessed at five different stages of the O. dentatum life cycle; the development of eggs to infective third-stage larvae (L3), the parasitic L3 stage, the moult from L3 to fourth-stage larvae (L4), the L4 stage and the adult stage.
Results: Free-living larvae of O. dentatum were highly susceptible to all five plant extracts. In contrast, only two of the five extracts had activity against L3, as evidenced by migration inhibition assays, whilst three of the five extracts inhibited the moulting of L3 to L4. All five extracts reduced the motility of L4, and the motility of adult worms exposed to a CT-rich extract derived from hazelnut skins was strongly inhibited, with electron microscopy demonstrating direct damage to the worm cuticle and hypodermis. Purified CT fractions retained anthelmintic activity, and depletion of CT from extracts by pre-incubation in polyvinylpolypyrrolidone removed anthelmintic effects, strongly suggesting CT as the active molecules.
Conclusions: These results suggest that CT may have promise as an alternative parasite control option for O. dentatum in pigs, particularly against adult stages. Moreover, our results demonstrate a varied susceptibility of different life-cycle stages of the same parasite to CT, which may offer an insight into the anthelmintic mechanisms of these commonly found plant compounds
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