136 research outputs found
Photoemission studies of GaMnAs: Mn-concentration dependent properties
Using angle-resolved photoemission, we have investigated the development of
the electronic structure and the Fermi level pinnning in GaMnAs
with Mn concentrations in the range 1--6%. We find that the Mn-induced changes
in the valence-band spectra depend strongly on the Mn concentration, suggesting
that the interaction between the Mn ions is more complex than assumed in
earlier studies. The relative position of the Fermi level is also found to be
concentration-dependent. In particular we find that for concentrations around
3.5--5% it is located very close to the valence-band maximum, which is in the
range where metallic conductivity has been reported in earlier studies. For
concentration outside this range, larger as well as smaller, the Fermi level is
found to be pinned at about 0.15 eV higher energy.Comment: REVTeX style; 7 pages, 3 figure
Nano-probing station incorporating MEMS probes for 1D device RF on-wafer characterization
International audienc
Exploring the relevance and feasibility of PES approaches for producing environmental services through changes in agricultural practices:a case study in the Mekong Region: Vietnam case.
Correlation Effects in Wave Function Mapping of Molecular Beam Epitaxy Grown Quantum Dots
Atomic Scale Modelling of Two-Dimensional Molecular Self-Assembly on a Passivated Si Surface
International audienceThe self-assembly of two-dimensional (2D) molecular structures on a solid surface relies on the subtle balance between non covalent intermolecular and molecule-surface forces. The energetics of 2D molecular lattices forming different patterns on a passivated semiconductor surface are here investigated by a combination of atomistic simulation methods. Density-functional theory provides structure and charges of the molecules, while metadynamics with empirical forces provides a best guess for the lowest-energy adsorption sites of single molecules and dimers. Subsequently, molecular dynamics simulations of extended molecular assemblies with empirical forces yield the most favorable lattice structures at finite temperature and pressure.The theoretical results are in good agreement with scanning tunneling microscopy observations of self-assembled molecular monolayers on a B-doped Si(111) surface, thus allowing to rationalize the competition of long-range dispersion forces between the molecules and the surface. Such a result demonstrates the interest of this predictive approach for further progress in supramolecular chemistry on semiconductor surface
Atomic scale investigation of silicon nanowires and nanoclusters
In this study, we have performed nanoscale characterization of Si-clusters and Si-nanowires with a laser-assisted tomographic atom probe. Intrinsic and p-type silicon nanowires (SiNWs) are elaborated by chemical vapor deposition method using gold as catalyst, silane as silicon precursor, and diborane as dopant reactant. The concentration and distribution of impurity (gold) and dopant (boron) in SiNW are investigated and discussed. Silicon nanoclusters are produced by thermal annealing of silicon-rich silicon oxide and silica multilayers. In this process, atom probe tomography (APT) provides accurate information on the silicon nanoparticles and the chemistry of the nanolayers
Antiretroviral-naive and -treated HIV-1 patients can harbour more resistant viruses in CSF than in plasma
Objectives The neurological disorders in HIV-1-infected patients remain prevalent. The HIV-1 resistance in plasma and CSF was compared in patients with neurological disorders in a multicentre study. Methods Blood and CSF samples were collected at time of neurological disorders for 244 patients. The viral loads were >50 copies/mL in both compartments and bulk genotypic tests were realized. Results On 244 patients, 89 and 155 were antiretroviral (ARV) naive and ARV treated, respectively. In ARV-naive patients, detection of mutations in CSF and not in plasma were reported for the reverse transcriptase (RT) gene in 2/89 patients (2.2%) and for the protease gene in 1/89 patients (1.1%). In ARV-treated patients, 19/152 (12.5%) patients had HIV-1 mutations only in the CSF for the RT gene and 30/151 (19.8%) for the protease gene. Two mutations appeared statistically more prevalent in the CSF than in plasma: M41L (P = 0.0455) and T215Y (P = 0.0455). Conclusions In most cases, resistance mutations were present and similar in both studied compartments. However, in 3.4% of ARV-naive and 8.8% of ARV-treated patients, the virus was more resistant in CSF than in plasma. These results support the need for genotypic resistance testing when lumbar puncture is performe
Phase transformation of PbSe/CdSe nanocrystals from core-shell to Janus structure studied by photoemission spectroscopy
Imaging and spectroscopy of artificial-atom states in core/shell nanocrystal quantum dots
Current imaging scanning tunneling microscopy is used to observe the
electronic wavefunctions in InAs/ZnSe core/shell nanocrystals. Images taken at
a bias corresponding to the s conduction band state show that it is localized
in the central core region, while images at higher bias probing the p state
reveal that it extends to the shell. This is supported by optical and tunneling
spectroscopy data demonstrating that the s-p gap closes upon shell growth.
Shapes of the current images resemble atom-like envelope wavefunctions of the
quantum dot calculated within a particle in a box model.Comment: to be published in Physical Review Letter
Analysis of Styrene Polymerization Without Surfactant and N2 Gas in Cylindrical Flask.
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