8,802 research outputs found
Study of nickel hydroxide electrodes. 2: Oxidation products of nickel (2) hydroxides
Pure phases of some oxidized Ni oxides were prepared galvanimetrically with the Ni(2) hydroxide electrode of an alkaline battery. The crystallographic data of these phases, their chemical behavior, and conditions of transition were studied
Reflection, refraction, and rejection : copper smelting heritage and the execution of environmental policy
This dissertation examines the global technological and environmental history of copper smelting and the conflict that developed between historic preservation and environmental remediation at major copper smelting sites in the United States after their productive periods ended. Part I of the dissertation is a synthetic overview of the history of copper smelting and its environmental impact. After reviewing the basic metallurgy of copper ores, the dissertation contains successive chapters on the history of copper smelting to 1640, culminating in the so-called German, or Continental, processing system; on the emergence of the rival Welsh system during the British industrial revolution; and on the growth of American dominance in copper production the late 19th and early 20th centuries. The latter chapter focuses, in particular, on three of the most important early American copper districts: Michigan’s Keweenaw Peninsula, Tennessee’s Copper Basin, and Butte-Anaconda, Montana. As these three districts went into decline and ultimately out of production, they left a rich industrial heritage and significant waste and pollution problems generated by increasingly more sophisticated technologies capable of commercially processing steadily growing volumes of decreasingly rich ores.
Part II of the dissertation looks at the conflict between historic preservation and environmental remediation that emerged locally and nationally in copper districts as they went into decline and eventually ceased production. Locally, former copper mining communities often split between those who wished to commemorate a region’s past importance and develop heritage tourism, and local developers who wished to clear up and clean out old industrial sites for other purposes. Nationally, Congress passed laws in the 1960s and 1970s mandating the preservation of historical resources (National Historic Preservation Act) and laws mandating the cleanup of contaminated landscapes (CERCLA, or Superfund), objectives sometimes in conflict – especially in the case of copper smelting sites. The dissertation devotes individual chapters to the conflicts that developed between environmental remediation, particularly involving the Environmental Protection Agency and the heritage movement in the Tennessee, Montana, and Michigan copper districts. A concluding chapter provides a broad model to illustrate the relationship between industrial decline, federal environmental remediation activities, and the growth of heritage consciousness in former copper mining and smelting areas, analyzes why the outcome varied in the three areas, and suggests methods for dealing with heritage-remediation issues to minimize conflict and maximize heritage preservation
The Morphology of the Expanding Ejecta of V2491 Cygni (2008 N.2)
Determining the evolution of the ejecta morphology of novae provides valuable
information on the shaping mechanisms in operation at early stages of the nova
outburst. Understanding such mechanisms has implications for studies of shaping
for example in proto-Planetary Nebulae. Here we perform morpho-kinematical
studies of V2491 Cyg using spectral data to determine the likely structure of
the ejecta and its relationship to the central system and shaping mechanisms.
We use Shape to model different morphologies and retrieve their spectra. These
synthetic spectra are compared with observed spectra to determine the most
likely morphology giving rise to them, including system inclination and
expansion velocity of the nova ejecta. We find the best fit remnant morphology
to be that of polar blobs and an equatorial ring with an implied inclination of
80 degrees and an maximum expansion velocity of the polar blobs of
3100 km/s and for the equatorial ring 2700
km/s. This inclination would suggest that we should observe eclipses which will
enable us to determine more precisely important parameters of the central
binary. We also note that the amplitude of the outburst is more akin to the
found in recurrent nova systems.Comment: 9 pages, 7 figures, accepted for publication in MNRA
The expression of stlA in Photorhabdus luminescens is controlled by nutrient limitation
Photorhabdus is a genus of Gram-negative entomopathogenic bacteria that also maintain a mutualistic association with nematodes from the family Heterorhabditis. Photorhabdus has an extensive secondary metabolism that is required for the interaction between the bacteria and the nematode. A major component of this secondary metabolism is a stilbene molecule, called ST. The first step in ST biosynthesis is the non-oxidative deamination of phenylalanine resulting in the production of cinnamic acid. This reaction is catalyzed by phenylalanine-ammonium lyase, an enzyme encoded by the stlA gene. In this study we show, using a stlA-gfp transcriptional fusion, that the expression of stlA is regulated by nutrient limitation through a regulatory network that involves at least 3 regulators. We show that TyrR, a LysR-type transcriptional regulator that regulates gene expression in response to aromatic amino acids in E. coli, is absolutely required for stlA expression. We also show that stlA expression is modulated by σS and Lrp, regulators that are implicated in the regulation of the response to nutrient limitation in other bacteria. This work is the first that describes pathway-specific regulation of secondary metabolism in Photorhabdus and, therefore, our study provides an initial insight into the complex regulatory network that controls secondary metabolism, and therefore mutualism, in this model organism
Chandra detection of extended X-ray emission from the recurrent nova RS Ophiuchi
Radio, infrared, and optical observations of the 2006 eruption of the
symbiotic recurrent nova RS Ophiuchi (RS Oph) showed that the explosion
produced non-spherical ejecta. Some of this ejected material was in the form of
bipolar jets to the east and west of the central source. Here we describe Xray
observations taken with the Chandra X-ray Observatory one and a half years
after the beginning of the outburst that reveal narrow, extended structure with
a position angle of approximately 300 degrees (east of north). Although the
orientation of the extended feature in the X-ray image is consistent with the
readout direction of the CCD detector, extensive testing suggests that the
feature is not an artifact. Assuming it is not an instrumental effect, the
extended X-ray structure shows hot plasma stretching more than 1,900 AU from
the central binary (taking a distance of 1.6 kpc). The X-ray emission is
elongated in the northwest direction - in line with the extended infrared
emission and some minor features in the published radio image. It is less
consistent with the orientation of the radio jets and the main bipolar optical
structure. Most of the photons in the extended X-ray structure have energies of
less than 0.8 keV. If the extended X-ray feature was produced when the nova
explosion occurred, then its 1".2 length as of 2007 August implies that it
expanded at an average rate of more than 2 mas/d, which corresponds to a flow
speed of greater than 6,000 km/s (d/1.6 kpc) in the plane of the sky. This
expansion rate is similar to the earliest measured expansion rates for the
radio jets.Comment: accepted in Ap
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