New insights into the outflows from R Aquarii

R Aquarii is a symbiotic binary surrounded by a large and complex nebula with a prominent curved jet. It is one of the closest known symbiotic systems, and therefore offers a unique opportunity to study the central regions of these systems and the formation and evolution of astrophysical jets. We studied the evolution of the central jet and outer nebula of R Aqr taking advantage of a long term monitoring campaign of optical imaging, as well as of high-resolution integral field spectroscopy. Narrow-band images acquired over a period of more than 21 years are compared in order to study the expansion and evolution of all components of the R Aqr nebula. The magnification method is used to derive the kinematic ages of the features that appear to expand radially. Integral field spectroscopy of the OIII 5007A emission is used to study the velocity structure of the central regions of the jet. New extended features, further out than the previously known hourglass nebula, are detected. The kinematic distance to R Aqr is calculated to be 178 pc using the expansion of the large hourglass nebula. This nebula of R Aqr is found to be roughly 650 years old, while the inner regions have ages ranging from 125 to 290 years. The outer nebula is found to be well described by a ballistic expansion, while for most components of the jet strong deviations from such behaviour are found. We find that the Northern jet is mostly red-shifted while its Southern part is blue-shifted, apparently at odds with findings from previous studies but almost certainly a consequence of the complex nature of the jet and variations in ionisation and illumination between observations.Comment: 13 pages, 8 figures, accepted for publication in A&

Reconstruction of Vertebral Bone Defects using an Expandable Replacement Device and Bioactive Glass S53P4 in the Treatment of Vertebral Osteomyelitis: Three Patients and Three Pathogens

Peer reviewe

Counteranion-controlled properties of polyelectrolyte multilayers

Polyelectrolyte multilayers consisting of poly(diallyldimethylammonium chloride) (PDADMA) and poly(sodium 4-styrenesulfonate) (PSS) were studied on a quartz crystal microbalance (QCM) utilizing a novel method to determine the elastic properties of the films. Since the multilayer was found to consist of a hard core and soft outer layer, as can be realized on the basis of the multilayer zone model, the multilayer films were made thick enough to reveal the elastic properties of the bulk material of the film. Several hundreds of layers were deposited using a fully automated multilayer deposition machine. We found out that, in addition to the increase in the bilayer mass, a remarkable increase of stiffness of the polyelectrolyte multilayer was observed while changing the counteranion used in the deposition process. The increase of stiffness was found to be comparable to the glass transition of common polymers. The increase is attributed to the counteranions that take part in polyelectrolyte charge compensation. The correlation of storage shear modulus and mass density to the hydration entropy of the anion could be clearly observed

Preparing for winter : the transcriptomic response associated with different day lengths in Drosophila montana

The work has been supported by a Natural Environment Research Council studentship to D.J.P. and an Academy of Finland grant to M.K. (project 268214).At northern latitudes, the most robust cue for assessing the onset of winter is the shortening of day lengths. Many species use day length as a cue to increase their cold tolerance and/or enter into diapause, but little is known about changes in gene expression that occur under different day lengths. We investigate the gene expression changes associated with differences in light/dark cycles in Drosophila montana, a northerly distributed species with a strong adult photoperiodic reproductive diapause. To examine gene expression changes induced by light both prior to and during diapause, we used both nondiapausing and diapausing flies. We found that the majority of genes that are differentially expressed between different day lengths in nondiapausing and diapausing flies differ. However, the biological processes involved were broadly similar. These included neuron development and metabolism, which are largely consistent with an increase in cold tolerance previously observed to occur in these flies. We also found that many genes associated with reproduction change in expression level between different day lengths, suggesting that D. montana use changes in day length to cue changes in reproduction both before and after entering into diapause. Finally, we also identified several interesting candidate genes for light-induced changes including Lsp2, para, and Ih.Publisher PDFPeer reviewe

Phosphonic acid derivatized polythiophene: A building block for metal phosphonate and polyelectrolyte multilayers

A water-soluble polythiophene with pendant phosphonic acid groups, poly(3-(3'-thienyloxy)propane-phosphonate) (P3TOPP), has been synthesized. Matrix-assisted laser desorption ionization (MALDI) measurements showed that P3TOPP is an oligomer with an average chain length of 10 monomer units. In aqueous solutions it could be electrochemically oxidized and displayed self-acid doping at pH below 13. P3TOPP was used to prepare polyelectrolyte multilayers with poly(diallyldimethylammonium chloride) (PDADMA) and metal phosphonate multilayers with Zr4+ ions by the sequential layer-by-layer technique. The films were characterized by electrochemistry, atomic force microscopy (AFM), UV-vis, IR, and X-ray photoelectron (XPS) spectroscopy. A regular layer-by-layer growth was observed with both types of multilayers. The nature of the films was probed with XPS, which showed that the observed binding energies were characteristic for metal phosphonates and polyelectrolyte multilayers in Zr/P3TOPP and P3T0PP/PDADMA films, respectively. In the former, the Zr:P ratio showed deviation from the theoretical stoichiometry, and the reasons for the nonstoichiometry are discussed. In the latter, the N:P ratio was consistent with the partial deprotonation of the phosphonate groups. The multilayers exhibited both electrochromism and pH-induced halochromism

Super star clusters and Supernovae in interacting LIRGs unmasked by NIR adaptive optics

We report on an on-going near-IR adaptive optics survey targeting interacting luminous IR galaxies. High-spatial resolution NIR data are crucial to enable interpretation of kinematic, dynamical and star formation (SF) properties of these very dusty objects. Whole progenitor nuclei in the interactions can be missed if only optical HST imaging is used. Here we specifically present the latest results regarding core-collapse supernovae found within the highly extincted nuclear regions of these galaxies. Direct detection and study of such highly obscured CCSNe is crucial for revising the optically-derived SN rates used for providing an independent measurement of the SF history of the Universe. We also present thus-far the first NIR luminosity functions of super star cluster (SSC) candidates. The LFs can then be used to constrain the formation and evolution of SSCs via constraints based on initial mass functions and cluster disruption models.Comment: 6 pages. To appear in proceedings of 'Galaxies and their Masks' (Namibia, April 2010), published by Springer, New York, eds. D.L. Block, K.C. Freeman, I. Puerar

e-MERLIN and VLBI observations of the luminous infrared galaxy IC883: a nuclear starburst and an AGN candidate revealed

The high star formation rates of luminous infrared galaxies (LIRGs) make them ideal places for core-collapse supernova (CCSN) searches. At radio frequencies, free from dust extinction, it is possible to detect compact components within the innermost LIRG nuclear regions, such as SNe and SN remnants, as well as AGN buried deep in the LIRG nuclei. We studied the LIRG IC883 aiming at: (i) investigating its (circum-)nuclear regions using the e-EVN at 5GHz, and e-MERLIN at 6.9GHz, complemented by archival VLBI data; (ii) detecting at radio frequencies the two recently reported circumnuclear SNe 2010cu and 2011hi, which were discovered by near-IR (NIR) adaptive optics observations of IC883; and (iii) further investigating the nature of SN2011hi at NIR by means of observations with Gemini-North. The circumnuclear regions traced by e-MERLIN at 6.9GHz have an extension of ~1kpc, and show a striking double-sided structure, which very likely corresponds to a warped rotating ring, in agreement with previous studies. Our e-EVN observations at 5GHz and complementary archival VLBI data at 5GHz and 8.4GHz, reveal the presence of various milliarcsec compact components in the nucleus of IC883. A single compact source, an AGN candidate, dominates the emission at both nuclear and circumnuclear scales, as imaged with the e-EVN and e-MERLIN, respectively. The other milliarcsec components are very suggestive of ongoing nuclear CCSN activity. Our e-EVN observations also resulted in upper limits to the radio luminosity of the two SNe in IC883 recently discovered at NIR. We refine the classification of SN2011hi as a Type IIP SN according to our latest Gemini-North epoch from 2012, in agreement with a low-luminosity radio SN nature. We estimate a CCSN rate lower limit of 1.1_{-0.6}^{+1.3} yr^{-1} for the entire galaxy, based on three nuclear radio SNe and the circumnuclear SNe 2010cu and 2011hi. (abridged)Comment: 9 pages, 5 figures and 2 tables. Accepted for publication in A&

Chemisorption of alkyl thiols and S-alkyl thiosulfates on Pt(111) and polycrystalline platinum surfaces

The self-assembled monolayers prepared from 1-dodecanethiol (C12SH) or S-dodecylthio sulfate (Bunte salt, C12SSO3Na) have been characterised on polycrystalline gold and platinum surfaces and on Pt(111). Contact angle and impedance measurements show that the film quality decreases in the order Au/C12SH > Pt/C12SH similar to Au/C12SSO3-Na > Pt/C12S SO3Na. XPS measurements show that the S-SO3 bond of organic thiosulfates is broken on platinum surfaces and the state of the surface-bound sulfur is indistinguishable from that of thiolate. On platinum three sulfur species are formed upon SAM formation and we suggest that the catalytic activity of platinum is responsible for their existence in pristine monolayers. (c) 2005 Elsevier B.V. All rights reserved

Radio monitoring of NGC 7469: Late time radio evolution of SN 2000ft and the circumnuclear starburst in NGC 7469

We present the results of an eight-year long monitoring of the radio emission from the Luminous Infrared Galaxy (LIRG) NGC 7469, using 8.4 GHz Very Large Array (VLA) observations at 0.3'' resolution. Our monitoring shows that the late time evolution of the radio supernova SN 2000ft follows a decline very similar to that displayed at earlier times of its optically thin phase. The late time radio emission of SN 2000ft is therefore still being powered by its interaction with the presupernova stellar wind, and not with the interstellar medium (ISM). Indeed, the ram pressure of the presupernova wind is \rho_w v_w^2 \approx 7.6E-9 dyn/cm^2, at a supernova age of approximately 2127 days, which is significantly larger than the expected pressure of the ISM around SN 2000ft. At this age, the SN shock has reached a distance r_{sh \approx 0.06 pc, and our observations are probing the interaction of the SN with dense material that was ejected by the presupernova star about 5820 years prior to its explosion. From our VLA monitoring, we estimate that the swept-up mass by the supernova shock after about six years of expansion is \approx 0.29 M_sun, assuming an average expansion speed of the supernova of 10000 km/s. We also searched for recently exploded core-collapse supernovae in our VLA images. Apart from SN 2000ft (S_\nu \approx 1760 microJy at its peak, corresponding to 1.1E28 erg/s/Hz, we found no evidence for any other radio supernova (RSN) more luminous than \approx 6.0E26 erg/s/Hz, which suggests that no other Type IIn SN has exploded since 2000 in the circumnuclear starburst of NGC 7469.Comment: 10 pages, 5 figures, accepted for publication in MNRA