Compressive strength, microstructure and hydration products of hybrid alkaline cements

Ordinary Portland cement (OPC) is the dominant binder in the construction industry with a global production that currently reaches a total of 3 Gt per year. As a consequence, the cement industry’s contribution to the total worldwide CO2 emissions is of about 7% of the total emissions. Publications on the field of alkali-activated binders (also termed geopolymers), state that this new material is, potentially, likely to become an alternative to Portland cement. However, recent LCA studies show that the environmental performance of alkali-activated binders depends, to great extent, of their composition. Also, researchers report that these binders can be produced in a more eco-efficient manner if the use of sodium silicate is avoided. This is due to the fact that the referred component is associated to a high carbon footprint. Besides, most alkali-activated cements suffer from severe efflorescence, a reaction originated by the fact that the alkaline and/or soluble silicates that are added during processing cannot be totally consumed. This paper presents experimental results on hybrid alkaline cements. The compressive strength results and the efflorescence observations show that some of the new mixes already exhibit a promising performance

The Evolution of the Intracluster Medium Metallicity in Sunyaev-Zel'dovich-Selected Galaxy Clusters at 0 < z < 1.5

We present the results of an X-ray spectral analysis of 153 galaxy clusters observed with the Chandra, XMM-Newton, and Suzaku space telescopes. These clusters, which span 0 < z < 1.5, were drawn from a larger, mass-selected sample of galaxy clusters discovered in the 2500 square degree South Pole Telescope Sunyaev Zel'dovich (SPT-SZ) survey. With a total combined exposure time of 9.1 Ms, these data yield the strongest constraints to date on the evolution of the metal content of the intracluster medium (ICM). We find no evidence for strong evolution in the global (r<R500) ICM metallicity (dZ/dz = -0.06 +/- 0.04 Zsun), with a mean value at z=0.6 of = 0.23 +/- 0.01 Zsun and a scatter of 0.08 +/- 0.01 Zsun. These results imply that >60% of the metals in the ICM were already in place at z=1 (at 95% confidence), consistent with the picture of an early (z>1) enrichment. We find, in agreement with previous works, a significantly higher mean value for the metallicity in the centers of cool core clusters versus non-cool core clusters. We find weak evidence for evolution in the central metallicity of cool core clusters (dZ/dz = -0.21 +/- 0.11 Zsun), which is sufficient to account for this enhanced central metallicity over the past ~10 Gyr. We find no evidence for metallicity evolution outside of the core (dZ/dz = -0.03 +/- 0.06 Zsun), and no significant difference in the core-excised metallicity between cool core and non-cool core clusters. This suggests that strong radio-mode AGN feedback does not significantly alter the distribution of metals at r>0.15R500. Given the limitations of current-generation X-ray telescopes in constraining the ICM metallicity at z>1, significant improvements on this work will likely require next-generation X-ray missions.Comment: 11 pages, 8 figures, 2 tables. Submitted to ApJ. Comments welcome

Reconstruction of metabolic networks from high-throughput metabolite profiling data: in silico analysis of red blood cell metabolism

We investigate the ability of algorithms developed for reverse engineering of transcriptional regulatory networks to reconstruct metabolic networks from high-throughput metabolite profiling data. For this, we generate synthetic metabolic profiles for benchmarking purposes based on a well-established model for red blood cell metabolism. A variety of data sets is generated, accounting for different properties of real metabolic networks, such as experimental noise, metabolite correlations, and temporal dynamics. These data sets are made available online. We apply ARACNE, a mainstream transcriptional networks reverse engineering algorithm, to these data sets and observe performance comparable to that obtained in the transcriptional domain, for which the algorithm was originally designed.Comment: 14 pages, 3 figures. Presented at the DIMACS Workshop on Dialogue on Reverse Engineering Assessment and Methods (DREAM), Sep 200

Extended radio emission in the galaxy cluster MS 0735.6+7421 detected with the Karl G. Jansky Very Large Array

MS 0735.6+7421 ($z = 0.216$) is a massive cool core galaxy cluster hosting one of the most powerful active galactic nuclei (AGN) outbursts known. The radio jets of the AGN have carved out an unusually large pair of X-ray cavities, each reaching a diameter of $200$ kpc. This makes MS 0735.6+7421 a unique case to investigate active galactic nuclei feedback processes, as well as other cluster astrophysics at radio wavelengths. We present new low-radio-frequency observations of MS 0735.6+7421 taken with the Karl G. Jansky Very Large Array (VLA): 5 hours of P-band ($224-480$ MHz) and 5 hours of L-band ($1-2$ GHz) observations, both in C configuration. Our VLA P-band ($224-480$ MHz) observations reveal the presence of a new diffuse radio component reaching a scale of $\sim$ $900$ kpc in the direction of the jets and of $\sim$ $500$ kpc in the direction perpendicular to the jets. This component is centered on the cluster core and has a radio power scaled at $1.4$ GHz of $P_{1.4\text{ GHz}} = (4\pm2)\times 10^{24}$ WHz$^{-1}$. Its properties are consistent with those expected from a radio mini-halo as seen in other massive cool core clusters, although it may also be associated with radio plasma that has diffused out of the X-ray cavities. Observations at higher spatial resolution are needed to fully characterize the properties and nature of this component. We also suggest that if radio mini-halos originate from jetted activity, we may be witnessing the early stages of this process.Comment: 11 pages, 7 figures, submitted to MNRA

Star-Forming Brightest Cluster Galaxies at 0.25 < z < 1.25: A Transitioning Fuel Supply

We present a multi-wavelength study of 90 brightest cluster galaxies (BCGs) in a sample of galaxy clusters selected via the Sunyaev Zel'dovich effect by the South Pole Telescope, utilizing data from various ground- and space-based facilities. We infer the star formation rate (SFR) for the BCG in each cluster, based on the UV and IR continuum luminosity, as well as the [O II] emission line luminosity in cases where spectroscopy is available, finding 7 systems with SFR > 100 Msun/yr. We find that the BCG SFR exceeds 10 Msun/yr in 31 of 90 (34%) cases at 0.25 < z < 1.25, compared to ~1-5% at z ~ 0 from the literature. At z > 1, this fraction increases to 92(+6)(-31)%, implying a steady decrease in the BCG SFR over the past ~9 Gyr. At low-z, we find that the specific star formation rate in BCGs is declining more slowly with time than for field or cluster galaxies, most likely due to the replenishing fuel from the cooling ICM in relaxed, cool core clusters. At z > 0.6, the correlation between cluster central entropy and BCG star formation - which is well established at z ~ 0 - is not present. Instead, we find that the most star-forming BCGs at high-z are found in the cores of dynamically unrelaxed clusters. We investigate the rest-frame near-UV morphology of a subsample of the most star-forming BCGs using data from the Hubble Space Telescope, finding complex, highly asymmetric UV morphologies on scales as large as ~50-60 kpc. The high fraction of star-forming BCGs hosted in unrelaxed, non-cool core clusters at early times suggests that the dominant mode of fueling star formation in BCGs may have recently transitioned from galaxy-galaxy interactions to ICM cooling.Comment: 20 pages, 10 figures. Submitted for publication in ApJ. Comments welcom

Revealing the velocity structure of the filamentary nebula in NGC 1275 in its entirety

We have produced for the first time a detailed velocity map of the giant filamentary nebula surrounding NGC 1275, the Perseus cluster’s brightest galaxy, and revealed a previously unknown rich velocity structure across the entire nebula. These new observations were obtained with the optical imaging Fourier transform spectrometer SITELLE at CFHT. With its wide field of view ( ∼11 arcmin × 11 arcmin), SITELLE is the only integral field unit spectroscopy instrument able to cover the 80 kpc  ×  55 kpc ( 3.8 arcmin × 2.6 arcmin) large nebula in NGC 1275. Our analysis of these observations shows a smooth radial gradient of the [N II]λ6583/H α line ratio, suggesting a change in the ionization mechanism and source across the nebula. The velocity map shows no visible general trend or rotation, indicating that filaments are not falling uniformly onto the galaxy, nor being uniformly pulled out from it. Comparison between the physical properties of the filaments and Hitomi measurements of the X-ray gas dynamics in Perseus is also explored

A Multi-Wavelength Mass Analysis of RCS2 J232727.6-020437, a ~3x1015^{15}M⊙_{\odot} Galaxy Cluster at z=0.7

We present an initial study of the mass and evolutionary state of a massive and distant cluster, RCS2 J232727.6-020437. This cluster, at z=0.6986, is the richest cluster discovered in the RCS2 project. The mass measurements presented in this paper are derived from all possible mass proxies: X-ray measurements, weak-lensing shear, strong lensing, Sunyaev Zel'dovich effect decrement, the velocity distribution of cluster member galaxies, and galaxy richness. While each of these observables probe the mass of the cluster at a different radius, they all indicate that RCS2 J232727.6-020437 is among the most massive clusters at this redshift, with an estimated mass of M_200 ~3 x10^15 h^-1 Msun. In this paper, we demonstrate that the various observables are all reasonably consistent with each other to within their uncertainties. RCS2 J232727.6-020437 appears to be well relaxed -- with circular and concentric X-ray isophotes, with a cool core, and no indication of significant substructure in extensive galaxy velocity data.Comment: 19 pages, 15 figures, submitted to ApJ on March 5, 2015; in press. Manuscript revised following the referee revie

Current Estimates for HIV-1 Production Imply Rapid Viral Clearance in Lymphoid Tissues

It has recently been estimated that a single HIV-1 infected cell produces between and more than viral particles over its life span. Since body-wide estimates of the ratio of free virus to productively infected cells are smaller than and much smaller than , individual virions must be cleared rapidly. This seems difficult to reconcile with the fact that most of the total body virus is trapped on follicular dendritic cells where it can survive for many months. It has also been difficult to reconcile the vast difference in the rates at which the virus is cleared from the blood in rhesus macaques and in chronically infected patients. Here we attempt to reconcile these seemingly contradictory observations by considering the virion clearance rate in various organs and the virion exchange rates between them. The main results are that the per capita clearance rate of free virus in lymphoid tissue should be fast, the virion exchange rate between lymphoid tissue and the blood should be slow, and the comparatively slow previous estimates for the virion clearance rate from the blood correspond to the rate of virion efflux from the blood to other organs where the virus is ultimately cleared

Lumpability Abstractions of Rule-based Systems

The induction of a signaling pathway is characterized by transient complex formation and mutual posttranslational modification of proteins. To faithfully capture this combinatorial process in a mathematical model is an important challenge in systems biology. Exploiting the limited context on which most binding and modification events are conditioned, attempts have been made to reduce the combinatorial complexity by quotienting the reachable set of molecular species, into species aggregates while preserving the deterministic semantics of the thermodynamic limit. Recently we proposed a quotienting that also preserves the stochastic semantics and that is complete in the sense that the semantics of individual species can be recovered from the aggregate semantics. In this paper we prove that this quotienting yields a sufficient condition for weak lumpability and that it gives rise to a backward Markov bisimulation between the original and aggregated transition system. We illustrate the framework on a case study of the EGF/insulin receptor crosstalk.Comment: In Proceedings MeCBIC 2010, arXiv:1011.005