57 research outputs found

    Technique for validating remote sensing products of water quality

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    Remote sensing of water quality is initiated as an additional part of the on going activities of the EAGLE2006 project. Within this context intensive in-situ and airborne measurements campaigns were carried out over the Wolderwijd and Veluwemeer natural waters. However, in-situ measurements and image acquisitions were not simultaneous. This poses some constraints on validating air/space-borne remote sensing products of water quality. Nevertheless, the detailed insitu measurements and hydro-optical model simulations provide a bench mark for validating remote sensing products. That is realized through developing a stochastic technique to quantify the uncertainties on the retrieved aquatic inherent optical properties (IOP). The output of the proposed technique is applied to validate remote sensing products of water quality. In this processing phase, simulations of the radiative transfer in the coupled atmosphere-water system are performed to generate spectra at-sensor-level. The upper and the lower boundaries of perturbations, around each recorded spectrum, are then modelled as function of residuals between simulated and measured spectra. The perturbations are parameterized as a function of model approximations/inversion, sensor-noise and atmospheric residual signal. All error sources are treated as being of stochastic nature. Three scenarios are considered: spectrally correlated (i.e. wavelength dependent) perturbations, spectrally uncorrelated perturbations and a mixed scenario of the previous two with equal probability of occurrence. Uncertainties on the retrieved IOP are quantified with the relative contribution of each perturbation component to the total error budget of the IOP. This technique can be used to validate earth observation products of water quality in remote areas where few or no in– situ measurements are available

    The dynamics of liquid slugs forced by a syringe pump

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    Microfluidic processes for chemical synthesis have become popular in recent years. The small scale of the chemical reactions promise greater control over reaction conditions and more timely creation of products. The small scale of microfluidics poses its own set of problems, however. At the microscale, the dominant fluid forces are viscous resistance and surface tension. The effects of viscosity and scale reduce the Reynolds number and make mixing difficult. Much work has been done to control mixing at the microscale. This problem is concerned with a different microfluidic problem: delivering reactants to the site of reaction. A common setup is to attach syringes full of reactant to a reaction chamber by narrow hydrophobic tubing. Using a stepper motor, a controlled dose of liquid may be injected into the tube. The hydrophobosity causes the dose to curve outward on the sides, becoming a "slug" of reactant with air in front and behind. The syringe at the rear is then switched for one full of air, and air pressure is used to drive the slug to the reaction site. If too much pressure is applied, the slug will arrive with a significant back pressure that will be relieved through bubbling in the reaction site. This causes the formation of a foam and is highly undesirable. We present a simple model based on Boyle’s law for the motion of a slug through a tube. We then extend this model for trains of slugs separated by air bubbles. Last, we consider the case of a flooded reaction site, where the forward air bubble must be pushed through the flooding liquid. In conclusion, we have determined the dynamics of a single slug moving towards an empty reaction chamber giving the final equilibrium position of the slug. A phase-plane analysis then determined a condition on the size of the slug needed to ensure that it comes to rest without oscillating about the equilibrium position. The effect of a flooded reaction chamber was then considered. In this case it is impossible to avoid bubbling due to the design of the device. We found that it is possible, however, to reduce the bubbling by minimising the back pressure behind the slug. Finally, the dynamics of multiple slugs with or without a flooded reaction chamber has been investigated

    Mimetic finite difference methods in image processing

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    Synthesis of layered silicon-graphene hetero-structures by wet jet milling for high capacity anodes in Li-ion batteries

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    While silicon-based negative electrode materials have been extensively studied, to develop high capacity lithium-ion batteries, implementing a large-scale production method that can be easily transferred to industy, has been a crucial challenge. Here, a scalable wet-jet milling method was developed to prepare a silicon-graphene hybrid material to be used as negative electrode in lithium-ion batteries. This synthesized composite, when used as an anode in lithium cells, demonstrated high Li ion storage capacity, long cycling stability and high-rate capability. In particular, the electrode exhibited a reversible discharge capacity exceeding 1763 mAh g-1 after 450 cycles with a capacity retention of 98% and a coulombic efficiency of 99.85% (with a current density of 358 mA g-1). This significantly supersedes the performance of a Si-dominant electrode structures. The capacity fade rate after 450 cycles was only 0.005% per cycle in the 0.05-1 V range. This superior electrochemical performance is ascribed to the highly layered, silicon-graphene porous structure, as investigated via focused ion beam in conjunction with scanning electron microscopy (FIB-SEM) tomography. The hybrid electrode could retain 89% of its porosity (under a current density of 358 mA g-1) after 200 cycles compared with only 35% in a Si-dominant electrode. Moreover, this morphology can not only accommodate the large volume strains from active silicon particles, but also maintains robust electrical connectivity. This confers faster transportation of electrons and ions with significant permeation of electrolyte within the electrode. Physicochemical characterisations were performed to further correlate the electrochemical performance with the microstructural dynamics. The excellent performance of the hybrid material along with the scalability of the synthesizing process is a step forward to realize high capacity/energy density lithium-ion batteries for multiple device applications

    Home birth and barriers to referring women with obstetric complications to hospitals: a mixed-methods study in Zahedan, southeastern Iran

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    <p>Abstract</p> <p>Background</p> <p>One factor that contributes to high maternal mortality in developing countries is the delayed use of Emergency Obstetric-Care (EmOC) facilities. The objective of this study was to determine the factors that hinder midwives and parturient women from using hospitals when complications occur during home birth in Sistan and Baluchestan province, Iran, where 23% of all deliveries take place in non- hospital settings.</p> <p>Methods</p> <p>In the study and data management, a mixed-methods approach was used. In the quantitative phase, we compared the existing health-sector data with World Health Organization (WHO) standards for the availability and use of EmOC services. The qualitative phase included collection and analysis of interviews with midwives and traditional birth attendants and twenty-one in-depth interviews with mothers. The data collected in this phase were managed according to the principles of qualitative data analysis.</p> <p>Results</p> <p>The findings demonstrate that three distinct factors lead to indecisiveness and delay in the use of EmOC by the midwives and mothers studied. Socio-cultural and familial reasons compel some women to choose to give birth at home and to hesitate seeking professional emergency care for delivery complications. Apprehension about being insulted by physicians, the necessity of protecting their professional integrity in front of patients and an inability to persuade their patients lead to an over-insistence by midwives on completing deliveries at the mothers' homes and a reluctance to refer their patients to hospitals. The low quality and expense of EmOC and the mothers' lack of health insurance also contribute to delays in referral.</p> <p>Conclusions</p> <p>Women who choose to give birth at home accept the risk that complications may arise. Training midwives and persuading mothers and significant others who make decisions about the value of referring women to hospitals at the onset of life-threatening complications are central factors to increasing the use of available hospitals. The hospitals must be safe, comfortable and attractive environments for parturition and should give appropriate consideration to the ethical and cultural concerns of the women. Appropriate management of financial and insurance-related issues can help midwives and mothers make a rational decision when complications arise.</p

    A systematic review of operating room ventilation

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    Ventilation systems are the primary way of eliminating airborne pathogenic particles in an operating room (OR). However, such systems can be complex due to factors such as different surgical instruments, diverse room sizes, various staff counts, types of clothing used, different surgical types and duration, medications, and patient conditions. OR ventilation should provide a thermally comfortable environment for the surgical staff team members while preventing the patient from suffering from any extreme hypothermia. Many technical, logistical, and ethical implications need to be considered in the early stage of designing a ventilation system for an OR. Years of research and a significant number of publications have highlighted the controversy and disagreement among infection specialists, design engineers, and ventilation experts in this context. This review article aims to provide a good understanding of OR ventilation systems in the context of air quality and infection control from existing research and provide multidimensional insights for appropriate design and operation of the OR. To this end, we have conducted a systematic review of the literature, covering 253 articles in this context. Systematic review and meta-analyses were used to map the evidence and identify research gaps in the existing clinical, practical, and engineering knowledge. The present study is categorized into six research focuses: ventilation system, thermal comfort, staff work practice and obstacles, door operation and passage, air cleaning technology, emission rate, and clothing systems. In the conclusion, we summarize the key limitations of the existing studies and insights for future research direction

    Comparative study of the implementation of tin and titanium oxide nanoparticles as electrodes materials in Li-ion batteries

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    Transition metal oxides potentially present higher specific capacities than the current anodes based on carbon, providing an increasing energy density as compared to commercial Li-ion batteries. However, many parameters could influence the performance of the batteries, which depend on the processing of the electrode materials leading to different surface properties, sizes or crystalline phases. In this work a comparative study of tin and titanium oxide nanoparticles synthesized by different methods, undoped or Li doped, used as single components or in mixed ratio, or alternatively forming a composite with graphene oxide have been tested demonstrating an enhancement in capacity with Li doping and better cyclability for mixed phases and composite anodes
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