The (Evolving) vineyard\u2019s age structure in the valencian community, Spain. A new demographic approach for rural development and landscape analysis

Vineyards have assumed a key role as rural landmarks in recent decades. Investigating vineyard dynamics and contexts may reveal various economic, cultural, and environmental aspects of rural landscapes, which can be linked to land-use changes and major soil degradation processes, including soil erosion. As a contribution to rural landscape studies, the purpose of this work is to investigate the spatial distribution of vineyard plots in the Valencian community, located in the eastern area of the Iberian Peninsula, focusing on the final product, the type of vineyard and how long each vineyard has been settled over time. The work provides a comprehensive analysis of a wine-growing landscape, considering strategic (spatial) assets in present and past times. Vineyards were interpreted as a distinctive landmarks that give value to local economies, basic knowledge of how long different types of wine plots have been present in the Valencian community is useful when estimating their degree of sustainability and formulating suggestions, policies, and strategies to prevent processes of landscape degradation at various spatial scales

Improving Performance of QUIC in WiFi

QUIC is a new transport protocol under standardization since 2016. Initially developed by Google as an experiment, the protocol is already deployed in large-scale, thanks to its support in Chromium and Google's servers. In this paper we experimentally analyze the performance of QUIC in WiFi networks. We perform experiments using both a controlled WiFi testbed and a production WiFi mesh network. In particular, we study how QUIC interplays with MAC layer features such as IEEE 802.11 frame aggregation. We show that the current implementation of QUIC in Chromium achieves sub-optimal throughput in wireless networks. Indeed, burstiness in modern WiFi standards may improve network performance, and we show that a Bursty QUIC (BQUIC), i.e., a customized version of QUIC that is targeted to increase its burstiness, can achieve better performance in WiFi. BQUIC outperforms the current version of QUIC in WiFi, with throughput gains ranging between 20% to 30%

Industrial sprawl and residential housing. Exploring the interplay between local development and land-use change in the Valencian Community, Spain

Urbanization in Mediterranean Europe has occurred in recent decades with expansion of residential, commercial and industrial settlements into rural landscapes outside the traditional metropolitan boundaries. Industrial expansion in peri-urban contexts was particularly intense in Southern Europe. Based on these premises, this work investigates residential and industrial settlement dynamics in the Valencian Community, Spain, between 2005 and 2015, with the aim to clarify the role of industrial expansion in total urban growth in a paradigmatic Mediterranean region. Since the early 1990s, the Valencian industrial sector developed in correspondence with already established industrial nodes, altering the surrounding rural landscape. Six variables (urban hierarchy, discontinuous settlements, pristine land under urban expansion, isolated industrial settlements, within- and out-of-plan industrial areas) were considered with the aim at exploring land-use change. Empirical results indicate a role of industrial development in pushing urban sprawl in coastal Valencia. A reflection on the distinctive evolution of residential and industrial settlements is essential for designing new planning measures for sustainable land management and containment of urban sprawl in Southern Europe. A comparative analysis of different alternatives of urban development based on quantitative assessment of land-use change provides guidelines for local development and ecological sustainability

A Nexafs Study of Nitric Oxide Layers Adsorbed from a nitrite Solution onto a Pt(111) Surface

NO molecules adsorbed on a Pt(111) surface from dipping in an acidic nitrite solution are studied by near edge X-ray absorption fine structure spectroscopy (NEXAFS), X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED) and scanning tunnelling microscopy (STM) techniques. LEED patterns and STM images show that no long range ordered structures are formed after NO adsorption on a Pt(111) surface. Although the total NO coverage is very low, spectroscopic features in N K-edge and O K-edge absorption spectra have been singled out and related to the different species induced by this preparation method. From these measurements it is concluded that the NO molecule is adsorbed trough the N atom in an upright conformation. The maximum saturation coverage is about 0.3 monolayers, and although nitric oxide is the major component, nitrite and nitrogen species are slightly co-adsorbed on the surface. The results obtained from this study are compared with those previously reported in the literature for NO adsorbed on Pt(111) under UHV conditions

Extended Huckel theory for bandstructure, chemistry, and transport. II. Silicon

In this second paper, we develop transferable semi-empirical parameters for the technologically important material, silicon, using Extended Huckel Theory (EHT) to calculate its electronic structure. The EHT-parameters areoptimized to experimental target values of the band dispersion of bulk-silicon. We obtain a very good quantitative match to the bandstructure characteristics such as bandedges and effective masses, which are competitive with the values obtained within an $sp^3 d^5 s^*$ orthogonal-tight binding model for silicon. The transferability of the parameters is investigated applying them to different physical and chemical environments by calculating the bandstructure of two reconstructed surfaces with different orientations: Si(100) (2x1) and Si(111) (2x1). The reproduced $\pi$- and $\pi^*$-surface bands agree in part quantitatively with DFT-GW calculations and PES/IPES experiments demonstrating their robustness to environmental changes. We further apply the silicon parameters to describe the 1D band dispersion of a unrelaxed rectangular silicon nanowire (SiNW) and demonstrate the EHT-approach of surface passivation using hydrogen. Our EHT-parameters thus provide a quantitative model of bulk-silicon and silicon-based materials such as contacts and surfaces, which are essential ingredients towards a quantitative quantum transport simulation through silicon-based heterostructures.Comment: 9 pages, 9 figure

A new sauropod titanosaur from the Plottier Formation (Upper Cretaceous) of Patagonia (Argentina)

This paper presents a new titanosaur sauropod, collected from levels of reddish clays assigned to the Plottier Formation (Coniacian-Santonian). The holotype of Petrobrasaurus puestohernandezi gen. et. sp. nov. is a disarticulated specimen, from which teeth, cervical, dorsal and caudal vertebrae, sternal plates, metacarpals, femora, tibia, a fragment of ilium, pubis, haemal arches, and cervical and dorsal ribs have been preserved. This period is of particular interest because it saw the definitive isolation of the vertebrate faunas of Patagonia, with the separation of South America from the rest of Gondwana, a process that had begun during the Early Cretaceous. Although some of the characters observed in Petrobrasaurus gen. nov. suggest a relationship with the South American clade Lognkosauria, this new sauropod is regarded as Titanosauria incertae sedis until a more profound analysis of the Titanosauria that in which it is included is undertaken