Alguns contributos da nanotecnologia para a sustentabilidade dos materiais de construção

Os avanços nanotecnológicos atingem inúmeras áreas da ciência, mas no âmbito da sustentabilidade dos materiais de construção os progressos embora importantes são escassos e acima de tudo objeto de reduzida divulgação. O presente artigo sintetiza uma avaliação do estado da arte relativa a alguns dos contributos da nanotecnologia para a sustentabilidade dos materiais de construção. No mesmo se aborda a compreensão dos compostos gerados durante a hidratação do cimento Portland, o aumento da resistência e da durabilidade de argamassas e betões pela adição de nanopartículas e nanotubos e de que forma a adição de nanopartículas pode contribuir para a autolimpeza, a purificação do ar e a capacidade bactericida em materiais construtivos por via do efeito fotocatalítico. O presente artigo aborda ainda os últimos desenvolvimentos da nanotecnologia com vista à eficiência energética, nomeadamente pela produção de isolamentos térmicos de elevado desempenho, janelas com baixa condutibilidade térmica, vidros com transmitância variável e materiais de mudança de fase mais eficientes

A discriminatory test for the wheat B and G genomes reveals misclassified accessions of Triticum timopheevii and Triticum turgidum

The tetraploid wheat species Triticum turgidum and Triticum timopheevii are morphologically similar, and misidentification of material collected from the wild is possible. We compared published sequences for the Ppd-A1, Ppd-B1 and Ppd-G1 genes from multiple accessions of T. turgidum and T. timopheevii and devised a set of four polymerase chain reactions (PCRs), two specific for Ppd-B1 and two for Ppd-G1. We used these PCRs with 51 accessions of T. timopheevii and 20 of T. turgidum. Sixty of these accessions gave PCR products consistent with their taxon identifications, but the other eleven accessions gave anomalous results: ten accessions that were classified as T. turgidum were identified as T. timopheevii by the PCRs, and one T. timopheevii accession was typed as T. turgidum. We believe that these anomalies are not due to errors in the PCR tests because the results agree with a more comprehensive analysis of genome-wide single nucleotide polymorphisms, which similarly suggest that these eleven accessions have been misclassified. Our results therefore show that the accepted morphological tests for discrimination between T. turgidum and T. timopheevii might not be entirely robust, but that species identification can be made cheaply and quickly by PCRs directed at the Ppd-1 gene.info:eu-repo/semantics/publishedVersio

Contributos da nanotecnologia para a sustentabilidade dos materiais de construção

Dissertação de mestrado integrado em Engenharia CivilOs avanços nanotecnológicos atingem inúmeras áreas da ciência, mas no âmbito da sustentabilidade dos materiais de construção os progressos embora importantes são escassos e acima de tudo objeto de reduzida divulgação. O presente artigo sintetiza uma avaliação do estado da arte relativa a alguns dos contributos da nanotecnologia para a sustentabilidade dos materiais de construção. No mesmo, se aborda a compreensão dos compostos gerados durante a hidratação do cimento Portland, o aumento da resistência e da durabilidade de argamassas e betões pela adição de nanopartículas e nanotubos e de que forma a adição de nanopartículas pode contribuir para a autolimpeza, a purificação do ar e a capacidade bactericida em materiais construtivos por via do efeito fotocatalítico. A presente dissertação de mestrado aborda ainda os últimos desenvolvimentos da nanotecnologia com vista à eficiência energética, nomeadamente pela produção de isolamentos térmicos de elevado desempenho, janelas com baixa condutibilidade térmica, vidros com transmitância variável e materiais de mudança de fase mais eficientes. Os contributos da nanotecnologia para a ecoeficiência dos materiais de construção são muito amplos, mas quase nada foi, ainda, conquistado comparado com as verdadeiras potencialidades que a nanotecnologia oferece à engenharia civil. Os produtos nanotecnológicos são ainda muito caros e difíceis de produzir em massa e com a qualidade desejada, mas prevê-se que o constante investimento e novas descobertas sejam alcançadas para tornar a própria nanotecnologia mais sustentável.Advances in nanotechnology have impacts in many areas of science. However, within building materials and its sustainability, the advances are few and subject to reduced disclosure. This article summarizes an evaluation of the state of the art relating to some of the contributions of nanotechnology to the sustainability of building materials. In it, is approached the understanding of compounds generated during the hydration of Portland cement, increased strength and durability of mortar and concrete by adding nanoparticles and Nano carbon filaments and how the addition of nanoparticles may contribute to self-cleaning, air purification and bactericidal capacity in building materials by means of photo catalytic effect. This dissertation also discusses the latest developments in nanotechnology aimed at energy efficiency, including the production of high performance thermal insulation, windows with low thermal conductivity, glasses with variable transmittance and more efficient phase change materials. Contributions of nanotechnology to eco-efficiency of building materials are wide, but almost nothing has yet achieved compared with the real potential that nanotechnology offers for civil engineering. Nanotechnology products are still very expensive and hard to mass-produce with the desired quality, but it´s expected that the ongoing investment and new discoveries be achieved to make nanotechnology itself more sustainable

Mechanical, surface and environmental evaluation of stone mastic asphalt mixtures with advanced asphalt binders using waste materials

The reuse of waste materials in asphalt mixtures has been recently investigated, in order to develop new sustainable solutions for the road-paving industry. Such materials should improve the mechanical performance and provide safe/comfortable pavement surface courses for road users, without compromising their environmental performance. Thus, the aim of this study is to evaluate the mechanical, surface and environmental properties of stone mastic asphalt (SMA) mixtures produced with forward-looking asphalt binders incorporating waste materials. These binders were designed to maximise the waste material content using motor oil, high-density polyethylene, styrene?butadiene?styrene and crumb rubber, while performing so well as a commercial modified bitumen. Finally, the overall performance of the SMA mixtures produced with the selected binders was evaluated. It was concluded that these mixtures improve the water sensitivity, fatigue cracking and permanent deformation performance. The requirements for macrotexture, skid resistance and presence of heavy metals in leachates of these mixtures were similarly fulfilled. Thus, this work shows that new asphalt mixtures with waste materials can be used in road-paving works to improve the performance without compromising human and environmental safety.Portuguese Government and EU/FSE within a PhD fellowship (SFRH/BD98379/2013) of the FCT, in the scope of POPH/QREN, by ERDF (European Regional Development Fund) funds through the Competitiveness Factors Operational Programme (COMPETE)info:eu-repo/semantics/publishedVersio

Carbon dioxide emissions and heavy metal contamination analysis of stone mastic asphalt mixtures produced with high rates of different waste materials

The incorporation of waste materials in asphalt mixtures has driven several studies mainly focused on improving their mechanical performance while minimizing the use of virgin materials. However, these could only be considered cleaner solutions for road paving works if their production and application do not present additional risks for human health and the environment. Therefore, this study aims at assessing the carbon dioxide emissions and possible leachates of stone mastic asphalt mixtures produced with high rates of different waste materials for binder modification or material recycling. Thus, a chemical analysis of eluates that were in contact with those mixtures and an estimation of the carbon dioxide emissions associated with their production and transportation were carried out under different scenarios. In conclusion, these mixtures comply with the established specifications for hazardous leachates. The addition of waste materials to these mixtures decreases carbon dioxide emissions, especially for recycled stone mastic asphalt mixtures with 50% reclaimed asphalt pavement material and bitumens modified with waste materials. Thus, the studied mixtures are innovative solutions for future use in pavement maintenance and rehabilitation operations, in line with the circular economy concept.The authors gratefully acknowledge the funding by the Portuguese Government and EU/FSE within a Portuguese Foundation for Science and Technology (FCT) Ph.D. grant (SFRH/BD98379/2013), in the scope of POPH/QREN

Development and application of a microsurfacing mix design method to assess the influence of the emulsion type

Microsurfacing asphalt mixtures are a preventive maintenance technology comprising the application of a slurry (produced with a modified asphalt emulsion), aggregate, filler, and water on top of an existing pavement at ambient temperature. Although it is a widely used technology, further studies on the mix design procedures are necessary to ensure an adequate composition. Thus, this study contributes to developing an improved mix design procedure for microsurfacing asphalt mixtures. Different mixtures were prepared, and the influence of the type and amount of asphalt emulsion and the amount of added water and filler (cement) on the characteristics of the mixture were evaluated. Two preliminary tests, referred to as the “pizza test” and the “ball test”, were proposed to determine the initial proportions of added water and cement in the mixture, respectively. Then, consistency, cohesion, and shaking abrasion tests were performed to determine the optimum content of each component and evaluate their influence on the mixture characteristics. The results showed that these tests are essential to optimize the mix composition, even though it was found that the mix design of microsurfacings is a complex task because the mixture is a system with chemical interactions strongly influenced by its composition.This research was funded by Fundação para a Ciência e a Tecnologia through a Ph.D. grant (number 2021.08004.BD). This work was also partly financed by FCT/MCTES through national funds (PIDDAC) under the R&D Unit Institute for Sustainability and Innovation in Structural Engineering (ISISE), reference UIDB/04029/2020, and under the Associate Laboratory Advanced Production and Intelligent Systems ARISE, reference LA/P/0112/2020

Low-temperature performance of polymer-modified binders in stone mastic asphalts

When temperatures drop to significantly low levels, road pavements are subjected to thermally-induced stresses, resulting in the appearance of thermal cracking, among other distresses. In these situations, polymers can be used as asphalt binder modifiers to improve certain asphalt binder properties, such as elastic recovery, cohesion, and ductility. Polymers also minimize some of the problems of asphalt mixtures, such as thermal and fatigue cracking and permanent deformation. This work’s objective was to study the behavior of asphalt mixtures at low temperatures, mainly when using modified binders. Thus, three binders were selected and tested: a standard 50/70 penetration grade bitumen and two polymer-modified binders (PMB), obtained by adding, respectively, 2.5% and 5.0% of styrene–butadiene–styrene (SBS) in the 50/70 pen grade bitumen. Then, the PMBs were incorporated into stone mastic asphalt mixtures (namely SMA 11), which were subjected to low-temperature mechanical tests based on the most recent European Standards. The asphalt binders and mixtures evaluated in this work were tested for thermal cracking resistance, creep, elastic recovery, cohesive strength, and ductility strength. Overall, it is concluded that the studied asphalt mixtures with PMB, with just 2.5% SBS, performed adequately at low temperatures down to −20 °C.This research was funded by FCT/MCTES through national funds (PIDDAC) under the R&D Unit Institute for Sustainability and Innovation in Structural Engineering (ISISE), under reference code UIDB/04029/2020

Estimation of energy consumption on the tire-pavement interaction for asphalt mixtures with different surface properties using data mining techniques

The energy or fuel consumption of the millions of vehicles that daily operate in road pavements has a significant economic and environmental impact on the use phase of road infrastructures regarding their life cycle analysis. Therefore, new solutions should be studied to reduce the vehicles energy consumption, namely due to the tire-pavement interaction, and contribute towards the sustainable development. This study aims at estimating the energy consumption due to the rolling resistance of tires moving over pavements with distinct surface characteristics. Thus, different types of asphalt mixtures were used in the surface course to determine the main parameters influencing the energy consumption. A laboratory scale prototype was developed explicitly for this evaluation. Data mining techniques were used to analyze the experimental results due to the complex correlation between the data collected during the tests, providing meaningful results. In particular, the artificial neural network allowed to obtain models with excellent capacity to estimate energy consumption. A sensitive analysis was carried out with a five input parameter model, which showed that the main parameters controlling the energy consumption are the vehicle speed and the mean texture depth.ERDF funds, through the Competitivity Factors Operational Programme – COMPETE, and by national funds, through FCT – Foundation for Science and Technology, within the scope of the Strategic Project UID/ECI/04047/2013 and the project POCI-01-0145-FEDER-007633info:eu-repo/semantics/publishedVersio

Valorização de resíduos plásticos na modificação de betumes para pavimentos rodoviários

Com o aumento do tráfego rodoviário são colocadas maiores exigências aos pavimentos, surgindo a necessidade de melhorar o seu desempenho. Um método que pode melhorar significativamente a qualidade dos pavimentos flexíveis é a adição de polímeros aos ligantes/misturas betuminosas. Assim, foram produzidos ligantes modificados com polímeros reciclados, em diferentes condições, cujo desempenho foi comparado com o de ligantes convencionais e de um ligante modificado comercial. Os resultados dos ensaios laboratoriais serão utilizados na seleção de resíduos plásticos e das condições de produção do betume modificado para otimizar o seu comportamento, salientando-se que este estudo procura promover a reutilização de resíduos de uma forma mais ecológica e económica.Financiado por Fundos FEDER através do Programa Operacional Fatores de Competitividade – COMPETE e por Fundos Nacionais através da FCT – Fundação para a Ciência e a Tecnologia no âmbito do projeto PLASTIROADS (PTDC/ECM/119179/2010) e do projeto estratégico UI 4047 – 2011-2012