A hydrodynamic study of the circumstellar envelope of alpha Scorpii

Context: Both the absolute mass-loss rates and the mechanisms that drive the mass loss of late-type supergiants are still not well known. Binaries such as alpha Sco provide the most detailed empirical information about the winds of these stars. Aims: The goal was to improve the binary technique for the determination of the mass-loss rate of alpha Sco A by including a realistic density distribution and velocity field from hydrodynamic and plasma simulations. Methods: We performed 3D hydrodynamic simulations of the circumstellar envelope of alpha Sco in combination with plasma simulations accounting for the heating, ionization, and excitation of the wind by the radiation of alpha Sco B. These simulations served as the basis for an examination of circumstellar absorption lines in the spectrum of alpha Sco B as well as of emission lines from the Antares nebula. Results: The present model of the extended envelope of alpha Sco reproduces some of the structures that were observed in the circumstellar absorption lines in the spectrum of alpha Sco B. Our theoretical density and velocity distributions of the outflow deviate considerably from a spherically expanding model, which was used in previous studies. This results in a higher mass-loss rate of (2 +/- 0.5) x 10^-6 M_sun/yr. The hot H II region around the secondary star induces an additional acceleration of the wind at large distances from the primary, which is seen in absorption lines of Ti II and Cr II at -30 km/s.Comment: 12 pages, 14 figures, accepted for publication in A&

Lay leadership dinner

Immanuel Janssen, master of ceremonies; R. Hopmann, L. Hempelmann, J. Klotz, R. Meyer, M. Miller, S. Nafzger, R. Bohlmann, speakers. Recorded May 7, 1981

Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts

The mechanism of the asymmetric hydrogenation of prochiral enamides by well-defined, neutral bis(phosphine) cobalt(0) and cobalt(II) precatalysts has been explored using(R,R)-iPrDuPhos ((R,R)-iPrDuPhos = (+)-1,2-bis[(2R,5R)-2,5-diisopropylphospholano]benzene) as a representative chiral bis(phosphine) ligand. A series of (R,R)-(iPrDuPhos)Co(enamide) (enamide = methyl-2-acetamidoacrylate (MAA), methyl(Z)-α-acetamidocinnamate (MAC), and methyl(Z)-acetamido(4-fluorophenyl)acrylate (4FMAC)) complexes (1-MAA, 1-MAC, and 1-4FMAC), as well as a dinuclear cobalt tetrahydride, [(R,R)-(iPrDuPhos)Co]2(μ2-H)3(H) (2), were independently synthesized, characterized, and evaluated in both stoichiometric and catalytic hydrogenation reactions. Characterization of (R,R)-(iPrDuPhos)Co(enamide) complexes by X-ray diffraction established the formation of the pro-(R) diastereomers in contrast to the (S)-alkane products obtained from the catalytic reaction. In situ monitoring of the cobalt-catalyzed hydrogenation reactions by UV–visible and freeze-quench electron paramagnetic resonance spectroscopies revealed (R,R)-(iPrDuPhos)Co(enamide) complexes as the catalyst resting state for all the three enamides studied. Variable time normalization analysis kinetic studies of the cobalt-catalyzed hydrogenation reactions in methanol established a rate law that is first order in (R,R)-(iPrDuPhos)Co(enamide) and H2 but independent of the enamide concentration. Deuterium-labeling studies, including measurement of an H2/D2 kinetic isotope effect and catalytic hydrogenations with HD, established an irreversible H2 addition step to the bound enamide. Density functional theory calculations support that this step is both rate and selectivity determining. Calculations, as well as HD-labeling studies, provide evidence for two-electron redox cycling involving cobalt(0) and cobalt(II) intermediates during the catalytic cycle. Taken together, these experiments support an unsaturated pathway for the [(R,R)-(iPrDuPhos)Co]-catalyzed hydrogenation of prochiral enamides

Radial Velocity Studies of Close Binary Stars. IX

Radial-velocity measurements and sine-curve fits to the orbital velocity variations are presented for the eighth set of ten close binary systems: AB And, V402 Aur, V445 Cep, V2082 Cyg, BX Dra, V918 Her, V502 Oph, V1363 Ori, KP Peg, V335 Peg. Half of the systems (V445 Cep, V2082 Cyg, V918 Her, V1363 Ori, V335 Peg) were discovered photometrically by the Hipparcos mission and all systems are double-lined (SB2) contact binaries. The broadening function method permitted improvement of the orbital elements for AB And and V502 Oph. The other systems have been observed for radial velocity variations for the first time; in this group are five bright (V<7.5) binaries: V445 Cep, V2082 Cyg, V918 Her, KP Peg and V335 Peg. Several of the studied systems are prime candidates for combined light and radial-velocity synthesis solutions.Comment: 17+ pages, 2 tables, 4 figure

HD Diesel engine equipped with a bottoming Rankine cycle as a waste heat recovery system. Part 2: Evaluation of alternative solutions

A theoretical investigation has been performed on the feasibility of introducing a waste heat recovery (WHR) system in a two-stage turbocharged HDD engine. The WHR is attained by introducing a Rankine cycle, which uses an organic substance or directly water as a working fluid depending on energetic performance considerations. A previous research was carried out to evaluate the maximum potential of this WHR concept, a conventional layout was used for coupling the Rankine cycle to the thermal engine. The objective of the present research is to broad the scope of the previous analysis by considering new alternative solutions for the problems related to the coupling between the WHR Rankine cycle and the thermal engine. These solutions are based on adapting one of the turbochargers by removing its turbine and trying to recover the energy by the Rankine cycle. Finally, the turbine of the Rankine cycle supplies the recovered energy directly to the compressor of this turbocharger. Thus, in these layouts the coupling is simpler as it involves only two turbomachines, which are supposed to share a similar rotating speed. From the results of the global energy balance, these alternative layouts produce slight benefits in fuel consumption but in all cases these benefits are lower compared to those attained with conventional layouts. © 2011 Published by Elsevier Ltd. All rights reserved.This work was partially funded by "Programa de Apoyo a la Investigacion y Desarrollo de la Universidad Politecnica de Valencia".Serrano Cruz, JR.; Dolz Ruiz, V.; Novella Rosa, R.; García Martínez, A. (2012). HD Diesel engine equipped with a bottoming Rankine cycle as a waste heat recovery system. Part 2: Evaluation of alternative solutions. Applied Thermal Engineering. 36:279-287. doi:10.1016/j.applthermaleng.2011.10.024S2792873

Speckle observations with PISCO in Merate - V. Astrometric measurements of visual binaries in 2006

International audienceWe present relative astrometric measurements of visual binaries made during the first semester of 2006, with the Pupil Interferometry Speckle camera and COronagraph at the 102-cm Zeiss telescope of the Brera Astronomical Observatory, in Merate. Our sample contains orbital couples as well as binaries whose motion is still uncertain. We obtained 217 new measurements of 194 objects, with angular separations in the range 0.1-4.2arcsec, and an average accuracy of 0.01arcsec. The mean error on the position angles is 0.5°. About half of those angles could be determined without the usual 180° ambiguity by the application of triple-correlation techniques. We also present a revised orbit for ADS 277 for which the previously published orbit resulted in a large residual from our measurements