On the Remarkable Superconductivity of FeSe and Its Close Cousins

Emergent electronic phenomena in iron-based superconductors have been at the forefront of condensed matter physics for more than a decade. Much has been learned about the origins and intertwined roles of ordered phases, including nematicity, magnetism, and superconductivity, in this fascinating class of materials. In recent years, focus has been centered on the peculiar and highly unusual properties of FeSe and its close cousins. This family of materials has attracted considerable attention due to the discovery of unexpected superconducting gap structures, a wide range of superconducting critical temperatures, and evidence for nontrivial band topology, including associated spin-helical surface states and vortex-induced Majorana bound states. Here, we review superconductivity in iron chalcogenide superconductors, including bulk FeSe, doped bulk FeSe, FeTe1−xSex, intercalated FeSe materials, and monolayer FeSe and FeTe1−xSex on SrTiO3. We focus on the superconducting properties, including a survey of the relevant experimental studies, and a discussion of the different proposed theoretical pairing scenarios. In the last part of the paper, we review the growing recent evidence for nontrivial topological effects in FeSe-related materials, focusing again on interesting implications for superconductivity

The Kondo lattice model from strong-coupling viewpoint

We present some preliminary results on the phase diagram of the 2D S=1/2 Kondo lattice model at finite doping. As a starting point the Hamiltonian is written in terms of local spin and charge excitations, and the interactions between these modes are subsequently treated in various perturbative schemes. We find that a paramagnetic-magnetic quantum phase transition does occur, and, at least on a superficial level, the Kondo effect does not break down at the critical point. The latter result however might well be a consequence of the inherent bias of our starting point and/or the level of approximation.Comment: 4 pages, to appear in the Proceedings of SCES 2001, Ann Arbor, August 200

Theory of quasiparticle vortex bound states in Fe-based superconductors: application to LiFeAs

Spectroscopy of vortex bound states can provide valuable information on the structure of the superconducting order parameter. Quasiparticle wavefunctions are expected to leak out in the directions of gap minima or nodes, if they exist, and scanning tunneling spectroscopy (STS) on these low-energy states should probe the momentum dependence of the gap. Anisotropy can also arise from band structure effects, however. We perform a quasiclassical calculation of the density of states of a single vortex in an anisotropic superconductor, and show that if the gap itself is not highly anisotropic, the Fermi surface anisotropy dominates, preventing direct observation of superconducting gap features. This serves as a cautionary message for the analysis of STS data on the vortex state on Fe-based superconductors, in particular LiFeAs, which we treat explicitly.Comment: 4 pages, 2 figure

Energy Gap Evolution Across the Superconductivity Dome in Single Crystals of (Ba1−x_{1-x}Kx_x)Fe2_2As2_2

The mechanism of unconventional superconductivity in iron-based superconductors (IBSs) is one of the most intriguing questions in current materials research. Among non-oxide IBSs, (Ba$_{1-x}$K$_x$)Fe$_2$As$_2$ has been intensively studied because of its high superconducting transition temperature and fascinating evolution of the superconducting gap structure from being fully isotropic at optimal doping ($x\approx$0.4) to becoming nodal at $x >$0.8. Although this marked evolution was identified in several independent experiments, there are no details of the gap evolution to date because of the lack of high-quality single crystals covering the entire K-doping range of the superconducting dome. We conducted a systematic study of the London penetration depth, $\lambda (T)$, across the full phase diagram for different concentrations of point-like defects introduced by 2.5 MeV electron irradiation. Fitting the low-temperature variation with the power law, $\Delta \lambda \sim T^{n}$, we find that the exponent $n$ is the highest and $T_c$ suppression rate with disorder is the smallest at optimal doping, and they evolve with doping being away from optimal, which is consistent with increasing gap anisotropy, including an abrupt change around $x\simeq 0.8$, indicating the onset of nodal behavior. Our analysis using a self-consistent $t$-matrix approach suggests the ubiquitous and robust nature of s$_{\pm}$ pairing in IBSs and argues against a previously suggested transition to a $d-$wave state near $x=1$ in this system

Detection of Single Molecules Illuminated by a Light-Emitting Diode

Optical detection and spectroscopy of single molecules has become an indispensable tool in biological imaging and sensing. Its success is based on fluorescence of organic dye molecules under carefully engineered laser illumination. In this paper we demonstrate optical detection of single molecules on a wide-field microscope with an illumination based on a commercially available, green light-emitting diode. The results are directly compared with laser illumination in the same experimental configuration. The setup and the limiting factors, such as light transfer to the sample, spectral filtering and the resulting signal-to-noise ratio are discussed. A theoretical and an experimental approach to estimate these parameters are presented. The results can be adapted to other single emitter and illumination schemes.Comment: 7 pages, 5 figure