Air Pollution and Outdoor Recreation On Urban Trails: A Case Study of the Elizabeth River Trail, Norfolk

Poor air quality represents a significant health risk for individuals engaging in recreation activities outdoors in urban parks and trails. This study investigated temporal variability in particulate matter (PM) exposure along an urban waterfront trail. We also used recreation choice frameworks to examine the effects of visitors’ perceptions of air quality (AQ) and health benefits on trail use. Average air quality during the collection period was “good” (PM10) to “moderate” (PM2.5). We found that PM density was significantly higher (p \u3c 0.001), though still in the “moderate” range, at 7–9 a.m., 11 a.m.–1 p.m., and 3–5 p.m., and on weekends. Visitors’ self-reported perceptions of health outcomes, but not air quality, significantly predicted trail use. Results suggest that these experiential factors may affect recreational choices depending on other factors, such as salience. Further research is merited to determine how experiential factors can be integrated with other theories of motivation to understand recreational decision-making

Gallavotti-Cohen-Type symmetry related to cycle decompositions for Markov chains and biochemical applications

We slightly extend the fluctuation theorem obtained in \cite{LS} for sums of generators, considering continuous-time Markov chains on a finite state space whose underlying graph has multiple edges and no loop. This extended frame is suited when analyzing chemical systems. As simple corollary we derive in a different method the fluctuation theorem of D. Andrieux and P. Gaspard for the fluxes along the chords associated to a fundamental set of oriented cycles \cite{AG2}. We associate to each random trajectory an oriented cycle on the graph and we decompose it in terms of a basis of oriented cycles. We prove a fluctuation theorem for the coefficients in this decomposition. The resulting fluctuation theorem involves the cycle affinities, which in many real systems correspond to the macroscopic forces. In addition, the above decomposition is useful when analyzing the large deviations of additive functionals of the Markov chain. As example of application, in a very general context we derive a fluctuation relation for the mechanical and chemical currents of a molecular motor moving along a periodic filament.Comment: 23 pages, 5 figures. Correction

Topped MAC with extra dimensions?

We perform the most attractive channel (MAC) analysis in the top mode standard model with TeV-scale extra dimensions, where the standard model gauge bosons and the third generation of quarks and leptons are put in D(=6,8,10,...) dimensions. In such a model, bulk gauge couplings rapidly grow in the ultraviolet region. In order to make the scenario viable, only the attractive force of the top condensate should exceed the critical coupling, while other channels such as the bottom and tau condensates should not. We then find that the top condensate can be the MAC for D=8, whereas the tau condensation is favored for D=6. The analysis for D=10 strongly depends on the regularization scheme. We predict masses of the top (m_t) and the Higgs (m_H), m_t=172-175 GeV and m_H=176-188 GeV for D=8, based on the renormalization group for the top Yukawa and Higgs quartic couplings with the compositeness conditions at the scale where the bulk top condenses. The Higgs boson in such a characteristic mass range will be immediately discovered in H -> WW^(*)/ZZ^(*) once the LHC starts.Comment: REVTEX4, 24 pages, 21 figures, to appear in PRD. The title is changed in PRD. One reference added, typos correcte

Optical spectroscopy of the radio pulsar PSR B0656+14

We have obtained the spectrum of a middle-aged PSR B0656+14 in the 4300-9000 AA range with the ESO/VLT/FORS2. Preliminary results show that at 4600-7000 AA the spectrum is almost featureless and flat with a spectral index $\alpha_nu ~ -0.2 that undergoes a change to a positive value at longer wavelengths. Combining with available multiwavelength data suggests two wide, red and blue, flux depressions whose frequency ratio is about 2 and which could be the 1st and 2nd harmonics of electron/positron cyclotron absorption formed at magnetic fields ~10^8G in upper magnetosphere of the pulsar.Comment: 4 pages, 4 figures, To appear in Astrophysics and Space Science, Proceedings of "Isolated Neutron Stars: from the Interior to the Surface", eds. D. Page, R. Turolla and S. Zan

Magnetic Field Effects on the Far-Infrared Absorption in Mn_12-acetate

We report the far-infrared spectra of the molecular nanomagnet Mn_12-acetate (Mn_12) as a function of temperature (5-300 K) and magnetic field (0-17 T). The large number of observed vibrational modes is related to the low symmetry of the molecule, and they are grouped together in clusters. Analysis of the mode character based on molecular dynamics simulations and model compound studies shows that all vibrations are complex; motion from a majority of atoms in the molecule contribute to most modes. Three features involving intramolecular vibrations of the Mn_12 molecule centered at 284, 306 and 409 cm-1 show changes with applied magnetic field. The structure near 284 cm$^{-1}$ displays the largest deviation with field and is mainly intensity related. A comparison between the temperature dependent absorption difference spectra, the gradual low-temperature cluster framework distortion as assessed by neutron diffraction data, and field dependent absorption difference spectra suggests that this mode may involve Mn motion in the crown.Comment: 5 pages, 4 figures, PRB accepte

Semiconductive and Photoconductive Properties of the Single Molecule Magnets Mn12_{12}-Acetate and Fe8_8Br8_8

Resistivity measurements are reported for single crystals of Mn$_{12}$-Acetate and Fe$_8$Br$_8$. Both materials exhibit a semiconductor-like, thermally activated behavior over the 200-300 K range. The activation energy, $E_a$, obtained for Mn$_{12}$-Acetate was 0.37 $\pm$ 0.05 eV, which is to be contrasted with the value of 0.55 eV deduced from the earlier reported absorption edge measurements and the range of 0.3-1 eV from intramolecular density of states calculations, assuming $2E_a$= $E_g$, the optical band gap. For Fe$_8$Br$_8$, $E_a$ was measured as 0.73 $\pm$ 0.1 eV, and is discussed in light of the available approximate band structure calculations. Some plausible pathways are indicated based on the crystal structures of both lattices. For Mn$_{12}$-Acetate, we also measured photoconductivity in the visible range; the conductivity increased by a factor of about eight on increasing the photon energy from 632.8 nm (red) to 488 nm (blue). X-ray irradiation increased the resistivity, but $E_a$ was insensitive to exposure.Comment: 7 pages, 8 figure

Quantum dynamics of crystals of molecular nanomagnets inside a resonant cavity

It is shown that crystals of molecular nanomagnets exhibit enhanced magnetic relaxation when placed inside a resonant cavity. Strong dependence of the magnetization curve on the geometry of the cavity has been observed, providing evidence of the coherent microwave radiation by the crystals. A similar dependence has been found for a crystal placed between Fabry-Perot superconducting mirrors. These observations open the possibility of building a nanomagnetic microwave laser pumped by the magnetic field

X=Y–ZH compounds as potential 1,3-dipoles. Part 64: Synthesis of highly substituted conformationally restricted and spiro nitropyrrolidines via Ag(I) catalysed azomethine ylide cycloadditions

1,3-Dipolar reactions of imines of both acyclic and cyclic α-amino esters with a range of nitroolefins using a combination of AgOAc or Ag2O with NEt3 are described. In most cases the reactions were highly regio- and stereospecific and endo-cycloadducts were obtained in good yield. However, in a few cases the initially formed cycloadducts underwent base catalysed epimerisation. The stereochemistry of the cycloadducts was assigned from NOE data and established unequivocally in several cases by X-ray crystallography

Dynamical chiral symmetry breaking in gauge theories with extra dimensions

We investigate dynamical chiral symmetry breaking in vector-like gauge theories in $D$ dimensions with ($D-4$) compactified extra dimensions, based on the gap equation (Schwinger-Dyson equation) and the effective potential for the bulk gauge theories within the improved ladder approximation. The non-local gauge fixing method is adopted so as to keep the ladder approximation consistent with the Ward-Takahashi identities. Using the one-loop $\bar{\rm MS}$ gauge coupling of the truncated KK effective theory which has a nontrivial ultraviolet fixed point (UV-FP) $g_*$ for the (dimensionless) bulk gauge coupling ${\hat g}$, we find that there exists a critical number of flavors, $N_f^{\rm crit}$ ($\simeq 4.2, 1.8$ for $D=6, 8$ for SU(3) gauge theory): For $N_f > N_f^{\rm crit}$, the dynamical chiral symmetry breaking takes place not only in the ``strong-coupling phase'' (${\hat g} >g_*$) but also in the ``weak-coupling phase'' (${\hat g} <g_*$) when the cutoff is large enough. For $N_f < N_f^{\rm crit}$, on the other hand, only the strong-coupling phase is a broken phase and we can formally define a continuum (infinite cutoff) limit, so that the physics is insensitive to the cutoff in this case. We also perform a similar analysis using the one-loop ``effective gauge coupling''. We find the $N_f^{\rm crit}$ turns out to be a value similar to that of the $\bar{\rm MS}$ case, notwithstanding the enhancement of the coupling compared with that of the $\bar{\rm MS}$.Comment: REVTEX4, 38 pages, 18 figures. The abstract is shortened; version to be published in Phys. Rev.