2,081 research outputs found
Air Pollution and Outdoor Recreation On Urban Trails: A Case Study of the Elizabeth River Trail, Norfolk
Poor air quality represents a significant health risk for individuals engaging in recreation activities outdoors in urban parks and trails. This study investigated temporal variability in particulate matter (PM) exposure along an urban waterfront trail. We also used recreation choice frameworks to examine the effects of visitors’ perceptions of air quality (AQ) and health benefits on trail use. Average air quality during the collection period was “good” (PM10) to “moderate” (PM2.5). We found that PM density was significantly higher (p \u3c 0.001), though still in the “moderate” range, at 7–9 a.m., 11 a.m.–1 p.m., and 3–5 p.m., and on weekends. Visitors’ self-reported perceptions of health outcomes, but not air quality, significantly predicted trail use. Results suggest that these experiential factors may affect recreational choices depending on other factors, such as salience. Further research is merited to determine how experiential factors can be integrated with other theories of motivation to understand recreational decision-making
Gallavotti-Cohen-Type symmetry related to cycle decompositions for Markov chains and biochemical applications
We slightly extend the fluctuation theorem obtained in \cite{LS} for sums of
generators, considering continuous-time Markov chains on a finite state space
whose underlying graph has multiple edges and no loop. This extended frame is
suited when analyzing chemical systems. As simple corollary we derive in a
different method the fluctuation theorem of D. Andrieux and P. Gaspard for the
fluxes along the chords associated to a fundamental set of oriented cycles
\cite{AG2}.
We associate to each random trajectory an oriented cycle on the graph and we
decompose it in terms of a basis of oriented cycles. We prove a fluctuation
theorem for the coefficients in this decomposition. The resulting fluctuation
theorem involves the cycle affinities, which in many real systems correspond to
the macroscopic forces. In addition, the above decomposition is useful when
analyzing the large deviations of additive functionals of the Markov chain. As
example of application, in a very general context we derive a fluctuation
relation for the mechanical and chemical currents of a molecular motor moving
along a periodic filament.Comment: 23 pages, 5 figures. Correction
Topped MAC with extra dimensions?
We perform the most attractive channel (MAC) analysis in the top mode
standard model with TeV-scale extra dimensions, where the standard model gauge
bosons and the third generation of quarks and leptons are put in D(=6,8,10,...)
dimensions. In such a model, bulk gauge couplings rapidly grow in the
ultraviolet region. In order to make the scenario viable, only the attractive
force of the top condensate should exceed the critical coupling, while other
channels such as the bottom and tau condensates should not. We then find that
the top condensate can be the MAC for D=8, whereas the tau condensation is
favored for D=6. The analysis for D=10 strongly depends on the regularization
scheme. We predict masses of the top (m_t) and the Higgs (m_H), m_t=172-175 GeV
and m_H=176-188 GeV for D=8, based on the renormalization group for the top
Yukawa and Higgs quartic couplings with the compositeness conditions at the
scale where the bulk top condenses. The Higgs boson in such a characteristic
mass range will be immediately discovered in H -> WW^(*)/ZZ^(*) once the LHC
starts.Comment: REVTEX4, 24 pages, 21 figures, to appear in PRD. The title is changed
in PRD. One reference added, typos correcte
Optical spectroscopy of the radio pulsar PSR B0656+14
We have obtained the spectrum of a middle-aged PSR B0656+14 in the 4300-9000
AA range with the ESO/VLT/FORS2. Preliminary results show that at 4600-7000 AA
the spectrum is almost featureless and flat with a spectral index $\alpha_nu ~
-0.2 that undergoes a change to a positive value at longer wavelengths.
Combining with available multiwavelength data suggests two wide, red and blue,
flux depressions whose frequency ratio is about 2 and which could be the 1st
and 2nd harmonics of electron/positron cyclotron absorption formed at magnetic
fields ~10^8G in upper magnetosphere of the pulsar.Comment: 4 pages, 4 figures, To appear in Astrophysics and Space Science,
Proceedings of "Isolated Neutron Stars: from the Interior to the Surface",
eds. D. Page, R. Turolla and S. Zan
Magnetic Field Effects on the Far-Infrared Absorption in Mn_12-acetate
We report the far-infrared spectra of the molecular nanomagnet Mn_12-acetate
(Mn_12) as a function of temperature (5-300 K) and magnetic field (0-17 T). The
large number of observed vibrational modes is related to the low symmetry of
the molecule, and they are grouped together in clusters. Analysis of the mode
character based on molecular dynamics simulations and model compound studies
shows that all vibrations are complex; motion from a majority of atoms in the
molecule contribute to most modes. Three features involving intramolecular
vibrations of the Mn_12 molecule centered at 284, 306 and 409 cm-1 show changes
with applied magnetic field. The structure near 284 cm displays the
largest deviation with field and is mainly intensity related. A comparison
between the temperature dependent absorption difference spectra, the gradual
low-temperature cluster framework distortion as assessed by neutron diffraction
data, and field dependent absorption difference spectra suggests that this mode
may involve Mn motion in the crown.Comment: 5 pages, 4 figures, PRB accepte
Semiconductive and Photoconductive Properties of the Single Molecule Magnets Mn-Acetate and FeBr
Resistivity measurements are reported for single crystals of
Mn-Acetate and FeBr. Both materials exhibit a
semiconductor-like, thermally activated behavior over the 200-300 K range. The
activation energy, , obtained for Mn-Acetate was 0.37 0.05
eV, which is to be contrasted with the value of 0.55 eV deduced from the
earlier reported absorption edge measurements and the range of 0.3-1 eV from
intramolecular density of states calculations, assuming = , the
optical band gap. For FeBr, was measured as 0.73 0.1 eV,
and is discussed in light of the available approximate band structure
calculations. Some plausible pathways are indicated based on the crystal
structures of both lattices. For Mn-Acetate, we also measured
photoconductivity in the visible range; the conductivity increased by a factor
of about eight on increasing the photon energy from 632.8 nm (red) to 488 nm
(blue). X-ray irradiation increased the resistivity, but was insensitive
to exposure.Comment: 7 pages, 8 figure
Quantum dynamics of crystals of molecular nanomagnets inside a resonant cavity
It is shown that crystals of molecular nanomagnets exhibit enhanced magnetic
relaxation when placed inside a resonant cavity. Strong dependence of the
magnetization curve on the geometry of the cavity has been observed, providing
evidence of the coherent microwave radiation by the crystals. A similar
dependence has been found for a crystal placed between Fabry-Perot
superconducting mirrors. These observations open the possibility of building a
nanomagnetic microwave laser pumped by the magnetic field
X=Y–ZH compounds as potential 1,3-dipoles. Part 64: Synthesis of highly substituted conformationally restricted and spiro nitropyrrolidines via Ag(I) catalysed azomethine ylide cycloadditions
1,3-Dipolar reactions of imines of both acyclic and cyclic α-amino esters with a range of nitroolefins using a combination of AgOAc or Ag2O with NEt3 are described. In most cases the reactions were highly regio- and stereospecific and endo-cycloadducts were obtained in good yield. However, in a few cases the initially formed cycloadducts underwent base catalysed epimerisation. The stereochemistry of the cycloadducts was assigned from NOE data and established unequivocally in several cases by X-ray crystallography
Dynamical chiral symmetry breaking in gauge theories with extra dimensions
We investigate dynamical chiral symmetry breaking in vector-like gauge
theories in dimensions with () compactified extra dimensions, based on
the gap equation (Schwinger-Dyson equation) and the effective potential for the
bulk gauge theories within the improved ladder approximation. The non-local
gauge fixing method is adopted so as to keep the ladder approximation
consistent with the Ward-Takahashi identities.
Using the one-loop gauge coupling of the truncated KK
effective theory which has a nontrivial ultraviolet fixed point (UV-FP)
for the (dimensionless) bulk gauge coupling , we find that there
exists a critical number of flavors, ( for
for SU(3) gauge theory): For , the dynamical
chiral symmetry breaking takes place not only in the ``strong-coupling phase''
() but also in the ``weak-coupling phase'' ()
when the cutoff is large enough. For , on the other hand,
only the strong-coupling phase is a broken phase and we can formally define a
continuum (infinite cutoff) limit, so that the physics is insensitive to the
cutoff in this case.
We also perform a similar analysis using the one-loop ``effective gauge
coupling''. We find the turns out to be a value similar to
that of the case, notwithstanding the enhancement of the
coupling compared with that of the .Comment: REVTEX4, 38 pages, 18 figures. The abstract is shortened; version to
be published in Phys. Rev.
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