1,688 research outputs found

    Electronic and Optical Properties of Aluminum Oxide Before and After Surface Reduction by Ar+ Bombardment

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    The electronic and optical properties of a-Al2O3 after induced by 3-keV Ar+ sputtering  have been studied quantitatively by use of reflection electron energy loss spectroscopy (REELS) spectra. The band gap values of a-Al2O3 was determined from the onset values of the energy loss spectrum to the background level of REELS spectra as a function of time Ar+ bombardment. The bandgap changes from 8.4 eV before sputtering to 6.2 eV after 4 minutes of sputtering.The optical properties of α-Al2O3 thin films have been determined by comparing the experimental cross section obtained from reflection electron energy loss spectroscopy with the theoretical inelastic scattering cross section, deduced from the simulated energy loss function (ELF) by using QUEELS-ε(k)-REELS software. The peak assignments are based on ELF and compared with reported data on the electronic structure of α-Al2O3 obtained using different techniques. The results demonstrate that the electronic and optical properties before and after surface reduction will provide further understanding in the fundamental properties of α-Al2O3 which will be useful in the design, modeling and analysis of devices applications performance.Received: 18 November 2013; Revised:12 June 2014; Accepted: 25 June 2014

    PHS48 Cost-Effectiveness Analysis of Tolvaptan for Hyponatreamia in South Korea

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    Lanz, AlfredoPla general de la part frontal de dona ajaguda sobre un suport en forma de llit o taula. Va ser donada per l'autor, Alfredo Lanz, i simbolitza el mar Mediterrani. Feta en tres planxes d'acer retallades de colors vius: verd, vermell i groc

    Enhanced production of tropane alkaloids in transgenic Scopolia parviflora hairy root cultures over-expressing putrescine N-methyl transferase (PMT) and hyoscyamine-6β-hydroxylase (H6H)

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    Scopolia parviflora adventitious roots were metabolically engineered by co-expression of the two gene putrescine N-methyl transferase (PMT) and hyoscyamine-6β-hydroxylase (H6H) cDNAs with the aid of Agrobacterium rhizogenes. The transformed roots developed into morphologically distinct S. parviflora PMT1 (SpPMT1), S. parviflora PMT1 (SpPMT2), and S. parviflora H6H (SpH6H) transgenic hairy root lines. Consequent to the introduction of these key enzyme genes, the production of the alkaloids hyoscyamine and scopolamine was enhanced. Among the transgenic hairy root lines, SpPMT2 line possessed the highest growth index. The treatment of transgenic hairy roots with growth regulators further enhanced the production of scopolamine. Thus, the results suggest that PMT1, PMT2, and H6H genes may not only be involved in the metabolic regulation of alkaloid production but also that these genes may play a role in the root development

    A first-principles study of MgB2 (0001) surfaces

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    We report self-consistent {\it ab initio} calculations of structural and electronic properties for the B- and Mg-terminated MgB2_{2} (0001) surfaces. We employ ultra-soft pseudopotentials and plane wave basis sets within the generalized gradient approximation. The surface relaxations are found to be small for both B- and Mg-terminated surfaces. For the B-terminated surface, both B σ{\sigma} and π{\pi} surface bands appear, while only one B π{\pi} surface band exists near the Fermi level for the Mg-terminated surface. The superconductivity of the MgB2_2 surfaces is discussed. The work function is predicted to be 5.95 and 4.25 eV for the B- and Mg-terminated surfaces respectively. The simulated scanning tunneling microscopy images of the surfaces are not sensitive to the sign and value of the bias voltages, but depend strongly on the tip-sample distance. An image reversal is predicted for the Mg-terminated surface.Comment: 3 pages, 4 figures, Revte

    Advances in single crystal growth and annealing treatment of electron-doped HTSC

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    High quality electron-doped HTSC single crystals of Pr2xCexCuO4+δ\rm Pr_{2-x}Ce_{x}CuO_{4+\delta} and Nd2xCexCuO4+δ\rm Nd_{2-x}Ce_{x}CuO_{4+\delta} have been successfully grown by the container-free traveling solvent floating zone technique. The optimally doped Pr2xCexCuO4+δ\rm Pr_{2-x}Ce_{x}CuO_{4+\delta} and Nd2xCexCuO4+δ\rm Nd_{2-x}Ce_{x}CuO_{4+\delta} crystals have transition temperatures TcT_{\rm c} of 2525\,K and 23.523.5\,K, respectively, with a transition width of less than 11\,K. We found a strong dependence of the optimal growth parameters on the Ce content xx. We discuss the optimization of the post-growth annealing treatment of the samples, the doping extension of the superconducting dome for both compounds as well as the role of excess oxygen. The absolute oxygen content of the as-grown crystals is determined from thermogravimetric experiments and is found to be 4.0\ge 4.0. This oxygen surplus is nearly completely removed by a post-growth annealing treatment. The reduction process is reversible as demonstrated by magnetization measurements. In as-grown samples the excess oxygen resides on the apical site O(3). This apical oxygen has nearly no doping effect, but rather influences the evolution of superconductivity by inducing additional disorder in the CuO2_{2} layers. The very high crystal quality of Nd2xCexCuO4+δ\rm Nd_{2-x}Ce_{x}CuO_{4+\delta} is particularly manifest in magnetic quantum oscillations observed on several samples at different doping levels. They provide a unique opportunity of studying the Fermi surface and its dependence on the carrier concentration in the bulk of the crystals.Comment: 19 pages, 7 figures, submitted to Eur. Phys. J.

    Anisotropy of the Upper Critical Field and Critical Current in Single Crystal MgB2_2

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    We report on specific heat, high magnetic field transport and acac-susceptibility measurements on magnesium diboride single crystals. The upper critical field Hc2H_{c2} for magnetic fields perpendicular and parallel to the Mg and B planes is presented for the first time in the entire temperature range. A very different temperature dependence has been observed in the two directions which yields to a temperature dependent anisotropy with Γ\Gamma \sim 5 at low temperatures and about 2 near TcT_c. A peak effect is observed in susceptibility measurements for HH \sim 2 T parallel to the cc-axis and the critical current density presnts a sharp maximum for HH parallel to the ab-plane.Comment: 6 pages, 5 figure

    Neutron beam test of CsI crystal for dark matter search

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    We have studied the response of Tl-doped and Na-doped CsI crystals to nuclear recoils and γ\gamma's below 10 keV. The response of CsI crystals to nuclear recoil was studied with mono-energetic neutrons produced by the 3^3H(p,n)3^3He reaction. This was compared to the response to Compton electrons scattered by 662 keV γ\gamma-ray. Pulse shape discrimination between the response to these γ\gamma's and nuclear recoils was studied, and quality factors were estimated. The quenching factors for nuclear recoils were derived for both CsI(Na) and CsI(Tl) crystals.Comment: 21pages, 14figures, submitted to NIM
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